The Effect of Grain Boundary Chemistry on the Slip Transmission Process Through Grain Boundaries in Ni3Al

1991 ◽  
Vol 238 ◽  
Author(s):  
I. M. Robertson ◽  
T. C. Lee ◽  
Raja Subramanian ◽  
H. K. Birnbaum
Keyword(s):  
Stress Concentration ◽  
Grain Boundary ◽  
Slip System ◽  
Grain Boundaries ◽  
Local Stress ◽  
Crack Advance ◽  
Boron Doped ◽  
Show Evidence ◽  
Fcc Alloy ◽  
Boundary Chemistry

ABSTRACTThe conditions established in disordered FCC systems for predicting the slip system that will be activated by a grain boundary to relieve a local stress concentration have been applied to the ordered FCC alloy Ni3Al. The slip transfer behavior in hypo-stoichiometric Ni3Al with (0.2 at. %B) and without boron was directly observed by performing the deformation experiments in situ in the transmission electron microscope. In the boron-free and boron-doped alloys, lattice dislocations were incorporated in the grain boundary, but did not show evidence of dissociation to grain boundary dislocations or of movement in the grain boundary plane. The stress concentration associated with the dislocation pileup at the grain boundary was relieved by the emission of dislocations from the grain boundary in the boron-doped alloy. The slip system initiated in the adjoining grain obeyed the conditions established for disordered FCC systems. In the boron-free alloy, the primary stress relief mechanism was grain-boundary cracking, although dislocation emission from the grain boundary also occurred and accompanied intergranular crack advance. Because of the importance of the grain boundary chemistry in the models for explaining the boron-induced ductility in hypo-stoichiometric Ni3Al, the chemistry of grain boundaries in well-annealed boron-doped and boron-free alloys was determined by using EDS. No Ni enrichment was found at the grain boundaries examined. These observations are discussed in terms of the different models proposed to explain the ductility improvement in the boron-doped, hypo-stoichiometric alloy.

Effects of Microstructure on Cavity Nucleation in Creeping Ceramics Containing Viscous Grain Boundary Phase

2008 ◽  
Vol 368-372 ◽  
pp. 1084-1087
Author(s):  
Chao Wang ◽  
Jun Liang ◽  
Yang Liu ◽  
Jie Cai Han
Keyword(s):  
Stress Concentration ◽  
Grain Boundary ◽  
Stress Concentration Factor ◽  
Concentration Factor ◽  
Critical Stress ◽  
Local Stress ◽  
Viscosity Coefficient ◽  
Boundary Phase ◽  
Cavity Nucleation ◽  
Grain Sizes

A theoretical model considering the distribution of the grain sizes and grain-boundary ledges was developed for cavity nucleation in creeping ceramics containing viscous grain boundary phase. The critical stress involving the effects of various shapes of cavities and viscosity coefficient (η) for cavity nucleation was presented. Then, the local stress concentration factor concerning different distributions of grain-boundary ledges was calculated and discussed. The results showed that various shapes of cavities and η are not the main influencing factors on the critical stress. The stress concentration factor increases with the increase of grain-boundary ledge size or the density. Therefore, it would be liable to cause cavity nucleation at gain boundary when the density of grain-boundary ledges is high and the size is large.

Anisotropic Behaviour of Grain Boundaries

2005 ◽  
Vol 482 ◽  
pp. 63-70 ◽  
Author(s):  
Václav Paidar ◽  
Pavel Lejček
Keyword(s):  
Grain Boundary ◽  
Grain Boundaries ◽  
Polycrystalline Materials ◽  
Grain Boundary Engineering ◽  
Interfacial Dislocation ◽  
Special Character ◽  
Boundary Properties ◽  
Properties Of Materials ◽  
Boundary Classification ◽  
Boundary Chemistry

Grain boundaries are decisive for many properties of materials. Due to short-range stress field their influence is primarily based on their atomic structure. Special character of grain boundary properties related to their structure, follows from the nature of atomic arrangements in the boundary cores, from the interfacial dislocation content and from the boundary mobility. All those aspects of boundary behaviour are strongly influenced by the boundary chemistry including various segregation phenomena. Approaches to the boundary classification and the interpretation of recent experimental results are discussed in the context of the complex relationship between microstructure and material properties. Such findings are essential for Grain Boundary Engineering proposed to improve the performance of polycrystalline materials.

