Wipp Site Studies: Secondary Selenite Veins in the Rustler Formation and Dewey Lake Red Beds

1987 ◽  
Vol 112 ◽  
Author(s):  
D. G. Brookins ◽  
S. J. Lambert
Keyword(s):  
Surface Water ◽  
Trace Element Data ◽  
Isotopic Data ◽  
Red Beds ◽  
Rock Interaction ◽  
Near Surface ◽  
Secondary Sources ◽  
Isotopic Compositions ◽  
Isotopic Studies ◽  
Water Rock Interaction

AbstractDefense-generated transuranic (TRU) waste will be stored at WIPP in the bedded halite of the Salado Formation (Permian), which is overlain by the impure Permian evaporites of the Rustler Formation and the Dewey Lake Red Beds. Both the Rustler and Dewey Lake contain abundant to less common secondary selenite veins of uncertain origin, and dissolution zones occur in the Rustler. The Rustler Formation also contains two dolomite aquifers, the Magenta and Culebra members. The purpose of this study is to determine whether vein selenite is locally derived, or has been introduced in moving groundwater solutions. We have used Sr isotopic studies and REE, U and other trace element data to address the problem. The Sr isotopic data show that neither the Salado nor Rustler anhydrites have exchanged with secondary sources of Sr, and this is supported by the REE and U data. Further, selenite veins from the Rustler possess Sr isotopic compositions identical to the Rustler, indicating local origin, and this is also supported by the U and REE data. Selenite veins from the Dewey Lake Red Beds possess Sr isotopic compositions closer to surface caliche deposits, and may contain near-surface derived Sr. U and REE data show more scatter and evidence for extrinsic sources than the vein/host-rock pairs from the Rustler. Sr isotopic compositions of the Magenta and Culebra indicate that the Magenta has undergone less water/rock interaction than the Culebra. Collectively, the data argue for more possible surface or near-surface water/rock interactions in the Dewey Lake Red Beds than in the Rustler Formation; such interactions in the Salado Formation have been minimal.

Variation in kaolinite morphology with growth temperature in isotopically mixed pore-fluids, Brent Group, UK North Sea

Clay Minerals ◽  
1994 ◽  
Vol 29 (4) ◽  
pp. 591-608 ◽  
Author(s):  
M. Osborne ◽  
R. S. Haszeldine ◽  
A. E. Fallick
Keyword(s):  
Meteoric Water ◽  
Pore Space ◽  
Pore Waters ◽  
The West ◽  
Rock Interaction ◽  
Isotopic Studies ◽  
Reservoir Sandstones ◽  
Oxygen Isotopic ◽  
Low Degrees ◽  
Water Rock Interaction

AbstractDiagenetic kaolinite in reservoir sandstones of the Brent Group precipitated following the dissolution of detrial feldspar. Two distinct morphologies of kaolinite occur: (1) early diagenetic vermiform kaolinite which is often associated with expanded detrital micas; (2) later diagenetic ‘blocky’ kaolinite. Combined hydrogen and oxygen isotopic studies suggest that vermiform kaolinite precipitated at 25–50°C, and blocky kaolinite at 50–80°C, from pore-waters of a similar isotopic composition (δ18O = −6.5 to −3.5‰). These pore-waters are interpreted to be either a mixture of meteoric and compactional waters, or alternatively a meteoric water that had evolved isotopically due to water-rock interaction. Kaolinite precipitation occurred predominantly during the late Cretaceous to early Eocene. Influx of meteoric water into the Brent Group, probably occurred during the Palaeocene. Fluid flow across the entire basin was driven by a hydrostatic head on the East Shetland Platform palaeo-landmass to the west. The development of the two kaolinite morphologies is possibly related to the degree of supersaturation at the time of precipitation. At low degrees of supersaturation, vermiform kaolinite precipitated slowly upon detrital mica surfaces. Blocky kaolinite precipitated more rapidly into open pore-space at higher degrees of supersaturation. Precipitation of blocky kaolinite was perhaps triggered by the decay of oxalate.

scholarly journals Possible Hydrochemical Processes Influencing Dissolved Solids in Surface Water and Groundwater of the Kaidu River Basin, Northwest China

