In-Situ Corrosion Studies on Cast Steel High-Level Waste Containers Plated with Titanium/Nickel-Alloys

1991 ◽  
Vol 257 ◽  
Author(s):  
W. Schwarzkopf ◽  
E. Smailos ◽  
R. KÖster
Keyword(s):  
Corrosion Protection ◽  
Corrosion Behaviour ◽  
Cast Steel ◽  
Steel Tube ◽  
High Level Waste ◽  
Vertical Temperature Profile ◽  
Corrosion Studies ◽  
In Situ Experiments ◽  
Container Manufacturing

ABSTRACTPrevious corrosion studies have shown that the passive alloys Ti 99.8-Pd and Hastelloy C4 are the most promising corrosion protection materials for long-term resistant carbon-steel containers for the disposal of heat-generating wastes in rock salt formations. Consequently, these materials are subject to more detailed investigations. The influence of selected container manufacturing characteristics (sealing technique, application mode of the corrosion protecting layer on the steel) on the corrosion behaviour of Ti 99.8-Pd and Hastelloy C4was studied using in-situ experiments. The corrosion resistance of the materials was examined both in NaCI brine and MgCl2-rich brine, which might enter into an HLW borehole under certain disposal conditions. Four electron-beam welded cast-steel tubes plated with corrosion protection layers made of Ti 99.8-Pd and Hastelloy C4, respectively, were stored for 18 months in 2-m deep heated boreholes in the Asse salt mine. The annular gap between the tubes and the borehole wall was filled with saturated NaCl-brine or Qbrine (MgCl2-rich). The vertical temperature profile in the boreholes ranged from 90°C to 200°CIn the cast-steel tube with a corrosion protection of Ti 99.8-Pd, no indication of corrosion was observed on the EB-welds or on the explosion plated material in both brines. The cast-steel tube with a corrosion protection of Hastelloy C4 also was found to be resistant to any kind of corrosion in the NaCl-brine. In the MgCl2-rich brine, however, small pitting corrosion of 15 pm was observed after 1.5 years on the passive surface layer that was formed.On the basis of these results, Ti 99.8-Pd continues to be considered as a promising corrosion protection material for long-lived HLW containers.

In-Situ Corrosion Studies on Cast Steel for a High-Level Waste Packaging in a Rock Salt Repository

1988 ◽  
Vol 127 ◽  
Author(s):  
W. Schwarzkopf ◽  
E. Smailos ◽  
R. Koster
Keyword(s):  
Electron Beam ◽  
Rock Salt ◽  
Corrosion Behaviour ◽  
Cast Steel ◽  
Maximum Temperature ◽  
High Level Waste ◽  
General Corrosion ◽  
Vertical Temperature Profile ◽  
Corrosion Studies

ABSTRACTPrevious corrosion studies performed on a number of materials have shown that unalloyed steels are promising materials for long-term resistant packagings to be used in disposal of heat-generating wastes in rock salt formations. This is the reason why those steels are the subject of more detailed investigations. This paper reports an in-situ experiment conducted in the Asse salt mine in which the influence of selected characteristics (welding, shape) of containers on the corrosion behaviour of cast steel was studied. The material was tested in NaCl brine which might intrude into an HLW borehole in an accident scenario. For this, an electron beam welded cast-steel tube was stored for 18 months in a 2-m deep heated borehole and the annular gap between the tube and the borehole wall was filled with saturated NaCl brine. The vertical temperature profile in the borehole was in the range from 90°C to 200°C; the maximum temperature occurred in the center of the heated zone and the minimum temperature in the upper parts of tube.Under the testing conditions cast steel was subjected to general corrosion at a maximum corrosion rate of 120 μm/a. Considering this magnitude of the corrosion rates, the resulting corrosion allowances are technically acceptable for a packaging having long service-lives. Pitting and crevice corrosion as well as stress-corrosion cracking did not occur in cast steel, and electron beam welding did not exert a noticeable influence on cast-steel corrosion. With these results available, cast steel continues to be considered as a promising HLW packaging material.