Characterization of Intergranular Phases in Doped Zirconia Polycrystals

1999 ◽  
Vol 589 ◽  
Author(s):  
N. D. Evans ◽  
P. H. Imamura ◽  
J. Bentley ◽  
M. L. Mecartney
Keyword(s):  
Grain Boundary ◽  
Grain Boundaries ◽  
Analytical Electron Microscopy ◽  
Tetragonal Zirconia ◽  
Barium Ions ◽  
Analytical Electron ◽  
Scanning Transmission ◽  
Triple Points ◽  
Boundary Chemistry

AbstractAnalytical electron microscopy at high spatial resolution in a scanning-transmission mode has been used to investigate the effects of glassy or crystalline material additions on grain boundary chemistry in yttria-stabilized zirconia polycrystals. Powders of additive phase were mixed into 3-mol% yttria-stabilized tetragonal zirconia polycrystals (‘3Y-TZP’) or 8-mol% yttria-stabilized cubic zirconia polycrystals (‘8Y-CSZ’). Zirconias processed without additive phases were also examinedWithout additives, grain boundaries were depleted in zirconium and enriched in yttrium. In 3Y-TZP with I wt% borosilicate glass, silicon was observed only at triple points, but not in grain boundaries. In 3Y-TZP with 1 wt% barium silicate glass, barium was observed both along grain boundaries and at triple points, whereas silicon was detected only within the triple points. This suggests either the composition of the additive phase at the grain boundary is different from that at the triple points, or that barium ions segregate to grain boundaries during processing. In 8Y-CSZ with I wt% silica, silicon was observed in grain boundaries by an EDS spatial differencing technique. In 8Y-CSZ with 10 wt% alumina, EDS revealed aluminum at all grain boundaries examined

Observation of grain boundary segregation in advanced ceramics using high-resolution imaging SIMS

1995 ◽  
Vol 53 ◽  
pp. 324-325
Author(s):  
R. Levi-Setti ◽  
K. K. Soni ◽  
J. M. Chabala ◽  
A. M. Thompson
Keyword(s):  
Grain Boundary ◽  
Grain Boundaries ◽  
High Spatial Resolution ◽  
Imaging Techniques ◽  
Boundary Segregation ◽  
Ion Microprobe ◽  
Broad Beam ◽  
Resolution Imaging ◽  
Boundary Chemistry

The significance of grain boundaries in controlling processing and properties of ceramics is widely acknowledged. Through the addition of suitable dopants to ceramics, their processability and properties can be improved. These dopants may segregate to grain boundaries, but the characterization of boundary chemistry is a challenging task. Studies of segregation phenomena require the application of high-lateralresolution techniques such as STEM/AEM or surface sensitive techniques such as AES, XPS. These techniques require rigorous sample preparation and have their limitations.The scanning ion microprobe is a powerful tool that has exhibited unprecedented potential in the characterization of grain boundaries in ceramics. When interfaced to a mass spectrometer (magnetic sector in our case), this instrument allows mapping of many trace elements at nanometer level in bulk specimens. The combination of excellent sensitivity and high spatial resolution enables direct imaging of grain boundary segregants. The results thus obtained are free from artifacts that typically complicate analysis with broad beam, non-imaging techniques.

An atom probe field ion microscope analysis of grain boundary chemistry in boron and carbon doped NiAl

1992 ◽  
Vol 50 (2) ◽  
pp. 1220-1221
Author(s):  
Raman Jayaram ◽  
M.K Miller
Keyword(s):  
Grain Boundary ◽  
Enrichment Factor ◽  
Grain Boundaries ◽  
Atom Probe ◽  
Probe Field ◽  
Carbon Doped ◽  
Boron Segregation ◽  
Microanalytical Technique ◽  
Microalloying Elements ◽  
Boundary Chemistry

The low temperature brittleness of nickel aluminides has been a serious impediment to their technological applications. A commonly employed technique to ductilize these materials involves the addition of suitable microalloying elements and correlating grain boundary chemistry with fracture mode. In the well documented case of Ni3Al, boron segregation to grain boundaries is accompanied by suppression of intergranular fracture and a significant increase in ductility. The high resolution microanalytical technique of atom probe field ion microscopy (APFIM) has been used in this study to analyze grain boundaries in order to characterize similar attempts to ductilize NiAl. APFIM specimens were prepared from tensile specimens of stoichiometric NiAl doped with either 0.04 or 0.12 at. % boron or 0.1 at % carbon, respectively. A field ion image of a grain boundary in a B-doped NiAl specimen is shown in Fig. 1. The brightly-imaging spots decorating the boundary were determined by atom probe analysis to be boron atoms. The boron enrichment factor at the boundary depends on the assumed thickness of the segregation as shown in Fig. 2 with an enrichment factor of ∼850 times for a monolayer coverage (i.e. 0.2 nm).

The Slip Transfer Process Through Grain Boundaries in HCP Ti

1993 ◽  
Vol 319 ◽  
Author(s):  
J. Shirokoff ◽  
I.M. Robertson ◽  
H.K. Birnbaum
Keyword(s):  
Grain Boundary ◽  
Slip System ◽  
Grain Boundaries ◽  
Slip Systems ◽  
Boundary Dislocation ◽  
Burgers Vector ◽  
Slip Transfer ◽  
Transmission Electron ◽  
Fcc Materials

AbstractInformation on the mechanisms of slip transfer across grain boundaries in an HCP α-Ti alloy has been obtained from deformation experiments performed In situ in the transmission electron microscope. Initially, lattice dislocations are accommodated within the grain boundary until a critical local dislocation density is reached. The boundary then responds by activating slip in the adjoining grain on the slip system experiencing the highest local resolved shear stress and producing the residual grain-boundary dislocation with the smallest Burgers vector. Slip on secondary slip systems may be initiated provided they reduce the magnitude of the Burgers vector of, or eliminate, the residual grainboundary dislocation. The selection rules used to predict the slip system activated by the grain boundary are the same as apply in ordered and disordered FCC materials.

