Phase Stability of β-Ti Phase in the TiAl Alloys with the Combined Addition of M Elements

2015 ◽  
Vol 1760 ◽  
Author(s):  
Hirotoyo Nakashima ◽  
Masao Takeyama

ABSTRACTPhase equilibria among the β-Ti, α-Ti and γ-TiAl phases were examined at 1473 K, in order to reveal the M/Nb ratio dependence of the relative phase stability of β phase in the Ti-Al-Nb-M (M: V, Cr, Mo) quaternary systems. In all of the quaternary systems, the expansion of β phase region toward the lower (Nb+M) content side is observed due to the existence of negative interaction to stabilize the β phase between the third and fourth elements (i.e. Nb-V, Nb-Cr and Nb-Mo). Composition dependence of the interaction is quantified as a function of the M/(Nb+M) ratio at 42 at.% Al. The strong interaction energy existing between the different group elements should be taken into account to design the multi-component TiAl alloys.

1990 ◽  
Vol 194 ◽  
Author(s):  
D. T. Hoelzer ◽  
F. Ebrahimi

AbstractAn alloy with the nominal composition 42Nb-28Ti-30Al (at.%) was heat treated in the sigma + beta phase region. The evolution of σ phase from the metastable β phase and the stability of the two-phase microstructure at various aging temperatures were evaluated using TEM techniques. The results indicate that the β phase in equilibrium with the σ phase at high temperatures decomposes to the orthorhombic phase at temperatures below 1200°C.


2017 ◽  
Vol 699 ◽  
pp. 256-261 ◽  
Author(s):  
X.J. Jiang ◽  
G. Yu ◽  
Z.H. Feng ◽  
C.Q. Xia ◽  
C.L. Tan ◽  
...  
Keyword(s):  

2020 ◽  
Vol 321 ◽  
pp. 13003
Author(s):  
Zimin Lu ◽  
Jiao Luo ◽  
Miaoquan Li

Effect of strain rate on α-lath thickness of TC17 alloy with a basketweave microstructure was studied in the present work. For this purpose, this alloy was deformed in the β phase region and subsequently soluted and aged in α+β phase region. Moreover, optical micrograph (OM) and electron backscatter diffraction (EBSD) were applied to analyze the change of lath thickness at different strain rates. The result showed that α-lath thickness increased with increasing strain rate. This phenomenon was possibly attributed to the higher degree of variant selection (DVS) at higher strain rate (0.1 s-1). The higher DVS was beneficial for the formation of parallel α-lath colonies during cooling after deformation. And, these parallel α-lath colonies would more easily grow up and coarsen during subsequent heat treatment. Therefore, α-lath at higher strain rate is more thick.


Metals ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1630
Author(s):  
Ke Wang ◽  
Yongqing Zhao ◽  
Weiju Jia ◽  
Silan Li ◽  
Chengliang Mao

Isothermal compressions of as-cast near-α Ti90 titanium alloy were carried out on a Gleeble-3800 simulator in the temperature range of 860–1040 °C and strain rates of 0.001–10 s−1. The deformation behavior of the alloy was characterized based on the analyses of flow curves, the constructions of Arrhenius constitutive equations and the processing map. The microstructure evolution of the alloy was analyzed using the optical microscopic (OM), transmission electron microscope (TEM), and electron backscatter diffraction (EBSD) techniques. The results show that the kinking and dynamic globularization of α lamellae is the dominant mechanism of flow softening in the α + β two-phase region, while the dynamic recovery (DRV) of β phase is the main softening mechanism in the β single-phase region. The dynamic globularization of α lamellae is mainly caused by the wedging of β phase into α laths and the shearing of α laths due to imposed shear strain. The activation of prismatic and pyramidal slip is found to be easier than that of basic slip during the deformation in the α + β two-phase region. In addition, the Schmid factor of equiaxial α is different from that of lamellar α, which also varies with the angle between its geometric orientation and compression direction (CD). Based on the processing map, the low η region within the temperature range of 860–918 °C with a strain rate range of 0.318–10 s−1 should be avoided to prevent the occurrence of deformation instability.


2020 ◽  
Vol 321 ◽  
pp. 08003
Author(s):  
Yujun Du ◽  
Xianghong Liu ◽  
Jinshan Li ◽  
Wenzhong Luo ◽  
Yongsheng He ◽  
...  

