A General Method for Determining the Mechanical Properties Needed for the Computer Analysis of Polymeric Structures Subjected to Changes in Temperature and Relative Humidity

1992 ◽  
Vol 267 ◽  
Author(s):  
Marion F. Mecklenburg ◽  
Charles S. Tumosa ◽  
Mark H. McCormick-Goodhart

ABSTRACTThis study examines the methods for determining the effects of temperature and relative humidity (RH) on the dimensional and mechanical properties of artists' materials. Using both of these properties, typical cultural objects, such as paintings and photographs can be modeled on the computer to correlate the magnitude of developed stresses to environmental changes. Comparing these calculated stresses with the measured strength of the materials provides the opportunity to assess the potential risk from damage due to environmental change. Recognizing that the mechanical properties of polymeric materials are functions of the rate of the application of load, the time they are subjected to a load, the temperature and the relative humidity, it becomes a question of identifying those parameters that are the most important in determining the correct information needed for computer modeling.

1990 ◽  
Vol 185 ◽  
Author(s):  
Marion F. Mecklenburg

AbstractMuch of the damage found in cultural and artistic objects is not chemical in nature but results from mechanical responses to stimuli such as changes in temperature, relative humidity, impact, and vibration. Analytical tools of engineering mechanics are available that allow us both to diagnose existing problems as well as to predict the effects of future potential hazardous conditions for many objects. A systematic approach of applying engineering principles to cultural objects requires two fundamental steps: 1, determining the mechanical properties of the constitutive material found in objects, and 2, developing analytical procedures that determine the overall effect of the individual material responses to various stimuli on the object as a whole. The individual material properties are typically defined as the yield and ultimate strengths, the elastic modulus, and the strains to yield and failure.For the vast proportion of cultural objects, the materials are organic, and their mechanical properties are dramatically altered by environmental factors such as changes in temperature and relative humidity.One of the most successful analytical techniques is Finite Element Analysis (FEA) using the digital computer. This method will allow one to numerically model an object, to mathematically induce environmental changes as well as determine the mechanical effects of these changes on the object modeled.


1992 ◽  
Vol 267 ◽  
Author(s):  
Jonah D. Erlebacher ◽  
Eric Brown ◽  
Marion F. Mecklenburg ◽  
Charles S. Tumosa

ABSTRACTThe mechanical properties of strength, modulus, and elongation to break were studied for artists' acrylic and alkyd paints under varying conditions of temperature and relative humidity (RH). In the ambient environment, 23° C, 50% RH, acrylic paints are very flexible and are able to sustain large deformations (>50%). Alkyd paints are much stiffer and stronger, and they cannot sustain deformations nearly as dramatic as the acrylics. Acrylic paints at 5% RH are stiffer and stronger than at 50% RH and their ability to stretch is lessened. At temperatures below 15° C at 50% RH, the strength and stiffness of acrylic paints begin to rise rapidly. Some were found to be brittle at 5° C, and by −3° C, all were brittle. At a lower RH, some acrylic paints became brittle at a temperature near 11° C. These temperatures and relative humidities may be found in the transport environment of art objects, and may render them subject to possible damage.


2020 ◽  
Vol 67 (2) ◽  
pp. 115-120
Author(s):  
Raisa A. Alekhina ◽  
Victoriya E. Slavkina ◽  
Yuliya A. Lopatina

The article presents options for recycling polymers. The use of biodegradable materials is promising. This is a special class of polymers that can decompose under aerobic or anaerobic conditions under the action of microorganisms or enzymes forming natural products such as carbon dioxide, nitrogen, water, biomass, and inorganic salts. (Research purpose) The research purpose is in reviewing biodegradable materials that can be used for the manufacture of products used in agriculture. (Materials and methods) The study are based on open information sources containing information about biodegradable materials. Research methods are collecting, studying and comparative analysis of information. (Results and discussion) The article presents the advantages and disadvantages of biodegradable materials, mechanical properties of the main groups of biodegradable polymers. The article provides a summary list of agricultural products that can be made from biodegradable polymer materials. It was found that products from the general group are widely used in agriculture. Authors have found that products from a special group can only be made from biodegradable polymers with a controlled decomposition period in the soil, their use contributes to increasing the productivity of crops. (Conclusions) It was found that biodegradable polymer materials, along with environmental safety, have mechanical properties that allow them producing products that do not carry significant loads during operation. We have shown that the creation of responsible products (machine parts) from biodegradable polymers requires an increase in their strength properties, which is achievable by creating composites based on them. It was found that the technological complexity of their manufacture and high cost are the limiting factors for the widespread use of biodegradable polymers at this stage.


Biomolecules ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 1456
Author(s):  
Isabel Matos Oliveira ◽  
Cristiana Gonçalves ◽  
Myeong Eun Shin ◽  
Sumi Lee ◽  
Rui Luis Reis ◽  
...  

