Electrochemical Performance of Lithium-Ion Hybrid Supercapacitors based on Activated Carbon and Nanoplatelet Li4Ti5O12 Insertion Electrode Synthesized by Nanoscission Technique

2015 ◽  
Vol 1740 ◽  
Author(s):  
Sandeep Singh ◽  
Alok C Rastogi ◽  
Fredrick Omenya ◽  
M Stanley Whittingham ◽  
Archit Lal ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Electrochemical Performance ◽  
Lithium Ion ◽  
Charge Transfer Resistance ◽  
Electrode Polarization ◽  
Hybrid Supercapacitor ◽  
Transfer Resistance ◽  
Hybrid Supercapacitors ◽  
Current Change ◽  
Kinetic Effects

ABSTRACTElectrochemical performance of hybrid supercapacitor (HSC) utilizing surface sculpted Li4Ti5O12 (LTO) insertion electrode having nanoplatelet-like morphology and activated carbon (AC) electrode is investigated for energy storage application. Cyclic voltammetry (CV) at variable scan rates 0.5 to 60 mV.s-1 in the 0-3.2 V range show pseusocapacitive behavior and fast rate of current change indicating rapid Faradaic kinetics. Nyquist impedance study show charge transfer resistance due to kinetic effects of electron transfer and Li+ de-intercalation process at the LTO anode. Low capacity (0.2 C-1C) charge-discharge (CD) curves show high Coulomb efficiency with marginal reduction at high 5-10 C rates due to irreversibility of adsorbed PF6 anions at the electrolyte-AC interface. Galvanostatic CD cycling tests over 50 cycles at different C-rates show decline in storage capacity due to electrode polarization effects. Reduction, broadening and shift of the Raman line at 678 cm-1 from Ti-O bonds in TiO6 octahedra after cycling indicates Li insertion reactions in functioning of hybrid supercapacitor. The hybrid supercapacitor cells have shown energy density, 29 Wh.kg-1 and power density, 350 W.kg-1.

scholarly journals Aggregation-Morphology-Dependent Electrochemical Performance of Co3O4 Anode Materials for Lithium-Ion Batteries

Molecules ◽  
2019 ◽  
Vol 24 (17) ◽  
pp. 3149 ◽  
Author(s):  
Linglong Kong ◽  
Lu Wang ◽  
Deye Sun ◽  
Su Meng ◽  
Dandan Xu ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
Anode Materials ◽  
High Performance ◽  
Retention Rate ◽  
Lithium Ion ◽  
Charge Transfer Resistance ◽  
Superior Performance ◽  
Electrode Structure ◽  
Transfer Resistance

The aggregation morphology of anode materials plays a vital role in achieving high performance lithium-ion batteries. Herein, Co3O4 anode materials with different aggregation morphologies were successfully prepared by modulating the morphology of precursors with different cobalt sources by the mild coprecipitation method. The fabricated Co3O4 can be flower-like, spherical, irregular, and urchin-like. Detailed investigation on the electrochemical performance demonstrated that flower-like Co3O4 consisting of nanorods exhibited superior performance. The reversible capacity maintained 910.7 mAh·g−1 at 500 mA·g−1 and 717 mAh·g−1 at 1000 mA·g−1 after 500 cycles. The cyclic stability was greatly enhanced, with a capacity retention rate of 92.7% at 500 mA·g−1 and 78.27% at 1000 mA·g−1 after 500 cycles. Electrochemical performance in long-term storage and high temperature conditions was still excellent. The unique aggregation morphology of flower-like Co3O4 yielded a reduction of charge-transfer resistance and stabilization of electrode structure compared with other aggregation morphologies.

Preparation and Electrochemical Performance of Mg2 + Doped Li4Ti5O12 Anode Materials for Lithium-Ion Batteries

2019 ◽  
Vol 960 ◽  
pp. 238-243
Author(s):  
Ming Wang ◽  
Xue Ming Zhang ◽  
Ying Bo Wang ◽  
Li Li Cheng ◽  
Xue Lei Wang ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Electrochemical Impedance ◽  
Solid Phase ◽  
Retention Rate ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Charge Transfer Resistance ◽  
Solid Phase Reaction ◽  
Phase Reaction ◽  
Transfer Resistance

