Production of Molecular Clusters of Lithium Niobate by Ultraviolet and Visible Laser Ablation

1991 ◽  
Vol 243 ◽  
Author(s):  
R. F. Haglund ◽  
K. Tang ◽  
C. H. Chen

AbstractWe have investigated laser ablation of molecular ions from the ferroelectric LiNbO3 at 532, 355 and 266 nm, comparing the effects of changing wavelength and intensity. The time-of-flight spectra show great sensitivity to the onset of plasma formation. Just below the plasma formation threshold, production of the monomer, dimer and trimer negative molecular ions were observed. Possible implications for thin-film deposition processing are discussed.

Author(s):  
M. Grant Norton ◽  
C. Barry Carter

Pulsed-laser ablation has been widely used to produce high-quality thin films of YBa2Cu3O7-δ on a range of substrate materials. The nonequilibrium nature of the process allows congruent deposition of oxides with complex stoichiometrics. In the high power density regime produced by the UV excimer lasers the ablated species includes a mixture of neutral atoms, molecules and ions. All these species play an important role in thin-film deposition. However, changes in the deposition parameters have been shown to affect the microstructure of thin YBa2Cu3O7-δ films. The formation of metastable configurations is possible because at the low substrate temperatures used, only shortrange rearrangement on the substrate surface can occur. The parameters associated directly with the laser ablation process, those determining the nature of the process, e g. thermal or nonthermal volatilization, have been classified as ‘primary parameters'. Other parameters may also affect the microstructure of the thin film. In this paper, the effects of these ‘secondary parameters' on the microstructure of YBa2Cu3O7-δ films will be discussed. Examples of 'secondary parameters' include the substrate temperature and the oxygen partial pressure during deposition.


1998 ◽  
Vol 66 (2) ◽  
pp. 183-187 ◽  
Author(s):  
M. Diegel ◽  
F. Falk ◽  
R. Hergt ◽  
H. Hobert ◽  
H. Stafast

1997 ◽  
Vol 295 (1-2) ◽  
pp. 77-82 ◽  
Author(s):  
A. Giardini Guidoni ◽  
A. Mele ◽  
T.M. Di Palma ◽  
C. Flamini ◽  
S. Orlando ◽  
...  

1996 ◽  
Vol 3 (5) ◽  
pp. 2203-2209 ◽  
Author(s):  
J. N. Leboeuf ◽  
K. R. Chen ◽  
J. M. Donato ◽  
D. B. Geohegan ◽  
C. L. Liu ◽  
...  

1998 ◽  
Vol 10 (4) ◽  
pp. 1091-1095 ◽  
Author(s):  
Valentin Panayotov ◽  
Teresa L. T. Birdwhistell ◽  
Brent Koplitz

ChemInform ◽  
2011 ◽  
Vol 42 (5) ◽  
pp. no-no
Author(s):  
Christof W. Schneider ◽  
Thomas Lippert

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