Deposition of CVD diamond onto Zirconium

2015 ◽  
Vol 1734 ◽  
Author(s):  
F. Brannan ◽  
P.W. May ◽  
S.C. Halliwell ◽  
L. Payne

ABSTRACTThe growth of thin films of chemical vapour deposition (CVD) diamond onto flat samples of pure Zr has been studied using various CVD growth conditions in a hot filament reactor. We find that although growth is straightforward, adhesion of the diamond layer onto the Zr is poor, with the diamond layer often delaminating upon cooling. SIMS depth profiles show this to be due to the presence of a strongly-bonded native oxide on the Zr surface which is not removed in the reducing H2 atmosphere during CVD. This, plus the lack of any substantial carbide interfacial layer to ‘glue’ the diamond onto the surface, together with a poor thermal expansion mismatch between Zr and diamond, and the Zr hcp-to-bcc phase transition at ∼860°C, all lead to poor adhesion. Some of these difficulties can be reduced by depositing at lower temperature (<500°C) at the cost of poorer quality diamond.

2015 ◽  
Vol 821-823 ◽  
pp. 982-985 ◽  
Author(s):  
Tibor Izak ◽  
Oleg Babchenko ◽  
Vít Jirásek ◽  
Gabriel Vanko ◽  
Marián Vojs ◽  
...  

In this study we present the diamond deposition on AlGaN/GaN substrates focusing on the quality of the diamond/GaN interface. The growth of diamond films was performed using microwave chemical vapour deposition system in different gas mixtures: standard CH4/H2(at low and high ratio of CH4to H2) and addition of CO2to CH4/H2gas chemistry. The diamond films were grown directly on GaN films either without or with thin interlayer. As interlayer, 100 nm thick Si3N4was used. Surprisingly, in the case of standard CH4/H2gas mixture, no diamond film was observed on the GaN with SiN interlayer, while adding of CO2resulted in diamond film formation of both samples with and without SiN interlayer. Moreover, adding of CO2led to higher growth rate. The morphology of diamond films and the quality of the diamond/GaN interface was investigated from the cross-section images by scanning electron microscopy and the chemical character (i.e. sp3versus sp2carbon bonds) was measured by Raman spectroscopy.


2007 ◽  
Vol 1039 ◽  
Author(s):  
Ken Haenen ◽  
Andrada Lazea ◽  
Vincent Mortet ◽  
Jan D'Haen ◽  
Peter Geithner ◽  
...  

AbstractPhosphorous-doping of predominantly (110) oriented polycrystalline CVD diamond films is presented. Incorporation of phosphorous into the diamond grains was accomplished by using novel microwave plasma enhanced chemical vapor deposition (MW PE CVD) growth conditions. The substitutional nature of the phosphorous atom was confirmed by applying the quasi-steady-state photocurrent technique (PC) and cathodoluminescence (CL) measurements at low temperature. Topographical information and the relation between substrate and P-doped film grain orientation was obtained with scanning electron microscopy (SEM) and electron back-scattered diffraction (EBSD). The optimized growth parameters for P-doped layers on (110) oriented polycrystalline diamond differ substantially from the standard conditions reported in literature for P-doping of single crystalline (111) and (100) oriented diamond surfaces.


Author(s):  
Jan Gaebler ◽  
Markus Höfer ◽  
Markus Armgardt ◽  
Sven Pleger ◽  
Lothar Schäfer

Rough, microcrystalline CVD diamond layers are under research for many years for grinding applications. This contribution will present an overview about the results, both for film development and for application tests. The crystallite protrusions of microcrystalline CVD diamond layers act as micro cutting edges. Thus, the CVD diamond film forms a grinding layer on tools for abrasive machining, like grinding wheels or abrasive pencils (burrs, points). Such grinding layers have significant advantages compared to conventional diamond grinding layers, which are formed by bonding of diamond grains onto the tool base body. The development comprises CVD diamond layers that have been deposited on silicon nitride and silicon carbide tool base bodies with diameters up to 290 mm to form grinding wheels. For the preparation of the diamond layers our unique large-scale hot-filament CVD reactor with a coating area of 1000 mm × 500 mm was used which is already industrialized for the production of diamond electrodes, face seals, and bearings, respectively. The process was adjusted to achieve film thicknesses of 20 µm with tolerances below ±1 µm over the full grinding wheel area. The height of the crystallite protrusions was up to 4 µm; this protrusion corresponds to a grit size of D 12 for conventional bonded diamond grinding layers. The grinding wheels achieved a much better workpiece roughness in the machining of glass, alumina, and cermets. It is assumed that this is due to the number of protrusions, which is by factor of 2 to 7 higher compared to bonded grinding layers, depending on the grit size. Additionally the CVD diamond grinding wheels showed a strongly reduced wear rate. It was 10 to 80 times lower compared to conventional bonded diamond grinding layers. This improvement is due to the much higher number of diamond micro cutting edges and the larger diamond volume that can withstand the wear for a longer time. Furthermore a process technique was developed to regenerate worn CVD diamond layers. During machining the diamond crystallite tips are flattened. It was shown that a short epitaxial-like CVD process is able to recreate the crystallite tips without a significant increase of crystallite size. In such a way the CVD grinding tool can be re-sharpened and re-used. Grinding tests have shown that the machining performance is the same as for newly coated CVD grinding layers. The contribution will also present the development of micro abrasive pencils with CVD diamond coating. Microcrystalline CVD diamond layers have been deposited on cemented carbide tool base bodies with cylindrical tip shape. Due to the ability of the CVD process to coat complex substrate geometries the tools have been coated very uniformly. The abrasive pencils were tested and showed low work piece roughness and very long tool life times. The smallest abrasive pencil that was developed and tested successfully had a diameter of 0.05 mm. The presentation will be complemented by results of the development of honing tools.