Spinel Li4Ti5O12 (LTO) doped with Mg2+ was synthesized by solid-phase reaction method. The Mg2+ doping quantity was 3%, 6%, 9%, and 12%, respectively. The structure and electrochemical performance of the prepared LTO composites were investigated by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), Electrochemical Impedance Spectroscopy (EIS), and galvanostatic charge-discharge tests. It was found that the doped Mg ion did not change the structure of Li4Ti5O12, and it was evenly distributed around Li4Ti5O12. When Mg2+ doping quantity increased from 3% to 12%, the internal resistance and charge transfer resistance of the composite both decreased. The first discharge specific capacity of 6%-Mg2+ doped LTO composite was 168 mAh/g, which was close to the theoretical capacity of pure lithium titanate (175 mAh/g), and the capacity retention rate was 98% after 100 cycles.

scholarly journals Improved Electrochemical Performance of 0.5Li2MnO3·0.5LiNi0.5Mn0.5O2 Cathode Materials for Lithium Ion Batteries Synthesized by Ionic-Liquid-Assisted Hydrothermal Method

2020 ◽  
Vol 8 ◽  
Author(s):  
Yanhong Xiang ◽  
Youliang Jiang ◽  
Saiqiu Liu ◽  
Jianhua Wu ◽  
Zhixiong Liu ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Ionic Liquid ◽  
Electrochemical Performance ◽  
Hydrothermal Method ◽  
Cathode Materials ◽  
Electrochemical Impedance ◽  
Rate Capability ◽  
Lithium Ion ◽  
Charge Transfer Resistance ◽  
Transfer Resistance

Well-dispersed Li-rich Mn-based 0.5Li2MnO3·0.5LiNi0.5Mn0.5O2 nanoparticles with diameter ranging from 50 to 100 nm are synthesized by a hydrothermal method in the presence of N-hexyl pyridinium tetrafluoroborate ionic liquid ([HPy][BF4]). The microstructures and electrochemical performance of the prepared cathode materials are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and electrochemical measurements. The XRD results show that the sample prepared by ionic-liquid-assisted hydrothermal method exhibits a typical Li-rich Mn-based pure phase and lower cation mixing. SEM and TEM images indicate that the extent of particle agglomeration of the ionic-liquid-assisted sample is lower compared to the traditional hydrothermal sample. Electrochemical test results indicate that the materials synthesized by ionic-liquid-assisted hydrothermal method exhibit better rate capability and cyclability. Besides, electrochemical impedance spectroscopy (EIS) results suggest that the charge transfer resistance of 0.5Li2MnO3· 0.5LiNi0.5Mn0.5O2 synthesized by ionic-liquid-assisted hydrothermal method is much lower, which enhances the reaction kinetics.

Synthesis of LiMn0.7Fe0.3PO4/C Composite Cathode Materials for Lithium-Ion Batteries

2013 ◽  
Vol 634-638 ◽  
pp. 2617-2620
Author(s):  
Na Chi ◽  
Jian Gang Li ◽  
Lei Wang ◽  
Jie Si Fu
Keyword(s):  
Electrochemical Performance ◽  
Electrochemical Impedance ◽  
Lithium Ion ◽  
Solid State Reaction Method ◽  
Composite Cathode ◽  
Charge Transfer Resistance ◽  
Electrochemical Impedance Spectra ◽  
Transfer Resistance ◽  
Cation Order ◽  
Increasing Temperature

LiMn0.7Fe0.3PO4/C composite cathode material was prepared by using a solid state reaction method. The effects of annealing temperatures on the structural and electrochemical performance of LiMn0.7Fe0.3PO4/C were investigated by using X-ray diffraction (XRD), scanning electron microscope (SEM), charge–discharge tests and electrochemical impedance spectra (EIS). The results showed that all of samples have pure ordered olivine phase with orthorhombic Pnma structure. The electrochemical performance of LiMn0.7Fe0.3PO4/C can be improved remarkably with increasing temperature from 550oC to 650 oC due to increased crystallization, cation-order and decreased charge transfer resistance. However, increase temperature to 700 oC leads to bigger crystal particle size and decreased cation-order, thus higher resistance and deteriorated electrochemical properties. The sample prepared at optimized temperature of 650 oC presents a remarkable improved electrochemical performance. It delivers an initial capacity of 125.1 mAhg-1 at 0.2C, 95 mAhg-1 at 5C, and a capacity retention of 98.0% after 30 cycles.