The Strategy of the Belgian Nuclear Research Centre in the Area of High-Level Waste Form Compatibility Research

2007 ◽  
Author(s):  
Karel Lemmens ◽  
Christelle Cachoir ◽  
Elie Valcke ◽  
Karine Ferrand ◽  
Marc Aertsens ◽  
...  
Keyword(s):  
Nuclear Research ◽  
Waste Form ◽  
Research Centre ◽  
High Level Waste ◽  
Spent Fuel ◽  
National Agency ◽  
Waste Forms ◽  
In Situ Experiments ◽  
High Level

The Belgian Nuclear Research Centre (SCK•CEN) has a long-standing expertise in research concerning the compatibility of waste forms with the final disposal environment. For high level waste, most attention goes to two waste forms that are relevant for Belgium, namely (1) vitrified waste from the reprocessing of spent fuel, and (2) spent fuel as such, referring to the direct disposal scenario. The expertise lies especially in the study of the chemical interactions between the waste forms and the disposal environment. This is done by laboratory experiments, supported by modeling. The experiments vary from traditional leach tests, to more specific tests for the determination of particular parameters, and highly realistic experiments. This results in a description of the phenomena that are expected upon disposal of the waste forms, and in quantitative data that allow a conservative long-term prediction of the in situ life time of the waste form. The predictions are validated by in situ experiments in the underground research laboratory HADES. The final objective of these studies, is to estimate the contribution of the waste form to the overall safety of the disposal system, as part of the Safety and Feasibility Case, planned by the national agency ONDRAF/NIRAS. The recent change of the Belgian disposal concept from an engineered barrier system based on the use of bentonite clay to a system based on a concrete buffer has caused a reorientation of the research programme. The expertise in the area of clay-waste interaction will however be maintained, to develop experimental methodologies in collaboration with other countries, and as a potential support to the decision making in those countries where a clay based near field is still the reference. The paper explains the current R&D approach, and highlights some recent experimental set-ups available at SCK•CEN for this purpose, with some illustrating results.

Corrosion Induced Hydrogen Evolution on High Level Waste Overpack Materials in Synthetic Groundwaters and Chloride Solutions

1988 ◽  
Vol 127 ◽  
Author(s):  
J. P. Simpson ◽  
R. Schenk
Keyword(s):  
Oxide Layer ◽  
Hydrogen Evolution ◽  
Corrosion Behaviour ◽  
Cast Steel ◽  
High Level Waste ◽  
General Corrosion ◽  
Layer Formation ◽  
High Level ◽  
Waste Repositories

ABSTRACTHydrogen evolution from anoxic corrosion of cast steel overpacks in high-level waste repositories is an important issue for design if, as has been estimated, the hydrogen is prevented from escaping by diffusion by a low permeability compacted bentonite backfill.Evaluation of the corrosion results showed three basic types of corrosion behaviour: general corrosion with oxide layer formation, unstable corrosion behaviour with pitting or macro-element formation and stable passive behaviour.Cast steel containers under Swiss repository conditions are expected to suffer general corrosion with oxide layer formation. This behaviour gives the highest long term corrosion rates (2–5 μm/a) without local attack, above the 0.03–0.8 μm/a tolerated for hydrogen escape by diffusion but below the 20 μm/a assumed for overpack design.

An in situ and ex situ TEM study of the formation of thin cobalt silicide films by molecular beam epitaxy on the silicon (100) surface

1988 ◽  
Vol 46 ◽  
pp. 884-885
Author(s):  
D. Loretto ◽  
J. M. Gibson ◽  
S. M. Yalisove ◽  
R. T. Tung
Keyword(s):  
Molecular Beam Epitaxy ◽  
Molecular Beam ◽  
Defect Density ◽  
High Vacuum ◽  
Ultra High Vacuum ◽  
Ex Situ ◽  
Metal Base ◽  
In Situ Experiments ◽  
Potential Applications

The cobalt disilicide/silicon system has potential applications as a metal-base and as a permeable-base transistor. Although thin, low defect density, films of CoSi2 on Si(111) have been successfully grown, there are reasons to believe that Si(100)/CoSi2 may be better suited to the transmission of electrons at the silicon/silicide interface than Si(111)/CoSi2. A TEM study of the formation of CoSi2 on Si(100) is therefore being conducted. We have previously reported TEM observations on Si(111)/CoSi2 grown both in situ, in an ultra high vacuum (UHV) TEM and ex situ, in a conventional Molecular Beam Epitaxy system.The procedures used for the MBE growth have been described elsewhere. In situ experiments were performed in a JEOL 200CX electron microscope, extensively modified to give a vacuum of better than 10-9 T in the specimen region and the capacity to do in situ sample heating and deposition. Cobalt was deposited onto clean Si(100) samples by thermal evaporation from cobalt-coated Ta filaments.

