Effects of Excimer Laser Ablation on the Surface of Hexagonal Boron Nitride

1990 ◽  
Vol 201 ◽  
Author(s):  
G. L. Doll ◽  
T. A. Perry ◽  
J. A. Sell

AbstractThe laser-induced changes in the hexagonal boron nitride targets that are used in the deposition of pulsed laser-deposited cubic boron nitride films are examined. Although the structure of the hexagonal boron nitride in the irradiated areas is unaltered, the surface morphology changes considerably. Boron-rich spheroids were found to cover the irradiated area. Their origin is consistent with the hydrodynamic sputtering of the hexagonal boron nitride targets, and a liberation of nitrogen atoms to the gas phase.

1994 ◽  
Vol 76 (5) ◽  
pp. 3088-3101 ◽  
Author(s):  
T. A. Friedmann ◽  
P. B. Mirkarimi ◽  
D. L. Medlin ◽  
K. F. McCarty ◽  
E. J. Klaus ◽  
...  

1997 ◽  
Vol 12 (2) ◽  
pp. 412-415 ◽  
Author(s):  
Stephen J. Harris ◽  
Anita M. Weiner ◽  
Gary L. Doll ◽  
Wen-Jin Meng

A BN film containing comparable amounts of sp2 and sp3 phases was subjected to a gas-phase chemical etch in a hot-filament environment containing 1% CH4 in H2. After a partial etch, examination by FTIR shows that the sp2 was preferentially etched, leaving a larger sp3 fraction than in the unetched film. The possibility that preferential etching could be used to increase the purity of cBN films is discussed.


2002 ◽  
Vol 11 (3-6) ◽  
pp. 1276-1280 ◽  
Author(s):  
Guenter Reisse ◽  
Steffen Weissmantel ◽  
Dirk Rost

2000 ◽  
Vol 70 (2) ◽  
pp. 197-201 ◽  
Author(s):  
S. Acquaviva ◽  
G. Leggieri ◽  
A. Luches ◽  
A. Perrone ◽  
A. Zocco ◽  
...  

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