Water ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 467
Author(s):  
Dalong Li ◽  
Haiyan Chen ◽  
Shaofeng Jia ◽  
Aifeng Lv
Keyword(s):  
Surface Water ◽  
River Basin ◽  
Human Activities ◽  
Hydrochemical Characteristics ◽  
Dissolved Solids ◽  
Rock Interaction ◽  
Hydrochemical Processes ◽  
Type Water ◽  
Kaidu River ◽  
Water Rock Interaction

Hydrochemical processes under intense human activities were explored on the basis of the hydrochemical characteristics of 109 surface water samples and 129 groundwater samples collected during August 2015 to September 2016, in the Kaidu River Basin. Results obtained in this study indicated that the water in the basin was neutral to slightly alkaline with low total dissolved solids. Rock weathering and evaporation controlled the natural hydrochemical mechanisms. Mountain groundwater and stream water were dominated by Ca2+-HCO3− type water, whereas the plains groundwater was dominated by mixed type water. The results of principal component analysis demonstrated that water-rock interaction and human activity explained 71.6% and 12.9% of surface water hydrochemical variations, respectively, and 75.1% and 14.2% of groundwater hydrochemical variations, respectively. Sulfate, chloride, and carbonate weathering were the major water-rock interaction processes. Livestock farming and agricultural activities were the primary human activities influencing the water hydrochemistry. In addition, cation exchange is another important process influencing the hydrochemical characteristics in the study area. This study would be helpful in forecasting of water quality in arid areas.

scholarly journals Contamination risk assessment of the Transboundary Zeravshan River using chemical and isotopic studies

2019 ◽  
Vol 98 ◽  
pp. 07021
Author(s):  
Parviz Normatov ◽  
Inom Normatov
Keyword(s):  
River Water ◽  
Small Rivers ◽  
Rock Interaction ◽  
Low Salinity ◽  
Isotopic Studies ◽  
Rain Events ◽  
Isotope Analyses ◽  
Dissolution Of Minerals ◽  
Water Rock Interaction ◽  
Water Dissolution

The results of chemical and isotope analyses of water of the Zeravshan River are presented. Results show that the low salinity of the river water in the upstream reach is formed mainly by water dissolution of minerals in natural rocks, i.e. the existence of a water-rock interaction process. The detection of heavy cations in the composition of the river water is due to their transport long distances in the form of microparticles by wind and accumulation in snow cover and glaciers. During the melting of snow and glaciers, and during rain events, pollutants are carried by streams, small rivers, and finally by Zeravshan River that distributes the pollutants over long distances.

scholarly journals Isotopic composition and elemental concentrations in groundwater in the Kuiseb Basin and the Cuvelai-Etosha Basin, Namibia

2018 ◽  
Vol 378 ◽  
pp. 93-98
Author(s):  
Nnenesi A. Kgabi ◽  
Eliot Atekwana ◽  
Johanna Ithindi ◽  
Martha Uugwanga ◽  
Kay Knoeller ◽  
...  
Keyword(s):  
Surface Water ◽  
Meteoric Water ◽  
Environmental Tracers ◽  
Rock Interaction ◽  
Water Line ◽  
Meteoric Water Line ◽  
Groundwater Aquifer ◽  
Groundwater Samples ◽  
Water Rock Interaction

Abstract. We assessed environmental tracers in groundwater in two contrasting basins in Namibia; the Kuiseb Basin, which is a predominantly dry area and the Cuvelai-Etosha Basin, which is prone to alternating floods and droughts. We aimed to determine why the quality of groundwater was different in these two basins which occur in an arid environment. We analysed groundwater and surface water for the stable isotope ratios of hydrogen (δ2H) and oxygen (δ18O) by cavity ring-down spectroscopy and metals by inductively coupled plasma mass spectrometry. The δ2H and δ18O of surface water in the Cuvelai-Etosha Basin plot on an evaporation trend below the global meteoric water line (GMWL) and the local meteoric water line (LMWL). The δ2H and δ18O of some groundwater samples in the Cuvelai-Etosha Basin also plot on the evaporation trend, indicating recharge by evaporated rain or evaporated surface water. In contrast, the δ2H and δ18O of groundwater samples in the Kuiseb Basin plot mostly along the GMWL and the LMWL, indicating direct recharge from unevaporated rain or unevaporated surface water. Fifty percent of groundwater samples in the Cuvelai-Etosha Basin was potable (salinity < 1 ppt) compared to 79 % in the Kuiseb Basin. The high salinity in the groundwater of the Cuvelai-Etosha Basin does not appear to be caused by evaporation of water (evapo-concentration) on surface prior to groundwater recharge, but rather by the weathering of the Kalahari sediments. The low salinity in the Kuiseb Basin derives from rapid recharge of groundwater by unevaporated rain and limited weathering of the crystalline rocks. The order of abundance of cations in the Kuiseb Basin is Na > K > Ca > Mg vs. Na > Mg > Ca > K for the Cuvelai-Etosha Basin. For metals in the Kuiseb Basin the order of abundance is Fe > Al > V > As > Zn vs. Al > Fe > V> As > Zn for the Cuvelai-Etosha Basin. The relative abundance of cations and metals are attributed to the differences in geology of the basins and the extent of water-rock interaction. Our results show that the quality of groundwater in Cuvelai-Etosha Basin and Kuiseb Basin which vary in the extent of aridity, is controlled by the extent of water-rock interaction at the surface and in the groundwater aquifer.

