Thermochemistry of the Amorphous System SiO2-GeO2: Comparision of Flame Hydrolysis Materials to High Temperature Fused Glasses

1989 ◽  
Vol 172 ◽  
Author(s):  
P. D. Maniar ◽  
A. Navrotsky ◽  
C. W. Draper
Keyword(s):  
High Temperature ◽  
Temperature Drop ◽  
Solution Calorimetry ◽  
Effect Of Temperature ◽  
Simple Manner ◽  
Tetrahedral Framework ◽  
Amorphous System ◽  
Preparation Conditions ◽  
Heats Of Mixing ◽  
Molten Lead

AbstractEnergetics and structure of germania doped silica prepared from high temperature melts and by flame hydrolysis were investigated using transposed temperature drop and solution calorimetry. Heat contents (H973-H298) are similar for first and second drops for the flame hydrolysis preforms reflecting the effect of temperature of deposition (1073 K) in creating a relaxed structure which is not easily rearranged. Heats of solution, at 973 K in molten lead borate, of fused glasses along the SiO2-GeO2 binary show ideal heats of mixing between the endmembers. This'indicates that fused glasses behave in a simple manner, with ideal substitution of Ge for Si in the tetrahedral framework. Flame hydrolysis samples (preform and annealed glasses) also show ideal heats of mixing. This suggests that the flame hydrolysis materials are energetically very similar to their bulk-melted counterparts. This insensitivity of energetics to preparation conditions is consistent with our previous studies on silica prepared at various temperatures [1].

scholarly journals High temperature wear assessment of mining machines operating tools

2020 ◽  
Vol 174 ◽  
pp. 03013
Author(s):  
Dmitrii Gromyka ◽  
Eldar Kremcheev
Keyword(s):  
High Temperature ◽  
Spontaneous Combustion ◽  
Process Development ◽  
Residual Life ◽  
Temperature Drop ◽  
Mineral Deposit ◽  
Effect Of Temperature ◽  
Wear Process ◽  
Mining Conditions ◽  
Machine Parts

Mining is widely associated with the use of a variety of mining machines for various duties, such as extraction, loading and transportation of rock. Due to prolonged use of machines, the amount of wear of operating tools and machine parts increases. This problem is especially acute for mining and loading machines used in excavation and reclamation, because the wear rate is increased on those duties. The development of wear process and evaluation of the residual life of operating tools of mining and loading machines is well studied in world practice. However, given the variety of climatic, geological and mining conditions, unique for each mineral deposit, we are facing difficulties in creating a comprehensive model of wear process development. In modern researches on this area such issues as estimation of operating tools residual life during intense wear under extreme conditions of high temperatures and sharp temperature drop are understudied. These conditions are typical for deposits of such minerals as coal and peat, which are especially prone to spontaneous combustion. This review discusses methods for assessing various wear mechanisms and the effect of temperature on the intensity of those processes, as well as methods to determine the residual life of operating tools of mining and loading machines working in high-temperature environment.

Energetics of Manganese Oxides

1995 ◽  
Vol 398 ◽  
Author(s):  
S. Fritsch ◽  
A. Navrotsky
Keyword(s):  
Phase Diagram ◽  
High Temperature ◽  
Enthalpy Of Formation ◽  
Manganese Oxides ◽  
Temperature Drop ◽  
Solution Calorimetry ◽  
Drop Calorimetry ◽  
Thermodynamic Cycles

ABSTRACTThe energetics of some manganese oxides : pyrolusite ΜnO2, bixbyite Μn2O3, hausmannite Μn3O4 and manganosite MnO were studied by transposed temperature drop calorimetry and high temperature drop solution calorimetry in molten 2PbOB2O3 at 977 K. The enthalpies of oxidation at 298 K in the Mn-O system, determined by appropriate thermodynamic cycles, are (in kJ/mol O2) : −441.4 ± 5.8 for the reaction 6 MnO + O2 -> 2 Mn3O4, −201.8 ± 8.7 for 4 Mn3O4 + O2 -> 6 Mn2O3 and −162.1 ± 7.2 for 2 Mn2O3 + O2 -> 4 ΜnO2 These values agree very well with previous data obtained by equilibrium ρθ2 measurements and indicate that direct calorimetrie measurements are well suited to obtain reliable enthalpy of formation data for oxides containing manganese in the 2+, 3+ and 4+ states. The phase diagram of the Mn-O system was calculated using these new values of enthalpies.

Enthalpy of Formation of Rare-earth Silicates Y2SiO5 and Yb2SiO5 and N-containing Silicate Y10(SiO4)6N2

1999 ◽  
Vol 14 (4) ◽  
pp. 1181-1185 ◽  
Author(s):  
Jian-Jie Liang ◽  
Alexandra Navrotsky ◽  
Thomas Ludwig ◽  
Hans J. Seifert ◽  
Fritz Aldinger
Keyword(s):  
Rare Earth ◽  
High Temperature ◽  
Enthalpy Of Formation ◽  
Temperature Drop ◽  
Solution Calorimetry ◽  
Enthalpies Of Formation ◽  
Binary Oxides ◽  
Standard Enthalpies Of Formation ◽  
Oxygen Gas ◽  
The Enthalpy Of Formation

