Synthesis and Characterization of a Methanofullerene-4-Fluoro-α-Cyanostilbene Dyad as a Potential Acceptor for Organic Solar Cells

2015 ◽  
Vol 1784 ◽  
Author(s):  
Venkata Neti

ABSTRACTA series of fluorine appended highly conjugated fullerenes were prepared containing fluoro-α-cyanostilbene and aryl ester units. These modified PCBM dyads are fully characterized by NMR, Mass spectrometry, UV-vis, and cyclic voltammetry (Figures 1-4). It was found that the presence of fluoro-α-cyanostilbenes and esters affects the cyclic voltammetry and absorption in the UV-Vis region. The PCBA modified fullerenes significantly influences the HOMO-LUMO energy and wide absorption compared to PCBM.

Author(s):  
Dorota Zając ◽  
Dariusz Przybylski ◽  
Jadwiga Sołoducho

AbstractDeveloping effective and low‐cost organic semiconductors is an opportunity for the development of organic solar cells (OPV). Herein, we report the molecular design, synthesis and characterization of two molecules with D–A–D–A configuration: 2-cyano-3-(5-(8-(3,4-ethylenodioxythiophen-5-yl)-2,3-diphenylquinoxalin-5-yl)thiophen-2-yl)acrylic acid (6) and 2-cyano-3-(5-(2,3-diphenyl-8-(thiophen-2-yl)quinoxalin-5-yl)thiophen-2-yl)acrylic acid (7). Moreover, we investigated the structural, theoretical and optical properties. The distribution of HOMO/LUMO orbitals and the values of the ionization potential indicate good semiconducting properties of the compounds and that they can be a bipolar material. Also, the optical study show good absorption in visible light (λabs 380–550 nm). We investigate the theoretical optoelectronic properties of obtained compounds as potential materials for solar cells.


2011 ◽  
Vol 161 (13-14) ◽  
pp. 1330-1335 ◽  
Author(s):  
Dongbo Mi ◽  
Ji-Hoon Kim ◽  
Sung Cheol Yoon ◽  
Changjin Lee ◽  
Jin-Kyun Lee ◽  
...  

2019 ◽  
Vol 160 ◽  
pp. 403-409 ◽  
Author(s):  
Jiyoung Kim ◽  
Woo-Hyung Lee ◽  
Jong Baek Park ◽  
Do-Hoon Hwang ◽  
In-Nam Kang

2019 ◽  
Vol 383 (1) ◽  
pp. 1700078 ◽  
Author(s):  
Bianca Pedroso Silva Santos ◽  
Jose Jonathan Rubio Arias ◽  
Maria de Fátima Vieira Marques ◽  
Jose Geraldo de Melo Furtado ◽  
Luiz Alberto Silva ◽  
...  

2011 ◽  
Vol 95 (4) ◽  
pp. 1182-1187 ◽  
Author(s):  
Dongbo Mi ◽  
Ji-Hoon Kim ◽  
Fei Xu ◽  
Soo-Hyung Lee ◽  
Sung Cheol Yoon ◽  
...  

2014 ◽  
Vol 2 (24) ◽  
pp. 4879-4892 ◽  
Author(s):  
Mirjam Löbert ◽  
Amaresh Mishra ◽  
Christian Uhrich ◽  
Martin Pfeiffer ◽  
Peter Bäuerle

Planarization of the molecular backbone in A–D–A oligomers leads to high fill factors and efficiencies in vacuum-processed organic solar cells.


2012 ◽  
Vol 22 (43) ◽  
pp. 22971 ◽  
Author(s):  
Venla M. Manninen ◽  
Walaa A. E. Omar ◽  
Juha P. Heiskanen ◽  
Helge J. Lemmetyinen ◽  
Osmo E. O. Hormi

2014 ◽  
Vol 50 (65) ◽  
pp. 9083-9085 ◽  
Author(s):  
Alexander V. Anyushin ◽  
Anton I. Smolentsev ◽  
Dmitry A. Mainichev ◽  
Cristian Vicent ◽  
Artem L. Gushchin ◽  
...  

The first berillododecatungstate [BeW12O40]6− has been synthesized and characterized by X-ray analysis, cyclic voltammetry, ESI-mass spectrometry, and 9Be and 183W NMR.


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