Quadratic Nonlinear Optical Properties of Polymeric Organic Materials.

1992 ◽  
Vol 247 ◽  
Author(s):  
L.-T. Cheng ◽  
R. P. Foss ◽  
G. R. Meredith ◽  
W. Tam ◽  
F. C. Zumsteg
Keyword(s):  
Thin Film ◽  
Optical Properties ◽  
Harmonic Generation ◽  
Nonlinear Optical ◽  
Second Harmonic ◽  
Optical Loss ◽  
Rational Approach ◽  
Thin Film Fabrication ◽  
Electro Optic ◽  
Film Fabrication

ABSTRACTWe discuss our rational approach to incorporate optically nonlinear molecules into polymeric and cross-linked materials through the use of isocyanate-hydroxy coupling chemistry. Thin film fabrication, optical loss, poling, second harmonic generation, and electro-optic properties are discussed.

K2Sn2ZnSe6, Na2Ge2ZnSe6, and Na2In2GeSe6: a new series of quaternary selenides with intriguing structural diversity and nonlinear optical properties

2016 ◽  
Vol 45 (18) ◽  
pp. 7627-7633 ◽  
Author(s):  
Molin Zhou ◽  
Chao Li ◽  
Xiaoshuang Li ◽  
Jiyong Yao ◽  
Yicheng Wu
Keyword(s):  
Optical Properties ◽  
Second Harmonic Generation ◽  
Harmonic Generation ◽  
Nonlinear Optical ◽  
Second Harmonic ◽  
Structural Diversity ◽  
Nonlinear Optical Properties

New selenides K2Sn2ZnSe6, Na2Ge2ZnSe6, and Na2In2GeSe6 exhibit diverse structures and Na2In2GeSe6 possesses a moderate second harmonic generation response.

Intracavity Second-Harmonic Generation and Influence of Optical Loss of Organic Nonlinear Optical Materials

1995 ◽  
Vol 34 (Part 1, No. 2A) ◽  
pp. 497-503 ◽  
Author(s):  
Hisashi Minemoto ◽  
Yusuke Ozaki ◽  
Katsuya Wakita ◽  
Nobuo Sonoda ◽  
Takatomo Sasaki
Keyword(s):  
Second Harmonic Generation ◽  
Harmonic Generation ◽  
Optical Materials ◽  
Nonlinear Optical ◽  
Second Harmonic ◽  
Optical Loss ◽  
Nonlinear Optical Materials

Second harmonic generation from alternate-layer LB films: quadratic enhancement with film thickness

1994 ◽  
Vol 445 (1924) ◽  
pp. 385-398 ◽  
Keyword(s):  
Optical Properties ◽  
Second Harmonic Generation ◽  
Film Thickness ◽  
Harmonic Generation ◽  
Nonlinear Optical ◽  
Second Harmonic ◽  
Lb Films ◽  
Langmuir Blodgett ◽  
Alternate Layer ◽  
Order Susceptibility

The second harmonic generation (SHG) from alternate-layer Langmuir-Blodgett (LB) films of stilbazolium dyes and 4, 4'-dioctadecyl-3, 5, 3', 5'-tetramethyldipyrryl-methene hydrobromide increases as I 2ω(N) = l 2ω(1) N 2 for N ≥ 2 bilayers, but the equivalent monolayer signal ( I 2ω(1) ) is significantly less than the intensity from LB monolayers of the corresponding dye on glass. This is attributed, in part, to the different molecular tilts and, in part, to the position of the anion which influences the charge distribution within the chromophore. For alternate-layer films of E-N-octadecyl-4-[2-(4-dimethylaminophenyl)ethenyl]pyridinium octadecylsulphate (dye I) the second-order susceptibility and chromophore tilt angle are χ (2) zzz = 45 pm V -1 and ϕ = 30° respectively, whereas the methoxy congener, E-N-octadecyl-4-[2-(4-methoxyphenyl)ethenyl]pyridinium octadecylsulphate (dye II), has χ (2) zzz = 11 Pm V -1 and ϕ = 35°. The nonlinear optical properties of such films are dependent upon the compatibility of the dye and spacer.

Investigation of the nonlinear optical properties of metamaterials by second harmonic generation

2011 ◽  
Vol 105 (1) ◽  
pp. 149-162 ◽  
Author(s):  
M. Gentile ◽  
M. Hentschel ◽  
R. Taubert ◽  
H. Guo ◽  
H. Giessen ◽  
...  
Keyword(s):  
Optical Properties ◽  
Second Harmonic Generation ◽  
Harmonic Generation ◽  
Nonlinear Optical ◽  
Second Harmonic ◽  
Nonlinear Optical Properties

Polar potassium rare earth nitrates K2[RE(NO3)5(H2O)2] (RE = La, Ce, Pr and Nd). II. Linear and nonlinear optical properties

2000 ◽  
Vol 33 (2) ◽  
pp. 380-386 ◽  
Author(s):  
H. Hellwig ◽  
S. Rühle ◽  
P. Held ◽  
L. Bohatý
Keyword(s):  
Optical Properties ◽  
Rare Earth ◽  
Second Harmonic Generation ◽  
Harmonic Generation ◽  
Nonlinear Optical ◽  
Second Harmonic ◽  
Point Group ◽  
Nonlinear Optical Properties ◽  
Rare Earth Nitrates ◽  
Linear And Nonlinear

Linear and nonlinear optical properties of the four isomorphic orthorhombic (point groupmm2) potassium rare earth nitrates K2[RE(NO3)5(H2O)2], with RE = La, Ce, Pr or Nd, have been investigated. Refractive indices in a wavelength range from 0.35 to 2.5 µm and the transmission spectra between 0.25 to 3.0 µm were measured. Using the Maker fringe technique, the d_{ijk}^{\rm\, SHG} coefficients of second-harmonic generation for a fundamental of the Nd–YAP laser (λ = 1079.5 nm) were determined for all four compounds. The d_{ijk}^{\rm\, SHG} coefficients of all four substances are about three times larger than those of KDP, as was first published by Ebberset al.[IEEE J. Quantum Electron.(1993),29, 497–507] for K2[La(NO3)5(H2O)2]. These nitrates are promising materials for application to nonlinear optics (e.g.second-harmonic generation of Nd laser radiation). The nonlinear optical properties of these compounds seem to have their origin mainly in the nitrate groups, as indicated by a simple model (summing the molecular hyperpolarizabilities of the NO3group). Neglecting local field effects, the hyperpolarizability of the NO3group was calculated as β222= 2.52 × 10−40 m4 V−1.

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