Rhyolites as probes of the crust: examples from Tertiary volcanism in Arizona, southwestern U.S.A.

1992 ◽  
Vol 83 (1-2) ◽  
pp. 347-359 ◽  
Author(s):  
Sonia Esperança ◽  
Thomas C. Moyer
Keyword(s):  
Colorado Plateau ◽  
Basin And Range ◽  
Crustal Extension ◽  
Isotopic Data ◽  
Crustal Component ◽  
Isotopic Compositions ◽  
Isotopic Studies ◽  
High Silica ◽  
End Members ◽  
Central Arizona

ABSTRACTGeochemical and isotopic data obtained from three bimodal basalt-rhyolite fields in west-central Arizona point to significant variation in the sources of the siliceous products despite petrological similarities between them. The studied fields, which straddle the boundary between the Basin and Range and Colorado Plateau physiographic provinces, include Castaneda Hills (CH) in the Basin and Range, Kaiser Spring (KS) in the Transition Zone, and Mount Floyd (MF) in the Colorado Plateau. Two types of rhyolite (high-silica [HSR] and low-silica [LSR]) occur as lavas in the KS and MF fields, whereas all analysed CH samples are HSR. These lavas generally post-date low-angle extension of the Basin and Range crust and become generally younger towards the Colorado Plateau. Our isotopic data illustrate that the CH rhyolites require a source with comparatively radiogenic Sr, that most rhyolites require a source with comparatively unradiogenic 206Pb/204Pb, and that the MF-HSR require a source with comparatively radiogenic Nd and 206Pb/204Pb. The isotopic data clearly indicate that the western Arizona rhyolites contain a large crustal component. Importantly, the Pb isotopic compositions of the rhyolites illustrate the transition between two crustal provinces identified by other workers on the basis of Nd and Pb isotopic studies of Proterozoic granites. The Sr, Nd, and Pb isotopic compositions of our rhyolites can be modelled by mixing a basaltic component with three hypothetical crustal end-members which themselves may be formed by mixing two crustal components. One crustal component, which is characterised by unradiogenic Pb and Sr, may be similar to the mafic gneiss xenoliths of Tule Tank on the Colorado Plateau. The second crustal component, which has more radiogenic Sr and Pb, may be similar to the Proterozoic Fenner Gneiss of southeastern California. This conceptual model indicates an apparent increase in the contribution of the depleted Tule Tank source from the Basin and Range onto the Colorado Plateau and accommodates the notion that there is an underlying consistency to the petrogeneses of the western Arizona rhyolites as suggested by their chemistry and mineralogy. Although the CH and KS lavas require only one crustal end-member, the MF-HSR and LSR require two isotopically distinct sources. This difference may be attributed to the homogenisation of diverse crustal lithologies by ductile stretching during crustal extension.

scholarly journals Origin of brackish groundwater in a sandstone aquifer on Bornholm, Denmark

2008 ◽  
Vol 39 (3) ◽  
pp. 209-222 ◽  
Author(s):  
N. O. Jørgensen ◽  
J. Heinemeier
Keyword(s):  
Water Body ◽  
Lower Cambrian ◽  
Crystalline Basement ◽  
Water Type ◽  
Rock Interaction ◽  
Isotopic Signatures ◽  
Sandstone Aquifer ◽  
Hydrochemical Data ◽  
Isotopic Studies ◽  
Water Rock Interaction

