Electrically Conductive Composite of Polyaniline and Poly(p-Phenylene-Terephthalamide)

1989 ◽  
Vol 173 ◽  
Author(s):  
Xian-Tong Bi ◽  
C. Wang ◽  
J. S. Bao

ABSTRACTThe improvement of the processibility and mechanical properties of poly-aniline (PAn) by processing a concentrated sulfuric acid solution of the mixture of chemically prepared conductive PAn powders and poly(p-phenylene-terephthalamide) (PPTA) in different weight ratios are presented.The concentrated sulfuric acid solution of PAn and PPTA were processed to films and threads, they are liquid crystalline conductive polymer composites, the electrical conductivities of the composites are between 10−4 -10−1 s/cm.PAn enhanced the tensile strength of PPTA, but does not effect the elongation. The morphology of the PPTA/PAn composite surfaces are fiberlike texture.

2000 ◽  
Vol 64 (5) ◽  
pp. 367-370
Author(s):  
Hideyuki Ogishi ◽  
Takeshi Suemitsu ◽  
Akira Takashima ◽  
Hyoe Ono ◽  
Hidemi Ukai ◽  
...  

1990 ◽  
Vol 43 (11) ◽  
pp. 1817 ◽  
Author(s):  
JFK Wilshire

The discovery of a new acid-catalysed monodentate N → C aromatic rearrangement, namely the phthalimidomethyl rearrangement, is reported. In this rearrangement, discovered during the reaction of N-hydroxymethylphthalimide with certain alkyl N-(4-nitrophenyl)carbamates in concentrated sulfuric acid solution, the phthalimidomethyl group migrates from its initial location on the nitrogen atom of the carbamate function to a carbon atom of the nitrophenyl group. Evidence, provided by an appropriate 'crossover' experiment, indicates that the rearrangement is intermolecular. Hindered rotation about the N(carbamoyl)-aryl bond of the N-phthalimidomethyl derivatives of both ethyl and methyl N-(2,4-dinitrophenyl)carbamate is reported.


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