Influence of Compression Process on Optical Properties of PDA Langmuir-Blodgett Films

1991 ◽  
Vol 237 ◽  
Author(s):  
Chun-wei Yuan ◽  
Chun-lin Lu ◽  
Yong Liang ◽  
Ning Gu ◽  
Yu Wei

ABSTRACTIn performing compression-expansion-recompression process during preparation of diacetylene (DA) monolayer, the change in colour of polydiacetylene (PDA) LB films was observed and more ordered structure of the films was achieved. The effect on optical properties could be ascribed to better arrangement of DA monomer which favoured the formation of PDA films in blue-form in polymerization.

2004 ◽  
Vol 13 (03n04) ◽  
pp. 355-358 ◽  
Author(s):  
JUN KAWAMATA ◽  
SHOICHIRO HIRAKAWA ◽  
SEIJI TANI ◽  
YUICHIRO OGATA ◽  
AKIHIKO YAMAGISHI

We have prepared hybrid Langmuir–Blodgett (LB) films consisting of a clay single layer and a non-amphiphilic polar molecule, 2,5-bis(p-dimethylaminocinnamylidene)-cyclopentanone. LB films deposited on solid substrates were characterized by means of UV-vis absorption spectroscopy and optical second-harmonic generation (SHG) measurements.


2015 ◽  
Vol 17 (11) ◽  
pp. 7386-7394 ◽  
Author(s):  
Lasya Maganti ◽  
Madhuri Jash ◽  
Anju Nair ◽  
T. P. Radhakrishnan

Negatively charged metal nanoparticles assemble as chain networks through Langmuir–Hinshelwood kinetics on a Langmuir film of positively charged amphiphiles. The extension of the networks captured in Langmuir–Blodgett films is tuned by the deposition pressure.


1992 ◽  
Vol 247 ◽  
Author(s):  
J. H. Cheung ◽  
R. B. Rosner ◽  
M. F. Rubner

ABSTRACTThe fabrication, structure and electrical properties of new electrically conductive Langmuir-Blodgett (LB) films of polyaniline and polypyrrole have been investigated. Polyaniline in its emeraldine-base form was mixed with stearic acid (PAN-B/SA) to produce stable films at the air-water interface (5/1 or 10/1 mole ratio of PAN-B/SA). These films were then transferred into multilayer films which were found to exhibit conductivities of about 1 S/cm upon doping with hydrochloric acid. The alkyl chains of the stearic acid molecules were found to be distributed randomly throughout the LB film thereby exerting a minimal influence on the electrical properties of the polyaniline phase. In addition to this mixed monolayer approach, a novel method of fabricating highly conductive polypyrrole LB films has been developed. This method is based on the sequential exposure of ferric stéarate LB films to hydrogen chloride (HC1) gas and pyrrole vapor. Each of these two solid state reactions was found to impart dramatic chemical and structural changes to the film. Polypyrrole LB films with conductivities as high as 5 S/cm were produced via this process. The electrical and optical properties of films made by both techniques were examined in order to elucidate their structure/property relationships.


2009 ◽  
Vol 29 (6) ◽  
pp. 1714-1718
Author(s):  
刘云龙 Liu Yunlong ◽  
王文军 Wang Wenjun ◽  
高学喜 Gao Xuexi ◽  
李云 Li Yun ◽  
李慧 Li Hui ◽  
...  

2000 ◽  
Vol 68 (1-3) ◽  
pp. 203-209 ◽  
Author(s):  
R Rella ◽  
P Siciliano ◽  
F Quaranta ◽  
T Primo ◽  
L Valli ◽  
...  

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