A multi-isotope approach in combination with hydrochemical data and borehole logging is applied to identify the source of brackish groundwater in a borehole in the well field of Neksø Municipal Waterworks in Bornholm, Denmark. The aquifer lithology consists of fractured Lower Cambrian sandstones resting on Proterozoic crystalline basement. The water body in the studied borehole is significantly stratified with respect to the hydrochemical and isotopic signatures and reveal a Na–Ca–Cl–HCO3 water type and TDS values &gt;1,000 mg/L below a halocline at 40–55 m below measurement point (bmp). The occurrence of brackish groundwater is remarkable for this aquifer, which otherwise yields potable groundwater of good quality. The stable isotope (18O and 2H) compositions indicate a meteoric origin of the brackish groundwater, which rules out seawater intrusion into the aquifer. 14C activities show apparent 14C ages of the brackish groundwater in the range 2200–4300 yr (BP), whereas the freshwater samples above the halocline indicate modern age. Hydrochemical (Cl/Br and Sr) and isotopic studies (18O, 2H and 87Sr/86Sr) of the brackish groundwater point to a well-mixed and homogeneous water body reflecting long water–rock interaction and suggest a contribution of palaeowater from the fractured crystalline basement which has intruded into the Lower Cambrian sandstone aquifer.

scholarly journals Study of Water-rock Interaction with Hydrochemical and Isotopic Datum in Laizhou Bay

2015 ◽  
Vol 9 (1) ◽  
pp. 90-97 ◽  
Author(s):  
Liu Feng ◽  
Ma Fengshan ◽  
Guo Jie ◽  
Ding Kuo
Keyword(s):  
Surface Water ◽  
Fresh Water ◽  
Water Surface ◽  
Saline Water ◽  
Eastern China ◽  
Laizhou Bay ◽  
Rock Interaction ◽  
Aquifer System ◽  
Isotopic Analyses ◽  
Water Rock Interaction

Water-rock interaction of the groundwater in aquifer system has been analyzed and inferred with hydrochemical and isotopic datum in Laizhou Bay, eastern China. 32 samples of groundwater from three boreholes (96-5#, 96-6#, 112- 1#), couples of seawater, saline water, fresh water, surface water and rainfall are obtained in study area for hydrochemical and isotopic analyses. The origin of groundwater is generally concluded by stable isotope (§18O and §D) and the analytic results of Na+, Ca2+, Mg2+, Cl-, SO2- , HCO3- changing with depth, combined with total dissolved solids (TDS), electrical conductivity (EC), can be apparently proofs for serious water-rock interaction. The conclusion reveals that the origin of 96-5#, 112-1# is most likely saline water different from that the groundwater of 96-6# which is possible originated from fresh water, surface water or mixing of both. Compared the ion content of same borehole at different depth and different boreholes with same depth, the optimal area for building main well and mining area is determined eventually is around 96-5#.

scholarly journals Exponential trends in flowback chemistry from a hydraulically stimulated deep geothermal borehole in granite; Pohang, South Korea

2019 ◽  
Vol 98 ◽  
pp. 08001
Author(s):  
David Banks ◽  
Neil Burnside ◽  
Rob Westaway ◽  
Günter Zimmermann ◽  
Hannes Hofmann
Keyword(s):  
Surface Water ◽  
South Korea ◽  
Tank Model ◽  
Hydraulic Stimulation ◽  
Rock Interaction ◽  
Flowback Water ◽  
First Approximation ◽  
Exponential Trend ◽  
End Members ◽  
Water Rock Interaction

Samples of flowback water from a 4.3 km deep geothermal borehole in granite (Pohang, South Korea) were collected following a period of hydraulic stimulation by injection of surface water. Electrical conductivity, temperature and water chemistry of the flowback water were measured. To a first approximation, the data conform closely to a simple ‘mixing tank’ model, with an exponential trend between two end members: an initial injected surface water to a more brackish ‘resident groundwater’ composition. Significant deviation from the ‘mixing tank’ trend would be an indication of significant recent water-rock interaction or other anomalous factors. Such a deviation can tentatively be seen in Na+/Cl- data, especially between 88 and 200 m3 flowback (2.8 to 8.8 hr).

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