scholarly journals On the Effect of Local Grain-Boundary Chemistry on the Macroscopic Mechanical Properties of a High Purity Y2O3-Al2O3-Containing Silicon Nitride Ceramic

2004 ◽  
Vol 839 ◽  
Author(s):  
A. Ziegler ◽  
J.M. McNaney ◽  
M. J. Hoffmann ◽  
R. O. Ritchie
Keyword(s):  
Mechanical Properties ◽  
Silicon Nitride ◽  
Grain Boundary ◽  
Oxygen Content ◽  
High Purity ◽  
Interfacial Structure ◽  
Crack Advance ◽  
Transgranular Fracture ◽  
Boundary Films ◽  
Boundary Chemistry

ABSTRACTThe effects of grain-boundary chemistry on the mechanical properties of a high-purity silicon nitride ceramics were investigated, with specific emphasis on the role of oxygen. Variations in the grain-boundary oxygen content, through control of oxidizing heat treatments and sintering additives, was found to result in a transition in fracture mechanism from transgranular to intergranular fracture, with an associated increase in fracture toughness. This phenomenon is correlated to an oxygen-induced change in grain-boundary chemistry that appears to affect fracture by “weakening” the interface, facilitating debonding and crack advance along the boundaries, thereby enhancing the toughness by grain bridging. It is concluded that if the oxygen content in the thin grain-boundary films exceeds a lower limit, which is ∼0.87 equiv% oxygen content, then the interfacial structure and bonding characteristics favor intergranular debonding during crack propagation; otherwise, transgranular fracture ensues, with consequent low toughness.

scholarly journals A correlation between grain boundary character and deformation twin nucleation mechanism in coarse-grained high-Mn austenitic steel

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Chang-Yu Hung ◽  
Yu Bai ◽  
Tomotsugu Shimokawa ◽  
Nobuhiro Tsuji ◽  
Mitsuhiro Murayama
Keyword(s):  
Grain Boundary ◽  
Grain Boundaries ◽  
Austenitic Steel ◽  
Deformation Twin ◽  
Local Stress ◽  
Nucleation Mechanism ◽  
Stacking Fault ◽  
Dislocation Dynamics ◽  
Coarse Grained ◽  
Twin Nucleation

AbstractIn polycrystalline materials, grain boundaries are known to be a critical microstructural component controlling material’s mechanical properties, and their characters such as misorientation and crystallographic boundary planes would also influence the dislocation dynamics. Nevertheless, many of generally used mechanistic models for deformation twin nucleation in fcc metal do not take considerable care of the role of grain boundary characters. Here, we experimentally reveal that deformation twin nucleation occurs at an annealing twin (Σ3{111}) boundary in a high-Mn austenitic steel when dislocation pile-up at Σ3{111} boundary produced a local stress exceeding the twining stress, while no obvious local stress concentration was required at relatively high-energy grain boundaries such as Σ21 or Σ31. A periodic contrast reversal associated with a sequential stacking faults emission from Σ3{111} boundary was observed by in-situ transmission electron microscopy (TEM) deformation experiments, proving the successive layer-by-layer stacking fault emission was the deformation twin nucleation mechanism, different from the previously reported observations in the high-Mn steels. Since this is also true for the observed high Σ-value boundaries in this study, our observation demonstrates the practical importance of taking grain boundary characters into account to understand the deformation twin nucleation mechanism besides well-known factors such as stacking fault energy and grain size.

Measurement of compositional changes accompanying solid-state transformations at grain boundaries in metals

1987 ◽  
Vol 45 ◽  
pp. 296-299
Author(s):  
Ernest L. Hall ◽  
Clyde L. Briant
Keyword(s):  
Solid State ◽  
Grain Boundary ◽  
Grain Boundaries ◽  
Precipitation Process ◽  
Second Phase ◽  
Slow Cooling ◽  
Collector Plate ◽  
Compositional Changes ◽  
Property Changes ◽  
Boundary Chemistry

In many multicomponent metallic systems, solid-state precipitation processes can occur upon slow cooling or isothermal aging of solutionized material. Frequently, the precipitates form at grain boundaries, which are preferred sites for the nucleation and growth of the second phase. The precipitates generally grow through a combination of matrix and grain boundary diffusion, in which the grain boundary acts as a collector plate for the delivery of the solute to the growing precipitate. The precipitation process is thus accompanied by significant changes in the chemistry of the grain boundary and matrix regions near the grain boundary. These grain boundary chemistry changes can have a profound effect on the macroscopic properties of the material, including corrosion resistance, strength, and ductility. In order to understand the mechanism associated with these property changes, it is necessary to obtain a complete and precise description of the magnitude and extent of the compositional changes which have occurred at the grain boundaries.

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