Rheumatoid arthritis is a rheumatic disease for which a healing treatment does not presently exist. Silk fibroin has been extensively studied for use in drug delivery systems due to its uniqueness, versatility and strong clinical track record in medicine. However, in general, natural polymeric materials are not mechanically stable enough, and have high rates of biodegradation. Thus, synthetic materials such as gellan gum can be used to produce composite structures with biological signals to promote tissue-specific interactions while providing the desired mechanical properties. In this work, we aimed to produce hydrogels of tyramine-modified gellan gum with silk fibroin (Ty–GG/SF) via horseradish peroxidase (HRP), with encapsulated betamethasone, to improve the biocompatibility and mechanical properties, and further increase therapeutic efficacy to treat rheumatoid arthritis (RA). The Ty–GG/SF hydrogels presented a β-sheet secondary structure, with gelation time around 2–5 min, good resistance to enzymatic degradation, a suitable injectability profile, viscoelastic capacity with a significant solid component and a betamethasone-controlled release profile over time. In vitro studies showed that Ty–GG/SF hydrogels did not produce a deleterious effect on cellular metabolic activity, morphology or proliferation. Furthermore, Ty–GG/SF hydrogels with encapsulated betamethasone revealed greater therapeutic efficacy than the drug applied alone. Therefore, this strategy can provide an improvement in therapeutic efficacy when compared to the traditional use of drugs for the treatment of rheumatoid arthritis.


2021 ◽  
Vol 9 (1) ◽  
Author(s):  
Mathilde Tiennot ◽  
Davide Iannuzzi ◽  
Erma Hermens

AbstractIn this investigation on the mechanical behaviour of paint films, we use a new ferrule-top nanoindentation protocol developed for cultural heritage studies to examine the impact of repeated relative humidity variations on the viscoelastic behaviour of paint films and their mechanical properties in different paint stratigraphies through the changes in their storage and loss moduli. We show that the moisture weathering impact on the micromechanics varies for each of these pigment-oil systems. Data from the nanoindentation protocol provide new insights into the evolution of the viscoelastic properties dsue to the impact of moisture weathering on paint films.


Molecules ◽  
2021 ◽  
Vol 26 (4) ◽  
pp. 773
Author(s):  
Ahmad Safwan Ismail ◽  
Mohammad Jawaid ◽  
Norul Hisham Hamid ◽  
Ridwan Yahaya ◽  
Azman Hassan

Polymer blends is a well-established and suitable method to produced new polymeric materials as compared to synthesis of a new polymer. The combination of two different types of polymers will produce a new and unique material, which has the attribute of both polymers. The aim of this work is to analyze mechanical and morphological properties of bio-phenolic/epoxy polymer blends to find the best formulation for future study. Bio-phenolic/epoxy polymer blends were fabricated using the hand lay-up method at different loading of bio-phenolic (5 wt%, 10 wt%, 15 wt%, 20 wt%, and 25 wt%) in the epoxy matrix whereas neat bio-phenolic and epoxy samples were also fabricated for comparison. Results indicated that mechanical properties were improved for bio-phenolic/epoxy polymer blends compared to neat epoxy and phenolic. In addition, there is no sign of phase separation in polymer blends. The highest tensile, flexural, and impact strength was shown by P-20(biophenolic-20 wt% and Epoxy-80 wt%) whereas P-25 (biophenolic-25 wt% and Epoxy-75 wt%) has the highest tensile and flexural modulus. Based on the finding, it is concluded that P-20 shows better overall mechanical properties among the polymer blends. Based on this finding, the bio-phenolic/epoxy blend with 20 wt% will be used for further study on flax-reinforced bio-phenolic/epoxy polymer blends.


2012 ◽  
Vol 2012 ◽  
pp. 1-6 ◽  
Author(s):  
Lijun Cheng ◽  
Yong Kang ◽  
Guishui Li

Difference between adsorption of benzene by diatomite and nano-TiO2immobilized on diatomite was investigated. And effects of temperature, light intensity, relative humidity, and initial benzene concentration on adsorption and degradation of benzene by nano-TiO2immobilized on diatomite were also studied. The experimental results showed that when initial benzene concentration was2.2×10−3 mg L−1, it could be degraded to below safe concentration (1.1×10−4 mg L−1) after 50 h when temperature was 20°C, but it just needed 30 h at 35°C. When light intensity was 6750 Lx, it needed 30 h for benzene to be degraded to below safe concentration, but benzene could barely be degraded without light. When relative humidity was 50%, benzene could be degraded to1.0×10−4 mg L−1after 30 h, while its concentration could be reduced to7.0×10−5 mg L−1at the relative humidity of 80%.


1989 ◽  
Vol 67 (3) ◽  
pp. 928-932 ◽  
Author(s):  
Kan-Fa Chang ◽  
P. V. Blenis

The effects of temperature and relative humidity (RH) on the survival of Endocronartium harknessii teliospores and the longevity of these spores out of doors during daylight hours were studied. In one experiment, fresh and liquid-nitrogen-stored spores of E. harknessii were impacted onto spider webs or plastic threads and incubated in darkness at temperatures of 6, 15, and 24 °C and RHs of 39 and 98%. Survival was measured after 1, 2, 4, 8, and 16 days. Spore longevity decreased with increasing temperature and was lower at 98 than at 39% RH. In a second experiment, spores were impacted onto spider webs and placed out of doors on clear days. Viability decreased linearly with time and averaged 33% after 12 h. The data suggest that E. harknessii has relatively good ability to survive in an airborne state and thus would have considerable potential for long distance spread.


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