Effects of Radiation on the Oxidation Potential of Salt Brine

1987 ◽  
Vol 112 ◽  
Author(s):  
W. J. Gray

AbstractTwo different types of experiments have shown that alpha and gamma radiation each increase the redox potential of salt brines. Other experiments have shown that the decrease in potential indicated by platinum electrodes in irradiated brines is due to the response of the electrodes to the hydrogen generated from the resulting water decomposition. Platinum electrodes indicated no change in redox potential of solutions containing equimolar concentrations of K3Fe(CN)5 and K4Fe(CN)5 when they were gamma irradiated in quartz containers; when stainless steel containers were used, the solutions reacted with the stainless steel but gamma radiation had no significant effect on that reaction or the solution composition. A gamma radiation dose rate of 2.4 × 104 rad/h measurably increased the uniform corrosion rate of mild steel in salt brines at 75°C, but at 150°C the increased thermal corrosion rate obscured any effect of even higher gamma radiation dose rates.

2017 ◽  
Vol 156 ◽  
pp. 00006
Author(s):  
A. Izham ◽  
A.T. Ramli ◽  
W.M. Saridan Wan Hassan ◽  
H.N. Idris ◽  
N.A. Basri

2021 ◽  
Author(s):  
Urmas Hõrrak ◽  
Xuemeng Chen ◽  
Kristo Hõrrak ◽  
Uko Rand ◽  
Kaupo Komsaare ◽  
...  

<p>The SMEAR Estonia station (58.277663 N, 27.308266 E, 36 m a.s.l.) was established in south-east of Estonia at the Järvselja Experimental Forestry in 2012 to investigate the atmosphere-biosphere interactions and atmospheric aerosol formation and growth.</p><p>In summer 2019, the gamma-radiation monitor GammaTRACER XL2-3 (Saphymo GmbH) was set up at Järvselja station and the rain sensor DRD11A (Vaisala Oyj) in autumn 2019. These devices enable to measure the gamma-radiation dose rate and precipitation intensity, which affect the ionization rate of atmospheric air close to ground, with high accuracy and time resolution, and complement our measurement system of atmospheric ions and aerosol particles.</p><p>The gamma-radiation dose rate measurements at about 1.2 m above the ground reveled on relatively steady background about 70 nSv/h occasional events with increase up to about 110 nSv/h, which correlated well with rainfall intensity. Commonly such events last 3-4 hours, but in specific meteorological situation with continuous long-lasting rain and air mass movement from southerly directions the effect can last 2-3 days, resulting in gradual increase in gamma-radiation dose rate level during about 24 h.</p><p>Such a phenomenon is known to occur due to wet deposition of radioactive aerosol particles during rain, namely due to the radon (<sup>222</sup> Rn) short-lived daughter progeny products (Po-218, Pb-214, Bi-214) attached to atmospheric aerosol particles. The radon (<sup>222</sup> Rn) daughter progeny involvement is confirmed by simultaneous gamma-spectrometric measurements with SARA AGS711F (Envinet GmbH) at Tõravere station (58° 15' 52,9" N, 26° 27' 42,1", 72 m), located about 50.3 km west from the Järvselja SMEAR station. The gamma dose rates showed very similar temporal behavior when both stations were affected by the same air mass with precipitation zone passing over the stations.</p><p>To our best knowledge, the details of rain-induced enhancement of gamma-radiation dose rate and atmospheric processes behind the phenomenon are not well known and are worth future investigations. The events of rain induced gamma-radiation dose rate enhancement at Järvselja SMEAR and Tõravere station are analyzed and discussed in more detail in the presentation and the spatial representativity of the phenomenon is estimated based on the gamma-radiation monitoring network data of Estonian Early Warning System.</p>


2014 ◽  
Vol 135 ◽  
pp. 67-74 ◽  
Author(s):  
M.S.M. Sanusi ◽  
A.T. Ramli ◽  
H.T. Gabdo ◽  
N.N. Garba ◽  
A. Heryanshah ◽  
...  

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