Polarized X-Ray Absorption Studies of Oxide Superconductors

1988 ◽  
Vol 143 ◽  
Author(s):  
E. Ercan Alp ◽  
S. M. Mini ◽  
M. Ramanathan ◽  
B. W. Veal ◽  
L. Soderholm ◽  
...  

AbstractPolarized X-ray absorption studies have been carried out at the Cu K-edge to study the effect of Sr doping in La2CuO4 and oxygen doping in YBa2Cu3O6+x. These measurements help to elucidate the transitions giving rise to the absorption edges. We offer an explanation of the polarization shifts of features in terms of the results of our embedded cluster calculations of electronic structure.

1991 ◽  
Vol 43 (9) ◽  
pp. 7263-7266 ◽  
Author(s):  
M. Abbate ◽  
F. M. F. de Groot ◽  
J. C. Fuggle ◽  
Y. J. Ma ◽  
C. T. Chen ◽  
...  

1987 ◽  
Vol 99 ◽  
Author(s):  
E. E. Alp ◽  
G. K. Shenoy ◽  
L. Soderholm ◽  
G. L. Goodman ◽  
D. G. Hinks ◽  
...  

ABSTRACTThe question of valence of Cu and rare-earth atoms in the newly discovered oxide superconductors with high transition temperatures is crucial to the understanding of their electronic structure. We have measured the X-Ray Absorption Near Edge Structure (XANES) of Cu K transition and Pr Ljjj transition to obtain information on the valence of Cu, and Pr in La2−xSrxCuO4 and Y1−xPrxBa2Cu3O7-δ. We will present the experimental results, compare them with calculations of absorption cross-section for model atomic clusters, and discuss the valence of Cu as a function of oxygen concentration.


2006 ◽  
Vol 243 (7) ◽  
pp. 1696-1700 ◽  
Author(s):  
J. I. Hwang ◽  
Y. Ishida ◽  
M. Kobayashi ◽  
Y. Osafune ◽  
T. Mizokawa ◽  
...  

2002 ◽  
Vol 09 (01) ◽  
pp. 387-391 ◽  
Author(s):  
A. J. NELSON ◽  
T. VAN BUUREN ◽  
C. BOSTEDT ◽  
K. I. SCHAFFERS ◽  
LOU TERMINELLO

X-ray photoemission and X-ray photoabsorption were used to study the composition and the electronic structure of ytterbium-doped strontium fluoroapatite (Yb:S-FAP). High resolution photoemission measurements on the valence band electronic structure were used to evaluate the density of occupied states of this fluoroapatite. Element-specific density of unoccupied electronic states in Yb:S-FAP was probed by X-ray absorption spectroscopy (XAS) at the Yb 4d ( N 4,5-edge), Sr 3d ( M 4,5-edge), P 2p ( L 2,3-edge), F 1s and O 1s (K-edges) absorption edges. These results provide the first measurements of the electronic structure and surface chemistry of this material.


2017 ◽  
Vol 46 (1) ◽  
pp. 102-125 ◽  
Author(s):  
Christina H. M. van Oversteeg ◽  
Hoang Q. Doan ◽  
Frank M. F. de Groot ◽  
Tanja Cuk

X-ray absorption studies of the geometric and electronic structure of primarily heterogeneous Co, Ni, and Mn based water oxidation catalysts are reviewed.


1992 ◽  
Vol 15 (3) ◽  
pp. 219-229 ◽  
Author(s):  
G. Meitzner ◽  
D. A. Fischer ◽  
J. H. Sinfelt

1988 ◽  
Vol 88 (1) ◽  
pp. 475-477 ◽  
Author(s):  
T. K. Sham ◽  
T. Ohta ◽  
T. Yokoyama ◽  
Y. Kitajima ◽  
M. Funabashi ◽  
...  

2015 ◽  
Vol 3 (16) ◽  
pp. 8613-8626 ◽  
Author(s):  
Ching-Hsiang Chen ◽  
Chun-Jern Pan ◽  
Wei-Nien Su ◽  
John Rick ◽  
Chih-Jen Wang ◽  
...  

Co helps maintain the lithium ions stably in the transition metal inter slabs and the surface electronic structure of oxygen ions is reversible during cycling between 4.6 V and 2.5 V.


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