Chemical Corrosion of Cogema Glass R7T7 in High Saline Brines

1987 ◽  
Vol 112 ◽  
Author(s):  
Werner Lutze ◽  
R. Müller ◽  
W. Montserrat
Keyword(s):  
Transport Process ◽  
Salt Dome ◽  
Deionized Water ◽  
Federal Republic Of Germany ◽  
Chemical Corrosion ◽  
Dome Formation ◽  
Corrosion Rates ◽  
Different Temperatures ◽  
Term Data

AbstractIn the Federal Republic of Germany, the salt dome formation at Gorleben has been selected as a possible site for final disposal of HLW. The waste form will be borosilicate glass, e. g. the French Cogema glass R7T7. The corrosion of this glass has been investigated in three reference salt brines (brine 1: high Mg, brine 2: Ca and Mg, and brine 3: high Na) at three different temperatures, 110°, 150°, and 190°C and three S/V ratios, 10, 100, and 1000m−1. Results are presented for brine 1 and are compared qualitatively with those obtained for the other brines. As in deionized water and pure NaCl, the corrosion rate decreases when silica saturation is approached, but the reaction does not cease. The data after silica saturation were used to calculate upper limiting, i. e. time-independent corrosion rates. The long-term data indicate that a transport process through the growing surface layer may become rate controlling, and that the rate may further decrease after silica saturation.

Comparative Labelling and Biokinetic Studies of 99mTc-EDTA(Sn) and 99mTc-DTPA(Sn)

1977 ◽  
Vol 16 (01) ◽  
pp. 30-35 ◽  
Author(s):  
N. Agha ◽  
R. B. R. Persson
Keyword(s):  
Complex Formation ◽  
Significant Influence ◽  
Room Temperature ◽  
Ph Value ◽  
Maximum Activity ◽  
Reduction Step ◽  
Labelling Yield ◽  
Different Temperatures ◽  
Kinetics Of

SummaryGelchromatography column scanning has been used to study the fractions of 99mTc-pertechnetate, 99mTcchelate and reduced hydrolyzed 99mTc in preparations of 99mTc-EDTA(Sn) and 99mTc-DTPA(Sn). The labelling yield of 99mTc-EDTA(Sn) chelate was as high as 90—95% when 100 μmol EDTA · H4 and 0.5 (Amol SnCl2 was incubated with 10 ml 99mTceluate for 30—60 min at room temperature. The study of the influence of the pH-value on the fraction of 99mTc-EDTA shows that pH 2.8—2.9 gave the best labelling yield. In a comparative study of the labelling kinetics of 99mTc-EDTA(Sn) and 99mTc- DTPA(Sn) at different temperatures (7, 22 and 37°C), no significant influence on the reduction step was found. The rate constant for complex formation, however, increased more rapidly with increased temperature for 99mTc-DTPA(Sn). At room temperature only a few minutes was required to achieve a high labelling yield with 99mTc-DTPA(Sn) whereas about 60 min was required for 99mTc-EDTA(Sn). Comparative biokinetic studies in rabbits showed that the maximum activity in kidneys is achieved after 12 min with 99mTc-EDTA(Sn) but already after 6 min with 99mTc-DTPA(Sn). The long-term disappearance of 99mTc-DTPA(Sn) from the kidneys is about five times faster than that for 99mTc-EDTA(Sn).

Heat wave effects on biomass and vegetative growth of macrophytes after long-term adaptation to different temperatures: a mesocosm study

2015 ◽  
Vol 66 (3) ◽  
pp. 265-274 ◽  
Author(s):  
Y Cao ◽  
ÉM Neif ◽  
W Li ◽  
J Coppens ◽  
N Filiz ◽  
...  
Keyword(s):  
Heat Wave ◽  
Vegetative Growth ◽  
Wave Effects ◽  
Different Temperatures

Hydrogeological responses in tropical mountainous springs

2019 ◽  
Author(s):  
Ricardo Sánchez-Murillo
Keyword(s):  
Costa Rica ◽  
Isotope Composition ◽  
Central Valley ◽  
Distribution Functions ◽  
Geochemical Composition ◽  
Transit Times ◽  
Management Plans ◽  
Best Fit ◽  
Term Data

This study presents a hydrogeochemical analysis of spring responses (2013-2017) in the tropical mountainous region of the Central Valley of Costa Rica. The isotopic distribution of δ18O and δ2H in rainfall resulted in a highly significant meteoric water line: δ2H = 7.93×δ18O + 10.37 (r2=0.97). Rainfall isotope composition exhibited a strong dependent seasonality. The isotopic variation (δ18O) of two springs within the Barva aquifer was simulated using the FlowPC program to determine mean transit times (MTTs). Exponential-piston and dispersion distribution functions provided the best-fit to the observed isotopic composition at Flores and Sacramento springs, respectively. MTTs corresponded to 1.23±0.03 (Sacramento) and 1.42±0.04 (Flores) years. The greater MTT was represented by a homogeneous geochemical composition at Flores, whereas the smaller MTT at Sacramento is reflected in a more variable geochemical response. The results may be used to enhance modelling efforts in central Costa Rica, whereby scarcity of long-term data limits water resources management plans.

