Heteroaromatics: Exceptional Materials for Second Order Nonlinear Optical Applications

1992 ◽  
Vol 247 ◽  
Author(s):  
Alex K-Y. Jen ◽  
K. Y. Wong ◽  
V. Pushkara Rao ◽  
K. Drost ◽  
R. M. Mininni
Keyword(s):  
Optical Properties ◽  
Power Law ◽  
Nonlinear Optical ◽  
Second Order ◽  
Electron Acceptors ◽  
Length Scale ◽  
Electron Systems ◽  
Good Solubility ◽  
Optical Applications ◽  
Nonlinear Optical Applications

ABSTRACTNew classes of nonlinear optical molecules were synthesized and characterized. It is shown experimentally that molecules with heteroaromatic π-electron systems exhibit exceptional second order nonlinear optical response and good solubility. Measurement of the nonlinear optical properties of molecules containing heteroaromatic moieties with different length scale reveals a power law dependence of Bμ on the number of π-electrons. Also, the effects of two nitro groups as electron acceptors on the aromatic ring are discussed.

scholarly journals Theoretical and experimental comparative studies of nonlinear optical properties for selected melaminium compounds

2010 ◽  
Vol 8 (6) ◽  
pp. 1192-1202 ◽  
Author(s):  
Marek Drozd ◽  
Mariusz Marchewka
Keyword(s):  
Optical Properties ◽  
Acetic Acid ◽  
Nonlinear Optical ◽  
Time Dependent ◽  
X Ray ◽  
Hartree Fock ◽  
Optical Applications ◽  
Experimental Values ◽  
Nonlinear Optical Applications ◽  
Theoretical Results

AbstractThe bis(melaminium) sulphate dihydrate, 2,4,6-triamine-1,3,5-triazin-1,3-ium tartrate monohydrate, 2,4,6-triamine-1,3,5-triazin-1-ium hydrogenphthalate, 2,4,6-triamine-1,3,5-triazin-1-ium acetate acetic acid solvate monohydrate, 2,4,6-triamine-1,3,5-triazin-1-ium bis(selenate) trihydrate, melaminium diperchlorate hydrate, melaminium bis(trichloroacetate) monohydrate and melaminium bis(4-hydroxybenzenesulphonate) dihydrate were discovered recently as perspective materials for nonlinear optical applications. On the basis of X-ray structures for eight melaminium compounds the time dependent Hartree Fock (TDHF) method was used for calculation of the polarizability, and first and second hyperpolarizability. Detailed directional studies of calculated hyperpolarizability for all investigated melaminium compounds are shown. The theoretical results are compared with experimental values of β.

Exceptionally Thermally Stable Polyimides for Second-Order Nonlinear Optical Applications

Science ◽  
1995 ◽  
Vol 268 (5217) ◽  
pp. 1604-1606 ◽  
Author(s):  
T. Verbiest ◽  
D. M. Burland ◽  
M. C. Jurich ◽  
V. Y. Lee ◽  
R. D. Miller ◽  
...  
Keyword(s):  
Nonlinear Optical ◽  
Second Order ◽  
Thermally Stable ◽  
Optical Applications ◽  
Nonlinear Optical Applications

A thorough understanding of the nonlinear optical properties of BODIPY/carborane/diketopyrrolopyrrole hybrid chromophores: module contribution, linear combination, one-/two-dimensional difference and carborane's arrangement

2019 ◽  
Vol 7 (25) ◽  
pp. 7531-7547 ◽  
Author(s):  
Hong-Qiang Wang ◽  
Jin-Ting Ye ◽  
Yuan Zhang ◽  
Yuan-Yuan Zhao ◽  
Yong-Qing Qiu
Keyword(s):  
Optical Properties ◽  
Linear Combination ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Two Dimensional ◽  
Optical Applications ◽  
Nonlinear Optical Applications

The high modularity of multicomponent photoactive BODIPY/carborane/diketopyrrolopyrrole hybrid chromophores was explored for linear/nonlinear optical applications.

High glass transition chromophore functionalised poly(maleimide-styrene)s for second-order nonlinear optical applications

Polymer ◽  
2000 ◽  
Vol 41 (16) ◽  
pp. 6049-6054 ◽  
Author(s):  
C Samyn ◽  
T Verbiest ◽  
E Kesters ◽  
K Van den Broeck ◽  
M Van Beylen ◽  
...  
Keyword(s):  
Glass Transition ◽  
Nonlinear Optical ◽  
Second Order ◽  
Optical Applications ◽  
Nonlinear Optical Applications

New Borate Structures for Nlo Applications

1993 ◽  
Vol 329 ◽  
Author(s):  
Douglas A. Keszler ◽  
Annapoorna Akella ◽  
Kathleen I. Schaffers ◽  
Theodore Alekel
Keyword(s):  
Optical Properties ◽  
Solid State ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Linear Optical Properties ◽  
Linear And Nonlinear ◽  
Linear Optical ◽  
Optical Applications ◽  
Nonlinear Optical Applications

AbstractBy considering selected examples of new structure types, guidelines are set forth for the synthesis of new solid-state inorganic borates that are likely to have desirable properties for nonlinear optical applications. The structures of two new, noncentrosymmetric orthoborate fluorides BaCaBO3F and Ba7(BO3)3F5 demonstrate a feasibility for controlling linear optical properties and for producing noncentrosymmetric borates that melt congruently. The structure of SrLi(B3O5)3 represents an additional example of a noncentrosymmetric borate resulting from chirality of the B3O7 ring. In addition to potential practical value, crystals of the type AMOB2O5 (A = K, Rb, and Cs; M = Nb and Ta) provide a unique means for examining the structural dependent interrelationships of linear and nonlinear optical properties.

New Cross-Linkable Polymers with Huisgen Reaction Incorporating High μβ Chromophores for Second-Order Nonlinear Optical Applications

2012 ◽  
Vol 24 (6) ◽  
pp. 1143-1157 ◽  
Author(s):  
Clément Cabanetos ◽  
Wissam Bentoumi ◽  
Virginie Silvestre ◽  
Errol Blart ◽  
Yann Pellegrin ◽  
...  
Keyword(s):  
Nonlinear Optical ◽  
Second Order ◽  
Huisgen Reaction ◽  
Optical Applications ◽  
Nonlinear Optical Applications
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