Carbon Nanotube Paper as Anode for Flexible Lithium-Ion Battery

NANO ◽  
2016 ◽  
Vol 11 (11) ◽  
pp. 1650120 ◽  
Author(s):  
Xiaogang Sun ◽  
Zhenhong Liu ◽  
Neng Li ◽  
Xiaoyong Wu ◽  
Yanyan Nie ◽  
...  
Keyword(s):  
Carbon Nanotube ◽  
Electrochemical Performance ◽  
Lithium Ion Battery ◽  
Electrochemical Impedance ◽  
Negative Electrode ◽  
Lithium Ion ◽  
Charge Transfer Resistance ◽  
Electrochemical Performances ◽  
Multiwalled Carbon ◽  
Transfer Resistance

In this investigation, multiwalled carbon nanotube (MWCNT) paper consists of MWCNTs and cellulose was fabricated by traditional paper-making method. It was applied directly as negative electrode in flexible lithium ion battery to replace ordinary electrode which is combined with anode material and current collector. The electrochemical performances of the as-produced MWCNT paper (AMP) and carbonized MWCNT paper (CMP) were evaluated in this study. The morphology and structure of the MWCNT papers were observed by scanning electron microscopy (SEM). The electrochemical performance of the battery was operated by cell test and electrochemical impedance spectroscopy (EIS) measurement. The charging and discharging results indicated that the CMP behaves with higher capacity than AMP. And the EIS analysis showed that a lower charge transfer resistance can be obtained in the CMP. The excellent electrochemical performance verifies the feasibility of MWCNT papers as a promising candidate for the anode in flexible lithium ion battery.

scholarly journals Role of TiO2 Phase Composition Tuned by LiOH on The Electrochemical Performance of Dual-Phase Li4Ti5O12-TiO2 Microrod as an Anode for Lithium-Ion Battery

Energies ◽  
2020 ◽  
Vol 13 (20) ◽  
pp. 5251
Author(s):  
Lukman Noerochim ◽  
Wahyu Caesarendra ◽  
Abdulloh Habib ◽  
Widyastuti ◽  
Suwarno ◽  
...  
Keyword(s):  
Phase Composition ◽  
Electrochemical Performance ◽  
Specific Capacity ◽  
Rate Capability ◽  
Lithium Ion ◽  
Charge Transfer Resistance ◽  
Dual Phase ◽  
Retention Capacity ◽  
Transfer Resistance ◽  
Tio2 Phase

In this study, a dual-phase Li4Ti5O12-TiO2 microrod was successfully prepared using a modified hydrothermal method and calcination process. The stoichiometry of LiOH as precursor was varied at mol ratio of 0.9, 1.1, and 1.3, to obtain the appropriate phase composition between TiO2 and Li4Ti5O12. Results show that TiO2 content has an important role in increasing the specific capacity of electrodes. The refinement of X-ray diffraction patterns by Rietveld analysis confirm that increasing the LiOH stoichiometry suppresses the TiO2 phase. In the scanning electron microscopy images, the microrod morphology was formed after calcination with diameter sizes ranging from 142.34 to 260.62 nm and microrod lengths ranging from 5.03–7.37 μm. The 0.9 LiOH sample shows a prominent electrochemical performance with the largest specific capacity of 162.72 mAh/g and 98.75% retention capacity achieved at a rate capability test of 1 C. This finding can be attributed to the appropriate amount of TiO2 that induced the smaller crystallite size, and lower charge transfer resistance, enhancing the lithium-ion insertion/extraction process and faster diffusion kinetics.

Probing the Effect of High Energy Ball Milling on the Structure and Properties of LiNi1/3Mn1/3Co1/3O2 Cathodes for Li-Ion Batteries

2016 ◽  
Vol 13 (3) ◽  
Author(s):  
Malcolm Stein ◽  
Chien-Fan Chen ◽  
Matthew Mullings ◽  
David Jaime ◽  
Audrey Zaleski ◽  
...  
Keyword(s):  
Particle Size ◽  
Electrochemical Performance ◽  
Crystallite Size ◽  
Ball Milling ◽  
Lithium Ion ◽  
High Energy ◽  
Li Ion Batteries ◽  
Structure And Properties ◽  
Transfer Resistance ◽  
Li Ion

