Characterization of Bituminous, Intermediate-Level Waste Products

1988 ◽  
Vol 127 ◽  
Author(s):  
Z. Kopajtic ◽  
D. Laske ◽  
H. P. Linder ◽  
M. Mohos ◽  
M. Nellen ◽  
...  

ABSTRACTThe influence of γ-irradiation on the properties of two types of bituminous reprocessing waste has been studied. Standard test methods were adapted for use with radioactive samples. Measurements of penetration, gas generation, thermal stability and leaching of irradiated and non-irradiated samples have been compared.

2008 ◽  
Vol 606 ◽  
pp. 79-92 ◽  
Author(s):  
C.H. Hsueh

Although standard test methods for biaxial strength measurements of ceramics have been established and the corresponding formulas for relating the biaxial strength to the fracture load have been approved by American Society for Testing and Materials (ASTM) and International Organization for Standardization, respectively, they are limited to the case of monolayered discs. Despite the increasing applications of multilayered ceramics, characterization of their strengths using biaxial flexure tests has been difficult because the analytical description of the relation between the strength and the fracture load for multilayers subjected to biaxial flexure tests is unavailable until recently. Using ring-on-ring tests as an example, the closed-form solutions for stresses in (i) monolayered discs based on ASTM formulas, (ii) bilayered discs based on Roark’s formulas, and (iii) multilayered discs based on Hsueh et al.’s formulas are reviewed in the present study. Finite element results for ring-on-rings tests performed on (i) zirconia monolayered discs, (ii) dental crown materials of porcelain/zirconia bilayered discs, and (iii) solid oxide fuel cells trilayered discs are also presented to validate the closed-form solutions. With Hsueh et al.’s formulas, the biaxial strength of multilayered ceramics can be readily evaluated using biaxial flexure tests.


2019 ◽  
pp. 089270571987252
Author(s):  
AM Abd Elbary ◽  
MT Tammam

Thermal, electrical, as well as mechanical behavior of blends of polyamide 6/polystyrene (PA6/PS) (50/50 wt/wt%) loaded with different concentrations of lead dioxide (PbO2) were investigated for X-ray shielding. Thermal stability and hardness (shore D) of these composites are studied. Addition of PbO2 decreases the thermal stability of the prepared composites. Stability of thermal properties confirmed by determining the activation energy for the thermal decomposition of unfilled PA6/PS and filled composites according to the Horowitz and Metzger method. Dielectric properties of bulk PbO2 have been investigated as a function of frequency and temperature in the frequency range from 40 Hz to 5 × 106 Hz and in the temperature range from 293 K to 423 K. The characterization of the prepared composites is done using scanning electron microscope. With PbO2-loaded PA6/PS blends composites, the dielectric properties were significantly influenced by γ-irradiation effects that ε′ and [Formula: see text] values increase with radiation dose up to 100 kGy for samples loaded with PbO2. Linear attenuation coefficient μ and half-value layer (HVL) of all composites strongly depend on the concentration of the filler used and the applied voltage of X-ray machine. HVL of the obtained composites that loaded with 100 wt/wt% of PbO2 nearly 3 mm can be used as X-ray tube housing, equipment housings and castings, electronic devices protection, and so on.


Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2449
Author(s):  
Beata Kaczmarek-Szczepańska ◽  
Olha Mazur ◽  
Marta Michalska-Sionkowska ◽  
Krzysztof Łukowicz ◽  
Anna Maria Osyczka

In this study, hydrogels based on chitosan cross-linked by glyoxal have been investigated for potential medical applications. Hydrogels were loaded with tannic acid at different concentrations. The thermal stability and the polyphenol-releasing rate were determined. For a preliminary assessment of the clinical usefulness of the hydrogels, they were examined for blood compatibility and in the culture of human dental pulp cells (hDPC). The results showed that after immersion in a polyphenol solution, chitosan/glyoxal hydrogels remain nonhemolytic for erythrocytes, and we also did not observe the cytotoxic effect of hydrogels immersed in tannic acid (TA) solutions with different concentration. Tannic acid was successfully released from hydrogels, and its addition improved material thermal stability. Thus, the current findings open the possibility to consider such hydrogels in clinics.


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