Side Chain Polymers for Electro-Optic Applications

1991 ◽  
Vol 228 ◽  
Author(s):  
Ronald N. DeMartino ◽  
Diane E. Allen ◽  
Richard Keosian ◽  
Garo Khanarian ◽  
David R. Haas
Keyword(s):  
Mechanical Properties ◽  
Optical Activity ◽  
Molecular Basis ◽  
Molecular Design ◽  
Polymeric Materials ◽  
Side Chain ◽  
New Materials ◽  
Electro Optic ◽  
Recent Developments ◽  
Nlo Materials

ABSTRACTOrganic and polymeric materials have emerged in recent years as candidates for advanced device and systems applications. This interest has arisen from the promise of extraordinary optical, structural, and mechanical properties of certain organic materials, and from the fundamental success of molecular design performed to create new materials.Our approach to the problem is to develop an understanding of the molecular basis of non-linear optical activity, incorporate the most promising candidates into tractable polymers, and evaluate these materials in device format. This paper will review some of the recent developments in the NLO materials effort at Hoechst Celanese.

Mechanical Properties of Supramolecular Polymeric Materials Formed by Cyclodextrins as Host Molecules and Cationic Alkyl Guest Molecules on the Polymer Side Chain

2018 ◽  
Vol 51 (16) ◽  
pp. 6318-6326 ◽  
Author(s):  
Yoshinori Takashima ◽  
Kohei Otani ◽  
Yuichiro Kobayashi ◽  
Hikaru Aramoto ◽  
Masaki Nakahata ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Polymeric Materials ◽  
Side Chain ◽  
Guest Molecules ◽  
Host Molecules

Mechanical properties of supramolecular polymeric materials cross-linked by donor–acceptor interactions

2019 ◽  
Vol 55 (26) ◽  
pp. 3809-3812 ◽  
Author(s):  
Misaki Itano ◽  
Yuichiro Kobayashi ◽  
Yoshinori Takashima ◽  
Akira Harada ◽  
Hiroyasu Yamaguchi
Keyword(s):  
Mechanical Properties ◽  
Polymeric Materials ◽  
Side Chain ◽  
Donor And Acceptor ◽  
Aromatic Donor ◽  
Donor Acceptor ◽  
Acceptor Molecules

We prepare a tough elastomer with aromatic donor and acceptor molecules introduced on the same polymer side chain.

Thermally Stable Poled Polymers: Highly Efficient Heteroaromatic Chromophores In High Temperature Polyimides

1993 ◽  
Vol 328 ◽  
Author(s):  
Alex K-Y. Jen ◽  
K. Y. Wong ◽  
V. Pushkara Rao ◽  
K. Drost ◽  
Y. M. Cai ◽  
...  
Keyword(s):  
High Temperature ◽  
Elevated Temperature ◽  
Functional Groups ◽  
Optical Activity ◽  
Nonlinear Optical ◽  
Temporal Stability ◽  
Thermally Stable ◽  
Electro Optic ◽  
Recent Developments

ABSTRACTIn this paper, we report our recent developments in achieving thermally stable polyimides that possess large second order nonlinear optical activity. We have developed several classes of novel chromophores based on the combination of efficient thiophene conjugating units and novel electron-donating and electron-accepting functional groups. Through these developments, we have synthesized chromophores that possess non-resonant βμ values as high as 9,100 × 10−48 esu measured at 1.9 μm. These chromophores also possess improved thermal and chemical stabilities. The incorporation of these chromophores in high temperature polyimides produces E-O Materials with high linear electro-optic coefficients (in excess of 15 pm/V at 1.3 μm) and long-term temporal stability at an elevated temperature of 150°C for more than 800 hours.

Possibilities of using biodegradable polymeric materials in the agricultural sector

2020 ◽  
Vol 67 (2) ◽  
pp. 115-120
Author(s):  
Raisa A. Alekhina ◽  
Victoriya E. Slavkina ◽  
Yuliya A. Lopatina
Keyword(s):  
Mechanical Properties ◽  
Biodegradable Polymers ◽  
Biodegradable Polymer ◽  
Agricultural Sector ◽  
Polymeric Materials ◽  
Polymer Materials ◽  
Limiting Factors ◽  
Research Purpose ◽  
Biodegradable Materials ◽  
Advantages And Disadvantages