Particle size plays an important role in the electrochemical performance of cathodes for lithium-ion (Li-ion) batteries. High energy planetary ball milling of LiNi1/3Mn1/3Co1/3O2 (NMC) cathode materials was investigated as a route to reduce the particle size and improve the electrochemical performance. The effect of ball milling times, milling speeds, and composition on the structure and properties of NMC cathodes was determined. X-ray diffraction analysis showed that ball milling decreased primary particle (crystallite) size by up to 29%, and the crystallite size was correlated with the milling time and milling speed. Using relatively mild milling conditions that provided an intermediate crystallite size, cathodes with higher capacities, improved rate capabilities, and improved capacity retention were obtained within 14 μm-thick electrode configurations. High milling speeds and long milling times not only resulted in smaller crystallite sizes but also lowered electrochemical performance. Beyond reduction in crystallite size, ball milling was found to increase the interfacial charge transfer resistance, lower the electrical conductivity, and produce aggregates that influenced performance. Computations support that electrolyte diffusivity within the cathode and film thickness play a significant role in the electrode performance. This study shows that cathodes with improved performance are obtained through use of mild ball milling conditions and appropriately designed electrodes that optimize the multiple transport phenomena involved in electrochemical charge storage materials.

scholarly journals Kinetics of electrochemical intercalation of lithium ion into Li[Li0.2Co0.3Mn0.5]O2 electrode from Li2SO4 solution

2021 ◽  
Vol 23 (09) ◽  
pp. 656-687
Author(s):  
K.C. Mahesh ◽  
◽  
G.S. Suresh ◽  
Keyword(s):  
Aqueous Electrolyte ◽  
Lithium Ion ◽  
Potential Drop ◽  
Charge Transfer Resistance ◽  
Transfer Resistance ◽  
Ohmic Potential Drop ◽  
Ion Intercalation ◽  
Time Invariant ◽  
Kinetics Of ◽  
Titration Technique

The kinetics of electrochemical lithium ion intercalation into Li[Li0.2Co0.3Mn0.5]O2 electrode in 2 M Li2SO4 aqueous electrolyte has been studied using two electroanalytical methods, namely, potentiostatic intermittent titration technique (PITT) and galvanostatic intermittent titration technique (GITT). The results are compared with those from nonaqueous electrolytes. Layered, lithium-rich Li[Li0.2Co0.3Mn0.5]O2 cathode material was synthesized by reactions under autogenic pressure at elevated temperature (RAPET) method. The effects of ohmic potential drop and charge-transfer resistance have been considered while predicting the current transients obtained with aqueous electrolyte. For PITT and GITT, we have defined their characteristic time-invariant functions, It1/2 and dE/dt1/2, respectively to present the diffusion time constant τ. Application of different theoretical diffusion models for treating the results obtained by the above-mentioned techniques allowed us to calculate the diffusion coefficient of lithium ions (D) at different potentials (E). The intercalation process is explained by considering the possible attractive interactions of the intercalated species in terms of Frumkin intercalation isotherm. We have observed a strictcorrespondence between the peaks of the intercalation capacitance and the minima in the corresponding log D vs. E curve.

Hydrothermal synthesis MoO3@CoMoO4 hybrid as an anode material for high performance lithium rechargeable batteries

2019 ◽  
Vol 12 (01) ◽  
pp. 1850104 ◽  
Author(s):  
Jinggao Wu ◽  
Qi Lai ◽  
Canyu Zhong
Keyword(s):  
Current Density ◽  
High Performance ◽  
High Current Density ◽  
Rate Capability ◽  
Lithium Ion ◽  
Charge Transfer Resistance ◽  
Rechargeable Batteries ◽  
Transfer Resistance ◽  
Lithium Rechargeable Batteries ◽  
One Step

MoO3@CoMoO4 hybrid is fabricated by a facile one-step hydrothermal method and is used as anode for lithium-ion battery (LIB). Compared to pristine MoO3, galvanostatic charge–discharge tests show that the hybrid electrode delivered a remarkable rate capability of 586.69[Formula: see text]mAh[Formula: see text]g[Formula: see text] at the high current density of 1000[Formula: see text]mA[Formula: see text]g[Formula: see text] and a greatly enhanced cyclic capacity of 887.36[Formula: see text]mA[Formula: see text]h[Formula: see text]g[Formula: see text] after 140 cycles at the current density of 200[Formula: see text]mA[Formula: see text]g[Formula: see text] (with capacity retention, 85.3%). The superior electrochemical properties could be ascribed to the synergistic effect of MoO3 and CoO nanostructure that results in the lower charge transfer resistance and the higher Li[Formula: see text] diffusion coefficient, thus leading to high performance Li[Formula: see text] reversibility storage.

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