Electron and ion irradiation-induced dissolution of mechanical twins in the intermetalic U3Si: An in situ HVEM study

1989 ◽  
Vol 47 ◽  
pp. 652-653
Author(s):  
Charles W. Allen ◽  
Robert C. Birtcher
Keyword(s):  
Elevated Temperatures ◽  
Ion Irradiation ◽  
Ion Beam ◽  
National Laboratory ◽  
Argonne National Laboratory ◽  
Heavy Ion ◽  
High Energy ◽  
Mechanical Twinning ◽  
In Situ Experiments

The uranium silicides, including U3Si, are under study as candidate low enrichment nuclear fuels. Ion beam simulations of the in-reactor behavior of such materials are performed because a similar damage structure can be produced in hours by energetic heavy ions which requires years in actual reactor tests. This contribution treats one aspect of the microstructural behavior of U3Si under high energy electron irradiation and low dose energetic heavy ion irradiation and is based on in situ experiments, performed at the HVEM-Tandem User Facility at Argonne National Laboratory. This Facility interfaces a 2 MV Tandem ion accelerator and a 0.6 MV ion implanter to a 1.2 MeV AEI high voltage electron microscope, which allows a wide variety of in situ ion beam experiments to be performed with simultaneous irradiation and electron microscopy or diffraction.At elevated temperatures, U3Si exhibits the ordered AuCu3 structure. On cooling below 1058 K, the intermetallic transforms, evidently martensitically, to a body-centered tetragonal structure (alternatively, the structure may be described as face-centered tetragonal, which would be fcc except for a 1 pet tetragonal distortion). Mechanical twinning accompanies the transformation; however, diferences between electron diffraction patterns from twinned and non-twinned martensite plates could not be distinguished.

A computer-control program for TEM in situ fatigue experiments

1989 ◽  
Vol 47 ◽  
pp. 620-621
Author(s):  
Kenneth S. Vecchio ◽  
John A. Hunt
Keyword(s):  
Slow Crack Growth ◽  
Computer Control ◽  
Control Program ◽  
Video Tape ◽  
Computer Control System ◽  
Transmission Electron ◽  
In Situ Experiments ◽  
Tremendous Amount ◽  
And Control

In-situ experiments conducted within a transmission electron microscope provide the operator a unique opportunity to directly observe microstructural phenomena, such as phase transformations and dislocation-precipitate interactions, “as they happen”. However, in-situ experiments usually require a tremendous amount of experimental preparation beforehand, as well as, during the actual experiment. In most cases the researcher must operate and control several pieces of equipment simultaneously. For example, in in-situ deformation experiments, the researcher may have to not only operate the TEM, but also control the straining holder and possibly some recording system such as a video tape machine. When it comes to in-situ fatigue deformation, the experiments became even more complicated with having to control numerous loading cycles while following the slow crack growth. In this paper we will describe a new method for conducting in-situ fatigue experiments using a camputer-controlled tensile straining holder.The tensile straining holder used with computer-control system was manufactured by Philips for the Philips 300 series microscopes. It was necessary to modify the specimen stage area of this holder to work in the Philips 400 series microscopes because the distance between the optic axis and holder airlock is different than in the Philips 300 series microscopes. However, the program and interfacing can easily be modified to work with any goniometer type straining holder which uses a penrmanent magnet motor.

