Magnetic Field Dependence of Jc in A T1–1223 Wire; Presence of Pinning and Good Grain Boundary Connectivity.

1991 ◽  
Vol 235 ◽  
Author(s):  
Toshiya J. Doi ◽  
Toshihide Nabatame ◽  
Michiya Okada ◽  
Toyotaka Yuasa ◽  
Kazuhide Tanaka ◽  
...  

ABSTRACTThe existence of effective pinning in single T1-layer 1223 superconductors has been reported [1–3], as opposed to lower values in T1- and Bi-double layer systems, which is intimately related to their crystal structures. In order to investigate the possibility of T1–1223 being applied as a practical superconductor, tape shaped wires of the chemical composition (T10.5Pb0.51 (Sr0.8Ba0.2Ca2Cu3O9were prepared. Transport Jc of T1–1223 was measured to be 1.8 × 104 A/cm2 at 77K in the absence of a magnetic field. These results seem to imply that T1–1223 has, not only effective pinning because of having a more 3-dimensional vortex line lattice like YBa2Cu3O7, but also better grain boundary weak-link performance than YBa2Cu3O7. PresenT1y it appears that T1–1223 may be a superior choice to make better superconducting wire, because of these considerations and of the higher Tc of 120K.(T10.5Pb0.5)1Sr2CaCu2O7 (T1–1212) also seems to have effective pinning, as well as T1–1223, supporting the idea that shorter Cu-O plane spacing, or absence of thicker insulating region such as T12O2 or Bi2O2 double layer, are beneficial for effective pinning through facilitating a better 3D-like vortex line lattice [4, 5]. Our “1212” and “1223” samples are good counter examples to the 2D pancake-like vortex theory [6, 7].

Author(s):  
J.-Y. Wang ◽  
Y. Zhu ◽  
A.H. King ◽  
M. Suenaga

One outstanding problem in YBa2Cu3O7−δ superconductors is the weak link behavior of grain boundaries, especially boundaries with a large-angle misorientation. Increasing evidence shows that lattice mismatch at the boundaries contributes to variations in oxygen and cation concentrations at the boundaries, while the strain field surrounding a dislocation core at the boundary suppresses the superconducting order parameter. Thus, understanding the structure of the grain boundary and the grain boundary dislocations (which describe the topology of the boundary) is essential in elucidating the superconducting characteristics of boundaries. Here, we discuss our study of the structure of a Σ5 grain boundary by transmission electron microscopy. The characterization of the structure of the boundary was based on the coincidence site lattice (CSL) model.Fig.l shows two-beam images of the grain boundary near the projection. An array of grain boundary dislocations, with spacings of about 30nm, is clearly visible in Fig. 1(a), but invisible in Fig. 1(b).


Author(s):  
Z. L. Wang ◽  
C. L. Briant ◽  
J. DeLuca ◽  
A. Goyal ◽  
D. M. Kroeger ◽  
...  

Recent studies have shown that spray-pyrolyzed films of the Tl-1223 compound (TlxBa2Ca2Cu3Oy, with 0.7 < × < 0.95) on polycrystalline yttrium stabilized zirconia substrates can be prepared which have critical current density Jc near 105 A/cm2 at 77 K, in zero field. The films are polycrystalline, have excellent c-axis alignment, and show little evidence of weak-link behavior. Transmission electron microscopy (TEM) studies have shown that most grain boundaries have small misorientation angles. It has been found that the films have a nigh degree of local texture indicative of colonies of similarly oriented grains. It is believed that inter-colony conduction is enhanced by a percolative network of small angle boundaries at colony interfaces. It has also been found that Jc is increased by a factor of 4 - 5 after the films were annealed at 600 °C in oxygen. This study is thus carried out to determine the effect on grain boundary chemistry of the heat treatment.


1999 ◽  
Vol 41 (11) ◽  
pp. 1821-1823
Author(s):  
O. I. Datsko ◽  
V. I. Alekseenko ◽  
A. L. Brusova

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