The article presents options for recycling polymers. The use of biodegradable materials is promising. This is a special class of polymers that can decompose under aerobic or anaerobic conditions under the action of microorganisms or enzymes forming natural products such as carbon dioxide, nitrogen, water, biomass, and inorganic salts. (Research purpose) The research purpose is in reviewing biodegradable materials that can be used for the manufacture of products used in agriculture. (Materials and methods) The study are based on open information sources containing information about biodegradable materials. Research methods are collecting, studying and comparative analysis of information. (Results and discussion) The article presents the advantages and disadvantages of biodegradable materials, mechanical properties of the main groups of biodegradable polymers. The article provides a summary list of agricultural products that can be made from biodegradable polymer materials. It was found that products from the general group are widely used in agriculture. Authors have found that products from a special group can only be made from biodegradable polymers with a controlled decomposition period in the soil, their use contributes to increasing the productivity of crops. (Conclusions) It was found that biodegradable polymer materials, along with environmental safety, have mechanical properties that allow them producing products that do not carry significant loads during operation. We have shown that the creation of responsible products (machine parts) from biodegradable polymers requires an increase in their strength properties, which is achievable by creating composites based on them. It was found that the technological complexity of their manufacture and high cost are the limiting factors for the widespread use of biodegradable polymers at this stage.

scholarly journals Anti-Inflammatory Properties of Injectable Betamethasone-Loaded Tyramine-Modified Gellan Gum/Silk Fibroin Hydrogels

Biomolecules ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 1456
Author(s):  
Isabel Matos Oliveira ◽  
Cristiana Gonçalves ◽  
Myeong Eun Shin ◽  
Sumi Lee ◽  
Rui Luis Reis ◽  
...  
Keyword(s):  
Rheumatoid Arthritis ◽  
Mechanical Properties ◽  
Silk Fibroin ◽  
Therapeutic Efficacy ◽  
Composite Structures ◽  
Gelation Time ◽  
Polymeric Materials ◽  
Gellan Gum ◽  
Traditional Use

Rheumatoid arthritis is a rheumatic disease for which a healing treatment does not presently exist. Silk fibroin has been extensively studied for use in drug delivery systems due to its uniqueness, versatility and strong clinical track record in medicine. However, in general, natural polymeric materials are not mechanically stable enough, and have high rates of biodegradation. Thus, synthetic materials such as gellan gum can be used to produce composite structures with biological signals to promote tissue-specific interactions while providing the desired mechanical properties. In this work, we aimed to produce hydrogels of tyramine-modified gellan gum with silk fibroin (Ty–GG/SF) via horseradish peroxidase (HRP), with encapsulated betamethasone, to improve the biocompatibility and mechanical properties, and further increase therapeutic efficacy to treat rheumatoid arthritis (RA). The Ty–GG/SF hydrogels presented a β-sheet secondary structure, with gelation time around 2–5 min, good resistance to enzymatic degradation, a suitable injectability profile, viscoelastic capacity with a significant solid component and a betamethasone-controlled release profile over time. In vitro studies showed that Ty–GG/SF hydrogels did not produce a deleterious effect on cellular metabolic activity, morphology or proliferation. Furthermore, Ty–GG/SF hydrogels with encapsulated betamethasone revealed greater therapeutic efficacy than the drug applied alone. Therefore, this strategy can provide an improvement in therapeutic efficacy when compared to the traditional use of drugs for the treatment of rheumatoid arthritis.

scholarly journals Recent Developments in Lignin- and Tannin-Based Non-Isocyanate Polyurethane Resins for Wood Adhesives—A Review

2021 ◽  
Vol 11 (9) ◽  
pp. 4242
Author(s):  
Manggar Arum Aristri ◽  
Muhammad Adly Rahandi Lubis ◽  
Sumit Manohar Yadav ◽  
Petar Antov ◽  
Antonios N. Papadopoulos ◽  
...  
Keyword(s):  
Automotive Industry ◽  
Polymeric Materials ◽  
Review Article ◽  
Future Perspectives ◽  
Wood Adhesives ◽  
Adhesion Properties ◽  
Lighting Industry ◽  
Renewable Natural Resources ◽  
Recent Developments ◽  
Strong Adhesion

This review article aims to summarize the potential of using renewable natural resources, such as lignin and tannin, in the preparation of NIPUs for wood adhesives. Polyurethanes (PUs) are extremely versatile polymeric materials, which have been widely used in numerous applications, e.g., packaging, footwear, construction, the automotive industry, the lighting industry, insulation panels, bedding, furniture, metallurgy, sealants, coatings, foams, and wood adhesives. The isocyanate-based PUs exhibit strong adhesion properties, excellent flexibility, and durability, but they lack renewability. Therefore, this study focused on the development of non-isocyanate polyurethane lignin and tannin resins for wood adhesives. PUs are commercially synthesized using polyols and polyisocyanates. Isocyanates are toxic, costly, and not renewable; thus, a search of suitable alternatives in the synthesis of polyurethane resins is needed. The reaction with diamine compounds could result in NIPUs based on lignin and tannin. The research on bio-based components for PU synthesis confirmed that they have good characteristics as an alternative for the petroleum-based adhesives. The advantages of improved strength, low curing temperatures, shorter pressing times, and isocyanate-free properties were demonstrated by lignin- and tannin-based NIPUs. The elimination of isocyanate, associated with environmental and human health hazards, NIPU synthesis, and its properties and applications, including wood adhesives, are reported comprehensively in this paper. The future perspectives of NIPUs’ production and application were also outlined.