Small button ingots of Ti2AlNb alloys with different contents of Mo, V and Zr were melted by vacuum non-consumable arc furnace. Due to the rapid cooling rate during melting process, only β grains without precipitation were observed in most of the button ingots and no regular phenomenon was found. However, when the samples were heated to β phase region and then furnace cooled to room temperate, different morphologies and quantities of primary α phase and second O phase formed from the β grains of different samples. It is suggested that the morphology of α phase was changed from lamellar to quadrilateral with increasing V and the lath O increased with increasing Zr. Besides, the residual β/B2 phase increased with increasing Mo and V. The EDS results showed that Al and Zr were enriched in α phase whereas Nb, Mo and V were enriched in β/B2 phase. The micro-hardness of these samples before and after heat treatment was detected and the micro-hardness increased with increasing Zr and decreasing Mo and V.


2016 ◽  
Vol 258 ◽  
pp. 501-505
Author(s):  
Alice Chlupová ◽  
Milan Heczko ◽  
Karel Obrtlík ◽  
Přemysl Beran ◽  
Tomáš Kruml

Two γ-based TiAl alloys with 7 at.% of Nb, alloyed with 2 at.% Mo and 0.5 at.% C, were studied. A heat treatment leading to very fine lamellar microstructure was applied on both alloys. Microstructure after the heat treatment was described and mechanical properties including fatigue behaviour were measured. The as-received material alloyed with C possesses high strength and very limited ductility, especially at RT. After application of selected heat treatment it becomes even more brittle; therefore, this process could be considered as not appropriate for this alloy. On the contrary, in the case of Mo alloyed material, both strength and ductility are improved by the heat treatment at RT and usual working temperature (~750 °C). Presence of the β phase is responsible for this effect. The selected heat treatment thus can be an alternative for this alloy to other thermomechanical treatments as high temperature forging.


2021 ◽  
Vol 1035 ◽  
pp. 562-567
Author(s):  
Li Chun Qi ◽  
Wen Xiao Qu ◽  
Yong Qi Zhu ◽  
Qing Liu

The phase compositions of surface and interior in Ti-32Nb-4Sn metastable b alloy were investigated. It was found that this alloy exhibits surface effect significantly different from the effects reported in Ti-10V-2Fe-3Al, Ti-22Nb-9Zr and the other titanium alloys. The surface of Ti-32Nb-4Sn specimen quenched from single b phase region was characterized by dominant b phase and a few of α″ and ω phase. While in the interior of the alloy, a large amount of α² martensite phase was observed in addition to b phase The orientation relationship between the α″ martensite and β phase is (110)β∥(002)α″, (020)β∥(022)α″ and [001]β∥[100]α″.


2019 ◽  
Vol 788 ◽  
pp. 136-147 ◽  
Author(s):  
Zhan Hu ◽  
Xiyi Zhou ◽  
Xi-an Nie ◽  
Siyu Zhao ◽  
Huiqun Liu ◽  
...  
Keyword(s):  

Materials ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 3623 ◽  
Author(s):  
Danying Zhou ◽  
Hua Gao ◽  
Yanhua Guo ◽  
Ying Wang ◽  
Yuecheng Dong ◽  
...  

A self-designed Ti-35421 (Ti-3Al-5Mo-4Cr-2Zr-1Fe wt%) titanium alloy is a new type of low-cost high strength titanium alloy. In order to understand the hot deformation behavior of Ti-35421 alloy, isothermal compression tests were carried out under a deformation temperature range of 750–930 °C with a strain rate range of 0.01–10 s−1 in this study. Electron backscatter diffraction (EBSD) was used to characterize the microstructure prior to and post hot deformation. The results show that the stress–strain curves have obvious yielding behavior at a high strain rate (>0.1 s−1). As the deformation temperature increases and the strain rate decreases, the α phase content gradually decreases in the α + β phase region. Meanwhile, spheroidization and precipitation of α phase are prone to occur in the α + β phase region. From the EBSD analysis, the volume fraction of recrystallized grains was very low, so dynamic recovery (DRV) is the dominant deformation mechanism of Ti-35421 alloy. In addition to DRV, Ti-35421 alloy is more likely to occur in continuous dynamic recrystallization (CDRX) than discontinuous dynamic recrystallization (DDRX).


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