Coliform transport in a pristine reservoir: modeling and field studies

1998 ◽  
Vol 37 (2) ◽  
pp. 137-144 ◽  
Author(s):  
Elisa Garvey ◽  
John E. Tobiason ◽  
Michael Hayes ◽  
Evelyn Wolfram ◽  
David A. Reckhow ◽  
...  
Keyword(s):  
Model Development ◽  
Fate And Transport ◽  
Field Studies ◽  
Meteorological Conditions ◽  
Reservoir Modeling ◽  
Vertical Circulation ◽  
Quality Model ◽  
Circulation Patterns ◽  
In Situ Experiments

This paper reports on field studies and model development aimed at understanding coliform fate and transport in the Quabbin Reservoir, an oligotrophic drinking water supply reservoir. An investigation of reservoir currents suggested the importance of wind driven phenomena, and that both lateral and vertical circulation patterns exist. In-situ experiments of coliform decay suggested dependence on light intensity and yielded an appropriate decay coefficient to be used in CE-QUAL-W2, a two-dimensional hydrodynamic and water quality model. Modeling confirmed the sensitivity of reservoir outlet concentration to vertical variability within the reservoir, meteorological conditions, and location of coliform source.

scholarly journals Upscaling THM modeling from small-scale to full-scale in-situ experiments in the Callovo-Oxfordian claystone

2021 ◽  
Vol 144 ◽  
pp. 104582
Author(s):  
D.M. Seyedi ◽  
C. Plúa ◽  
M. Vitel ◽  
G. Armand ◽  
J. Rutqvist ◽  
...  
Keyword(s):  
Full Scale ◽  
Small Scale ◽  
In Situ Experiments

scholarly journals Memory Effect on a LDH/zeolite A Composite: An XRD In Situ Study

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2102
Author(s):  
Breno G. P. Bezerra ◽  
Lindiane Bieseki ◽  
Mariele I. S. de Mello ◽  
Djalma R. da Silva ◽  
Cristiane B. Rodella ◽  
...  
Keyword(s):  
Memory Effect ◽  
Inert Atmosphere ◽  
Effect Study ◽  
Physical Mixture ◽  
Zeolite A ◽  
Three Samples ◽  
In Situ Experiments ◽  
Double Hydroxide ◽  
Rehydration Process

In this memory effect study, hydrotalcite-type compounds in the lamellar double hydroxide-like (LDH)/zeolite A composite material were analyzed using X-Ray Diffration XRD) in situ experiments. Three samples were analyzed: Al,Mg-LDH, Al,Mg-LDH/ZA composite, and a physical mixture (50/50 wt%) of zeolite A and Al,Mg-LDH. The Al,Mg-LDH sample was treated at 500 °C in an O2 atmosphere and subsequently rehydrated. The Al,Mg-LDH/ZA composites had three treatments: one was performed at 300 °C in a He atmosphere, and two treatments were performed with an O2 atmosphere at 300 and 500 °C. In the physical mixture, two treatments were carried out under O2 flow at 500 °C and under He flow at 300 °C. Both went through the rehydration process. All samples were also analyzed by energy dispersive spectroscopy (EDS) and scanning electron microscopy (SEM). The results show that the LDH phase in the Al,Mg-LDH/ZA compounds has memory effects, and thus, the compound can be calcined and rehydrated. For the LDH in the composite, the best heat treatment system is a temperature of 300 °C in an inert atmosphere.

Effects of corrosion on a steel bowstring bridge in marine environment: A case-study of assessment and retrofit

2021 ◽  
Vol 16 (4) ◽  
pp. 121-137
Author(s):  
Michele Fabio Granata
Keyword(s):  
Corrosion Protection ◽  
Marine Environment ◽  
Spray Coating ◽  
Thermal Spray Coating ◽  
In Situ Tests ◽  
Limit States ◽  
Intervention Measures ◽  
Near Future

The case-study of a steel bowstring bridge set in a marine environment and highly damaged by corrosion is presented. The bridge was built in 2004 and was repainted for corrosion protection in 2010. Despite the recent construction and the maintenance interventions, many structural elements like hangers are highly damaged by corrosion with decreasing performance in terms of serviceability and ultimate limit states. A deep investigation was carried out in order to assess the bridge and to establish the necessary retrofit actions to be carried out in the near future. In-situ tests reveal the reduced performance of the original steel in terms of strength and corrosion protection, together with the inefficiency of the successive maintenance interventions. The paper presents assessment of the bridge and retrofit measures, including replacement of the hangers and galvanization through thermal spray coating technology, in order to increase its service life. The results of the investigations and the intervention measures are outlined and discussed.

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