A Study of Structural Properties of the TiO2-NbO2 Solid Solution by Neutron Diffraction

1988 ◽  
Vol 138 ◽  
Author(s):  
Hisao Yamada ◽  
Raymond G. Teller ◽  
Inho Song
1990 ◽  
Vol 210 ◽  
Author(s):  
R.I. Smith ◽  
A.R. West

AbstractCrystallographic results on the Li4-3x(Al,Ga)xSiO4 solid solutions are reviewed. The six sets of sites available for Li+ ions fall into two groups. The ‘framework’ sites, which also contain the substitutional Al,Ga ions, appear to have little effect on conductivity. The ‘channel’sites contain varying amounts of Li+ ions and are responsible for the dramatic variations in conductivity with x. There is evidence for the presence of one—dimensional defects, comprising columns of ordered Li+ ions, in both the framework and channel sites. The relative numbers of these linear defects has a large bearing on the solid solution mechanism in the framework sites and their occurrence in the channel sites may be responsible for the low conductivity in stoichiometric Li4SiO4.


2003 ◽  
Vol 390 (3) ◽  
pp. 213-220 ◽  
Author(s):  
W. Wong-Ng ◽  
L.J. Swartzendruber ◽  
J.A. Kaduk ◽  
L.H. Bennett

1993 ◽  
Vol 73 (10) ◽  
pp. 6075-6077 ◽  
Author(s):  
Moshe Kuznietz ◽  
Gilles André ◽  
Françoise Bourée ◽  
Haim Pinto ◽  
Hanania Ettedgui ◽  
...  

2021 ◽  
Vol 6 ◽  
pp. 83-87
Author(s):  
A. A. Alekseev ◽  
◽  
S. S. Goncharov ◽  

It is found that the low-temperature decomposition of martensite in quenched medium-carbon steel occurs in two stages. In the first stage, the rate of decomposition is higher than that in the subsequent stage. Application of the neutron diffraction method allows the identification of two stages of transformation in the first stage of martensite decomposition. It is shown that the first stage is associated predominantly with carbon segregation at dislocations, and the second, with the outdiffusion of carbon from the supersaturated solid solution with the formation of dispersed particles of metastable carbides. It is shown that the change in the concentration of carbon and, accordingly, the degree of tetragonal lattice of martensite at aging and low tempering occurs to a certain limit, independent of the cooling rate during quenching and tempering temperature. This is due to the establishment of a relative equilibrium between a supersaturated solid solution and fine particles of metastable iron carbide. It is found that the determining process, which leads to a change in the microhardness the low-temperature decomposition, is the out diffusion of carbon from the supersaturated solid solution.


2010 ◽  
Vol 22 (12) ◽  
pp. 3589-3598 ◽  
Author(s):  
Yuanzhi Tang ◽  
F. Marc Michel ◽  
Lihua Zhang ◽  
Richard Harrington ◽  
John B. Parise ◽  
...  

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