Time-Resolved X-Ray Absorption Spectroscopy: Strengths and Limitations

1988 ◽  
Vol 143 ◽  
Author(s):  
A. Fontaine ◽  
E. Dartyge ◽  
J. P. Itie ◽  
A. Jucha ◽  
A. Polian ◽  
...  
Keyword(s):  
Absorption Spectroscopy ◽  
Materials Science ◽  
Energy Scale ◽  
Time Resolved ◽  
Decay Channels ◽  
X Ray ◽  
Exact Shape ◽  
Full Benefit ◽  
Short Time ◽  
X Ray Absorption

AbstractX-ray Absorption Spectroscopy has proved to be a powerful tool to elucidate a huge number of questions in materials science. Great interest exists in time-resolved experiments achieved with extreme energy resolution and energy scale stability to take a full benefit of the strong correlation between the stereochemical environment of the absorbing atom and the exact shape and position of the absorption edge.Fast energy dispersive X-ray spectroscopy allows in-situ observations with data collected in a short time. Nowadays the main limitation concerns very low-concentration samples since It is no longer possible to use the dispersive geometry because detection of the signal via the decay channels is no more possible.

X-Ray Absorption Spectroscopy as an in-situ Tool in Materials Science

1997 ◽  
Vol 502 ◽  
Author(s):  
T. Ressler ◽  
Joe Wong ◽  
W. Metz
Keyword(s):  
Absorption Spectroscopy ◽  
Materials Science ◽  
Ex Situ ◽  
Structural Studies ◽  
Time Resolved ◽  
X Ray ◽  
Complementary Techniques ◽  
X Ray Absorption ◽  
Established Technique

ABSTRACTIn addition to being an established technique for ex-situ structural studies, x-ray absorption spectroscopy (XAS) has recently been realized to be a powerful tool for in-situ time-resolved investigations in materials science. This paper describes two complementary techniques: quick-scanning EXAFS (QEXAFS) and energy-dispersive XAS (DXAS) which offer time resolution in the seconds and milliseconds range, respectively. Formation of a heterogeneous catalyst from a solid-state reaction of a precursor is presented as an example of a time-resolved XAS application.

scholarly journals A setup for ultrafast time-resolved x-ray absorption spectroscopy

2004 ◽  
Vol 75 (1) ◽  
pp. 24-30 ◽  
Author(s):  
Melanie Saes ◽  
Frank van Mourik ◽  
Wojciech Gawelda ◽  
Maik Kaiser ◽  
Majed Chergui ◽  
...  
Keyword(s):  
Absorption Spectroscopy ◽  
Time Resolved ◽  
X Ray ◽  
X Ray Absorption

scholarly journals Development of an experimental apparatus to observe ultrafast phenomena by tender X-ray absorption spectroscopy at PAL-XFEL

2022 ◽  
Vol 29 (1) ◽  
Author(s):  
Yujin Kim ◽  
Daewoong Nam ◽  
Rory Ma ◽  
Sangsoo Kim ◽  
Myung-jin Kim ◽  
...  
Keyword(s):  
Absorption Spectroscopy ◽  
Spectroscopic Technique ◽  
Ultrafast Dynamics ◽  
Electronic Information ◽  
Time Resolved ◽  
X Ray ◽  
Experimental Apparatus ◽  
Technical Achievement ◽  
X Ray Absorption ◽  
Pal Xfel

Understanding the ultrafast dynamics of molecules is of fundamental importance. Time-resolved X-ray absorption spectroscopy (TR-XAS) is a powerful spectroscopic technique for unveiling the time-dependent structural and electronic information of molecules that has been widely applied in various fields. Herein, the design and technical achievement of a newly developed experimental apparatus for TR-XAS measurements in the tender X-ray range with X-ray free-electron lasers (XFELs) at the Pohang Accelerator Laboratory XFEL (PAL-XFEL) are described. Femtosecond TR-XAS measurements were conducted at the Ru L 3-edge of well known photosensitizer tris(bipyridine)ruthenium(II) chloride ([Ru(bpy)3]2+) in water. The results indicate ultrafast photoinduced electron transfer from the Ru center to the ligand, which demonstrates that the newly designed setup is applicable for monitoring ultrafast reactions in the femtosecond domain.

scholarly journals Time-resolved X-ray absorption spectroscopy of infrared-laser-induced temperature jumps in liquid water

2009 ◽  
Vol 96 (1) ◽  
pp. 11-18 ◽  
Author(s):  
G. Gavrila ◽  
K. Godehusen ◽  
C. Weniger ◽  
E. T. J. Nibbering ◽  
T. Elsaesser ◽  
...  
Keyword(s):  
Absorption Spectroscopy ◽  
Liquid Water ◽  
Infrared Laser ◽  
Time Resolved ◽  
X Ray ◽  
Temperature Jumps ◽  
X Ray Absorption

scholarly journals Decomposing electronic and lattice contributions in optical pump – X-ray probe transient inner-shell absorption spectroscopy of CuO

2019 ◽  
Vol 216 ◽  
pp. 414-433 ◽  
Author(s):  
Johannes Mahl ◽  
Stefan Neppl ◽  
Friedrich Roth ◽  
Mario Borgwardt ◽  
Catherine Saladrigas ◽  
...  
Keyword(s):  
Heat Transport ◽  
Absorption Spectroscopy ◽  
Energy Deposition ◽  
Optical Pump ◽  
Time Resolved ◽  
X Ray ◽  
X Ray Absorption

Laser-induced energy deposition and heat transport in CuO is studied by picosecond time-resolved X-ray absorption spectroscopy.

scholarly journals Tandem X-ray absorption spectroscopy and scattering for in situ time-resolved monitoring of gold nanoparticle mechanosynthesis

2020 ◽  
Vol 56 (71) ◽  
pp. 10329-10332 ◽  
Author(s):  
Paulo F. M. de Oliveira ◽  
Adam A. L. Michalchuk ◽  
Ana Guilherme Buzanich ◽  
Ralf Bienert ◽  
Roberto M. Torresi ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Gold Nanoparticle ◽  
Absorption Spectroscopy ◽  
Mechanochemical Synthesis ◽  
Time Resolved ◽  
X Ray ◽  
X Ray Absorption

A new tandem approach combines XRD and XANES for time-resolved in situ monitoring of the mechanochemical synthesis of gold nanoparticles.

Applications of X-Ray Absorption Spectroscopy in Materials Science

2006 ◽  
pp. 15-30
Author(s):  
V. Briois ◽  
Ch. Giorgetti ◽  
F. Baudelet ◽  
A. M. Flank ◽  
M. S. Tokumoto ◽  
...  
Keyword(s):  
Absorption Spectroscopy ◽  
Materials Science ◽  
X Ray ◽  
X Ray Absorption

scholarly journals Tracing the 267 nm-Induced Radical Formation in Dimethyl Disulfide Using Time-Resolved X-ray Absorption Spectroscopy

2019 ◽  
Vol 10 (6) ◽  
pp. 1382-1387 ◽  
Author(s):  
Kirsten Schnorr ◽  
Aditi Bhattacherjee ◽  
Katherine J. Oosterbaan ◽  
Mickaël G. Delcey ◽  
Zheyue Yang ◽  
...  
Keyword(s):  
Absorption Spectroscopy ◽  
Dimethyl Disulfide ◽  
Radical Formation ◽  
Time Resolved ◽  
X Ray ◽  
X Ray Absorption
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