The enthalpies of formation of two rare-earth silicates (Y2SiO5 and Yb2SiO5) and a N-containing rare-earth silicate Y10(SiO4)6N2 have been determined using high-temperature drop solution calorimetry. Alkali borate (52 wt% LiBO2·48 wt% NaBO2) solvent was used at 800 °C, and oxygen gas was bubbled through the melt. The nitrogen-containing silicate was oxidized during dissolution. The standard enthalpies of formation are for Y2SiO5, Yb2SiO5, and Y10(SiO4)6N2, respectively, –22868.54 ± 5.34, –22774.75 ± 8.21, and –14145.20 ± 16.48 kJ/mol from elements, and –52.53 ± 4.83, –49.45 6 ± 8.35, and –94.53 ± 11.66 kJ/mol from oxides (Y2O3 or Yb2O3, SiO2) and nitride (Si3N4). The silicates and N-containing silicate are energetically stable with respect to binary oxides and Si3N4, but the N-containing silicate may be metastable with respect to assemblages containing Y2SiO5, Si3N4, and SiO2. A linear relationship was found between the enthalpy of formation of a series of M2SiO5 silicates from binary oxides and the ionic potential (z/r) of the metal cation.

Thermodynamic properties of montechellite

2019 ◽  
Vol 64 (12) ◽  
pp. 1274-1280
Author(s):  
L. P. Ogorodova ◽  
Yu. D. Gritsenko ◽  
M. F. Vigasina ◽  
A. Yu. Bychkov ◽  
D. A. Ksenofontov ◽  
...  
Keyword(s):  
High Temperature ◽  
Gibbs Energy ◽  
Solution Calorimetry ◽  
Thermochemical Study ◽  
Gibbs Energy Of Formation ◽  
Calvet Microcalorimeter ◽  
Magnesium Orthosilicate ◽  
Calcium And Magnesium ◽  
The Enthalpy Of Formation ◽  
Energy Of Formation

A thermochemical study of natural calcium and magnesium orthosilicate ─ monticellite (Ca1.00Mg0.95)[SiO4] (Khabarovsk Territory, Russia) was carried out on the Tian-Calvet microcalorimeter. The enthalpy of formation from the elements fHоel(298.15 K) = -2238.4 4.5 kJ / mol was determined by the method of high-temperature melt solution calorimetry. The enthalpy and Gibbs energy of formation of monticellite of the theoretical composition of CaMg[SiO4] are calculated: fH0el(298.15 K) = -2248.4 4.5 kJ/mol and fG0el(298.15 K) = -2130.5 4.5 kJ/mol.

scholarly journals The modification effect of temperature on the relationship between air pollutants and daily incidence of influenza in Ningbo, China

2021 ◽  
Vol 22 (1) ◽  
Author(s):  
Rui Zhang ◽  
Yujie Meng ◽  
Hejia Song ◽  
Ran Niu ◽  
Yu Wang ◽  
...  
Keyword(s):  
Air Pollution ◽  
High Temperature ◽  
Air Pollutants ◽  
Meteorological Data ◽  
Effect Of Temperature ◽  
Distributed Lag ◽  
Modification Effect ◽  
Incidence Risk ◽  
The Impact ◽  
The Relationship

Abstract Background Although exposure to air pollution has been linked to many health issues, few studies have quantified the modification effect of temperature on the relationship between air pollutants and daily incidence of influenza in Ningbo, China. Methods The data of daily incidence of influenza and the relevant meteorological data and air pollution data in Ningbo from 2014 to 2017 were retrieved. Low, medium and high temperature layers were stratified by the daily mean temperature with 25th and 75th percentiles. The potential modification effect of temperature on the relationship between air pollutants and daily incidence of influenza in Ningbo was investigated through analyzing the effects of air pollutants stratified by temperature stratum using distributed lag non-linear model (DLNM). Stratified analysis by sex and age were also conducted. Results Overall, a 10 μg/m3 increment of O3, PM2.5, PM10 and NO2 could increase the incidence risk of influenza with the cumulative relative risk of 1.028 (95% CI 1.007, 1.050), 1.061 (95% CI 1.004, 1.122), 1.043 (95% CI 1.003, 1.085), and 1.118 (95% CI 1.028, 1.216), respectively. Male and aged 7–17 years were more sensitive to air pollutants. Through the temperature stratification analysis, we found that temperature could modify the impacts of air pollution on daily incidence of influenza with high temperature exacerbating the impact of air pollutants. At high temperature layer, male and the groups aged 0–6 years and 18–64 years were more sensitive to air pollution. Conclusion Temperature modified the relationship between air pollution and daily incidence of influenza and high temperature would exacerbate the effects of air pollutants in Ningbo.

Experimental results of the Li-Pb-Pt system obtained by the high temperature drop calorimetry

2021 ◽  
pp. 115824
Author(s):  
S. Terlicka ◽  
A. Dębski ◽  
W. Gąsior ◽  
A. Fornalczyk ◽  
M. Saternus
Keyword(s):  
High Temperature ◽  
Temperature Drop ◽  
Experimental Results ◽  
Drop Calorimetry

Effect of temperature on the microbial ecology of a hydrocarbon-contaminated Antarctic soil: Implications for high temperature remediation

2008 ◽  
Vol 53 (1) ◽  
pp. 115-129 ◽  
Author(s):  
Susan H. Ferguson ◽  
Shane M. Powell ◽  
Ian Snape ◽  
John A.E. Gibson ◽  
Peter D. Franzmann
Keyword(s):  
High Temperature ◽  
Microbial Ecology ◽  
Effect Of Temperature ◽  
Antarctic Soil
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