scholarly journals A Broadband High-Diffraction-Efficiency Electro-Optic Bragg Deflector Based on Monolithic Dual-Grating Periodically-Poled Lithium Niobate

Photonics ◽  
2021 ◽  
Vol 8 (7) ◽  
pp. 242
Author(s):  
An-Chung Chiang ◽  
Yuan-Yao Lin ◽  
Shou-Tai Lin ◽  
Yen-Yin Lin
Keyword(s):  
Lithium Niobate ◽  
Wave Theory ◽  
Beam Radius ◽  
Acceptance Angle ◽  
Periodically Poled ◽  
Periodically Poled Lithium Niobate ◽  
Electro Optic ◽  
Recent Developments ◽  
Strong Focusing ◽  
Grating Design

Electro-optic (EO) Bragg deflectors have been extensively used in a variety of applications. Recent developments show that bandwidths and deflection efficiencies, as well as angular bandwidths, would significantly limit the utilization of EO Bragg deflectors, especially for applications which need strong focusing, such as intra-cavity applications. In this paper, we introduce a broadband EO Bragg deflector based on periodically-poled lithium niobate with a monolithic dual-grating design. We analyzed the deflection properties of this device by using a modified coupled wave theory and showed that this device can be still efficient for a small beam radius under strong focusing, whereas a single-grating one becomes very inefficient. Using a 1064-nm laser beam with a 100-μm beam radius, we obtained a 74% deflection efficiency with a 190-V bias voltage with a 0.5-mm-thick and 7.5-mm-long dual-grating sample. The acceptance angle for the Bragg condition of this device is as large as a few tens of mrad. The potential bandwidth of this device exceeds 500 nm if the proper operation region is chosen.

scholarly journals Mechanical and Morphological Properties of Bio-Phenolic/Epoxy Polymer Blends

Molecules ◽  
2021 ◽  
Vol 26 (4) ◽  
pp. 773
Author(s):  
Ahmad Safwan Ismail ◽  
Mohammad Jawaid ◽  
Norul Hisham Hamid ◽  
Ridwan Yahaya ◽  
Azman Hassan
Keyword(s):  
Mechanical Properties ◽  
Phase Separation ◽  
Polymer Blends ◽  
Epoxy Polymer ◽  
Flexural Modulus ◽  
Polymeric Materials ◽  
Morphological Properties ◽  
Comparison Results ◽  
Unique Material ◽  
Different Types

Polymer blends is a well-established and suitable method to produced new polymeric materials as compared to synthesis of a new polymer. The combination of two different types of polymers will produce a new and unique material, which has the attribute of both polymers. The aim of this work is to analyze mechanical and morphological properties of bio-phenolic/epoxy polymer blends to find the best formulation for future study. Bio-phenolic/epoxy polymer blends were fabricated using the hand lay-up method at different loading of bio-phenolic (5 wt%, 10 wt%, 15 wt%, 20 wt%, and 25 wt%) in the epoxy matrix whereas neat bio-phenolic and epoxy samples were also fabricated for comparison. Results indicated that mechanical properties were improved for bio-phenolic/epoxy polymer blends compared to neat epoxy and phenolic. In addition, there is no sign of phase separation in polymer blends. The highest tensile, flexural, and impact strength was shown by P-20(biophenolic-20 wt% and Epoxy-80 wt%) whereas P-25 (biophenolic-25 wt% and Epoxy-75 wt%) has the highest tensile and flexural modulus. Based on the finding, it is concluded that P-20 shows better overall mechanical properties among the polymer blends. Based on this finding, the bio-phenolic/epoxy blend with 20 wt% will be used for further study on flax-reinforced bio-phenolic/epoxy polymer blends.

scholarly journals A Review on Microstructural Features and Mechanical Properties of Wheels/Rails Cladded by Laser Cladding

Micromachines ◽  
2021 ◽  
Vol 12 (2) ◽  
pp. 152
Author(s):  
Xinlin Wang ◽  
Lei Lei ◽  
Han Yu
Keyword(s):  
Mechanical Properties ◽  
Service Life ◽  
Process Optimization ◽  
Laser Cladding ◽  
Future Development ◽  
Heat Affected Zone ◽  
Small Deformation ◽  
Microstructural Characteristics ◽  
Low Input ◽  
Recent Developments

The service life of rails would be remarkably reduced owing to the increase of axle load, which can induce the occurrence of damages such as cracks, collapse, fat edges, etc. Laser cladding, which can enhance the mechanical properties of the rail by creating a coating, has received great attention in the area of the rails due to the attractive advantages such as low input heat, small heat-affected zone, and small deformation. In this paper, recent developments in the microstructural characteristics and mechanical properties of a cladded layer on the rail are reviewed. The method of process optimization for enhancing the properties of a cladded layer are discussed. Finally, the trend of future development is forecasted.

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