Large thermoelectric power generated by the van Hove singularity in NaxCoO2

2007 ◽  
Vol 1044 ◽  
Author(s):  
Tsunehiro Takeuchi ◽  
Syuhei Kuno

AbstractMechanism leading to the large thermoelectric power and metallic electrical conduction observed in NaxCoO2 was investigated by means of angle resolved photoemission spectroscopy and the Bloch-Boltzmann theory. As a result of thermoelectric power calculation using the experimentally determined electronic structure under the assumptions of rigid band and constant mean free path, NaxCoO2 were found to possess the Boltzmann-type electrical conduction over a wide carrier-concentration range. Analysis using the simplest tight-binding bands revealed that the two-dimensional hexagonal lattices including the crystalline structure of the present NaxCoO2 produce a characteristic spectral conductivity leading to the large thermoelectric power and metallic electrical conduction.

ACS Nano ◽  
2019 ◽  
Author(s):  
Matthew J. Hamer ◽  
Johanna Zultak ◽  
Anastasia V. Tyurnina ◽  
Viktor Zólyomi ◽  
Daniel Terry ◽  
...  

2021 ◽  
Vol 38 (12) ◽  
pp. 127102
Author(s):  
Yuxin Yang ◽  
Wenhui Fan ◽  
Qinghua Zhang ◽  
Zhaoxu Chen ◽  
Xu Chen ◽  
...  

We report the structure and physical properties of two newly discovered compounds AV8Sb12 and AV6Sb6 (A = Cs, Rb), which have C 2 (space group: Cmmm) and C 3 (space group: R 3 ¯ m ) symmetry, respectively. The basic V-kagome unit appears in both compounds, but stacking differently. A V2Sb2 layer is sandwiched between two V3Sb5 layers in AV8Sb12, altering the V-kagome lattice and lowering the symmetry of kagome layer from hexagonal to orthorhombic. In AV6Sb6, the building block is a more complex slab made up of two half-V3Sb5 layers that are intercalated by Cs cations along the c-axis. Transport property measurements demonstrate that both compounds are nonmagnetic metals, with carrier concentrations at around 1021 cm−3. No superconductivity has been observed in CsV8Sb12 above 0.3 K under in situ pressure up to 46 GPa. Compared to CsV3Sb5, theoretical calculations and angle-resolved photoemission spectroscopy reveal a quasi-two-dimensional electronic structure in CsV8Sb12 with C 2 symmetry and no van Hove singularities near the Fermi level. Our findings will stimulate more research into V-based kagome quantum materials.


1997 ◽  
Vol 237-238 ◽  
pp. 377-379
Author(s):  
T. Yokoya ◽  
A. Chainani ◽  
T. Takahashi ◽  
H. Ding ◽  
J.C. Campuzano ◽  
...  

2000 ◽  
Vol 470 (1-2) ◽  
pp. 43-52 ◽  
Author(s):  
Daiichiro Sekiba ◽  
Tamami Inokuchi ◽  
Yasushi Wakimoto ◽  
Kazutoshi Yagi-Watanabe ◽  
Hirohito Fukutani

1993 ◽  
Vol 07 (19) ◽  
pp. 3375-3404 ◽  
Author(s):  
S. DAS SARMA ◽  
SONG HE

Detailed numerical results are presented for the calculated conductance of quantum point contacts, or, narrow constrictions between high mobility two-dimensional electron systems fabricated on semiconductor nanostructures. The conductance is calculated from the two-terminal multichannel transmission matrix formalism using the recursive single-particle Green’s function technique. The Green’s functions are obtained recursively for a tight-binding two-dimensional disordered Anderson lattice model representing the constriction. The conductance is calculated as a function of the shape and the size of the constriction (i.e., its geometry), the temperature, and, the elastic disorder in the system. Our main results, which are consistent with experimental findings, are: (1) increase of elastic scattering destroys the quantization; (2) for a fixed amount of disorder (i.e., for a given value of the elastic mean free path), the conductance quantization is poorer for longer constrictions; (3) in general, the quantization is poorer for higher quantum numbers or subbands; (4) constrictions with sharper geometry have sharper quantization, but may have quantum resonances associated with their sharp corners; (5) the quantum resonances (in sharp constrictions) are suppressed for shorter constriction lengths and at higher temperatures; (6) in general, higher temperatures lower the quantization quality by smoothening out the conductance except for sharp constrictions where at the lowest temperatures the quantum resonances show up, adversely affecting the quantization; (7) in smooth or adiabatic constrictions, the conductance quantization is smooth (but not extremely accurate) but, adiabaticity is not a necessary requirement for conductance quantization; (8) in general, geometry, finite temperature, and finite disorder effects do not allow better than 1% type accuracy in the quantization (compared with integral multiples of 2e2/h) even in the best of circumstances; (9) increase of elastic disorder smoothly takes the system from a conductance quantized regime to the regime of universal conductance fluctuations; and, (10) inelastic scattering, which we treat only in a very crude phenomenological model, behaves similar to thermal effects in broadening and smearing the sharpness of the conductance quantization. We also discuss the effect of an external magnetic field on the conductance quantization phenomenon. Some results are given for the conductance of two constrictions in series.


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