Morphometric studies of artemia males from different populations of the Altai region

2020 ◽  
pp. 28-38
Author(s):  
L. Vesnina ◽  
G. Lukerina ◽  
T. Ronzhina ◽  
A. Savos’kin ◽  
D. Surkov
Keyword(s):  
Sexual Dimorphism ◽  
Hydrogen Index ◽  
Morphometric Parameters ◽  
Altai Region ◽  
Sexual Structure ◽  
Different Populations ◽  
Artemia Population ◽  
Term Data ◽  
Brine Salinity

The long-term data from morphometric studies of Artemia males from bisexual and parthenogenetic populations from hyperhaline reservoirs of the Altai region (Bolshoe Yarovoe Lake, Maloe Shklo Lake, and the Tanatar Lakes system) is analyzed in this paper. The description of signs of sexual dimorphism and sexual structure in different populations is given. The influence of brine salinity and hydrogen index on morphometric parameters of males was analyzed. There are differences in the sexual structure of the Artemia population: in the lakes Maloe Shklo and the thanatar system, the populations are bisexual (the share of males is 28.5 — 75.0 %), in the lake Bolshoe yarovoe — parthenogenetic (the share of males on average does not exceed 3 %). At the same time, sexual dimorphism is typical for both types of populations: females are larger than males, males have a larger head (the distance between the eyes is greater by 15.5 %, the diameter of the eye is 26.1 %, the length of the antenna is 22.3 %) and a larger number of bristles (36.1 %). The greatest variability is observed in the parameters of the Furka structure associated with the salinity of water by feedback and the pH — line indicator. Significant differences between the samples of males were revealed. The largest number of significant differences in morphometric indicators was found between samples of males from bisexual populations (lake thanatar and lake Maloe Shklo), the smallest — between males from the parthenogenetic population of lake Bolshoe yarovoe and males from lake Maloe Shklo.

Diel, lunar and seasonal vertical migration in the deep western Gulf of Mexico evidenced from a long-term data series of acoustic backscatter

2021 ◽  
pp. 102562
Author(s):  
Laura Ursella ◽  
Sara Pensieri ◽  
Enric Pallàs-Sanz ◽  
Sharon Z. Herzka ◽  
Roberto Bozzano ◽  
...  
Keyword(s):  
Gulf Of Mexico ◽  
Vertical Migration ◽  
Acoustic Backscatter ◽  
Data Series ◽  
Term Data

scholarly journals Long-Term Stability of Different Kinds of Gas Nanobubbles in Deionized and Salt Water

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1808
Author(s):  
Yali Zhou ◽  
Zhenyao Han ◽  
Chunlin He ◽  
Qin Feng ◽  
Kaituo Wang ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Bubble Size ◽  
Ostwald Ripening ◽  
Salt Water ◽  
Dlvo Theory ◽  
Deionized Water ◽  
Hydrodynamic Cavitation ◽  
Term Stability ◽  
Long Term Stability

Nanobubbles have many potential applications depending on their types. The long-term stability of different gas nanobubbles is necessary to be studied considering their applications. In the present study, five kinds of nanobubbles (N2, O2, Ar + 8%H2, air and CO2) in deionized water and a salt aqueous solution were prepared by the hydrodynamic cavitation method. The mean size and zeta potential of the nanobubbles were measured by a light scattering system, while the pH and Eh of the nanobubble suspensions were measured as a function of time. The nanobubble stability was predicted and discussed by the total potential energies between two bubbles by the extended Derjaguin–Landau–Verwey–Overbeek (DLVO) theory. The nanobubbles, except CO2, in deionized water showed a long-term stability for 60 days, while they were not stable in the 1 mM (milli mol/L) salt aqueous solution. During the 60 days, the bubble size gradually increased and decreased in deionized water. This size change was discussed by the Ostwald ripening effect coupled with the bubble interaction evaluated by the extended DLVO theory. On the other hand, CO2 nanobubbles in deionized water were not stable and disappeared after 5 days, while the CO2 nanobubbles in 1 mM of NaCl and CaCl2 aqueous solution became stable for 2 weeks. The floating and disappearing phenomena of nanobubbles were estimated and discussed by calculating the relationship between the terminal velocity of the floating bubble and bubble size.

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