2015 ◽  
Vol 75 (7) ◽  
Author(s):  
T. M. Yong ◽  
E. Hamzah ◽  
M. A. Mat Yajid

A nanocrystalline diamond bilayer has been deposited via hot filament chemical vapour deposition method. The bilayer has been produced by two different deposition parameters. The first is by limiting microcrystalline diamond growth and the second layer by pulsing additional oxygen gas into the system. The two layers become indistinguishable after the deposition ends. The pretreatment of the substrate, tungsten carbide has been varied i.e. its various seeding sizes (<0.1 μm synthetic, <0.5 μm synthetic, <0.25 μm natural, <0.5 μm natural, and <1 μm natural); with and without hammering by silicon carbide. This set up is highly similar to that of previous work however the different deposition time has caused the microcrystalline diamond layer to be nanocrystalline diamond instead. Results presented are the optical and SEM (up to 100,000x magnification) images of both planar and cross-section of the diamond layer. AFM gave topographical analysis of the diamond layer. The results show that the thickness is about 1.7 μm, top layer diamond about 100 nm in size and are indeed diamonds by XRD and Raman.  


Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1301
Author(s):  
Anna Dychalska ◽  
Wojciech Koczorowski ◽  
Marek Trzcinski ◽  
Lidia Mosińska ◽  
Mirosław Szybowicz

Extensive Raman spectroscopy studies combined with scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) measurements were performed to investigate structural and chemical changes in diamond layers deposited by chemical vapour deposition (CVD) upon post-growth treatment with hydrogen. The aim of this study is to characterize the changes in micro-structural properties of diamond layers with different grain sizes and different contents of sp2 carbon phase. Hydrogenation or oxidization of diamond layer surface is often performed to modify its properties; however, it can also strongly affect the surface structure. In this study, the impact of hydrogenation on the structure of diamond layer surface and its chemical composition is investigated. Owing to their polycrystalline nature, the structural properties of CVD diamond layers can strongly differ within the same layer. Therefore, in this project, in order to compare the results before and after hydrogen treatment, the diamond layers are subjected to Raman spectroscopy studies in the vicinity of a T-shape marker fabricated on the surface of each diamond layer studied.


2007 ◽  
Vol 16 (3) ◽  
pp. 609-615 ◽  
Author(s):  
S. Konoplyuk ◽  
T. Abe ◽  
T. Takagi ◽  
T. Uchimoto

2013 ◽  
Vol 85 (4) ◽  
pp. 1427-1438 ◽  
Author(s):  
MATHIAS A. CHIA ◽  
ANA T. LOMBARDI ◽  
MARIA DA GRACA G. MELAO

The need for clean and low-cost algae production demands for investigations on algal physiological response under different growth conditions. In this research, we investigated the growth, biomass production and biochemical composition of Chlorella vulgaris using semi-continuous cultures employing three growth media (LC Oligo, Chu 10 and WC media). The highest cell density was obtained in LC Oligo, while the lowest in Chu medium. Chlorophyll a, carbohydrate and protein concentrations and yield were highest in Chu and LC Oligo media. Lipid class analysis showed that hydrocarbons (HC), sterol esthers (SE), free fatty acids (FFA), aliphatic alcohols (ALC), acetone mobile polar lipids (AMPL) and phospholipids (PL) concentrations and yields were highest in the Chu medium. Triglyceride (TAG) and sterol (ST) concentrations were highest in the LC Oligo medium. The results suggested that for cost effective cultivation, LC Oligo medium is the best choice among those studied, as it saved the cost of buying vitamins and EDTA associated with the other growth media, while at the same time resulted in the best growth performance and biomass production.


RSC Advances ◽  
2016 ◽  
Vol 6 (90) ◽  
pp. 87607-87615 ◽  
Author(s):  
B. B. Wang ◽  
D. Gao ◽  
I. Levchenko ◽  
K. Ostrikov ◽  
M. Keidar ◽  
...  

A simple and efficient method for synthesizing complex graphene-inspired BNCO nanoflakes by plasma-enhanced hot filament chemical vapour deposition using B4C as a precursor and N2/H2 reactive gases is reported.


2014 ◽  
Vol 875-877 ◽  
pp. 228-231
Author(s):  
Shafique Ahmed Arain ◽  
Christopher Wilkins ◽  
Hafiz Badaruddin

Diethyl dithiocarbamate [Cd (S2CN Et2)2] complex is used to deposit the cadmium sulphide thin film at much lower temperature by Aerosol Assisted Chemical Vapour deposition (AACVD) and same precursor is used to synthesize the nanocrystals in Oleylamine at elevated temperature. Thermogravimetric analysis shows that precursor [Cd (S2CN Et2)2] decomposes in the single stage, losing 62% of total weight. Deposition of thin films at 300°C and 400°C showed the growth of CdS clusters which were made of granular crystallites. These results are confirmed by SEM analysis. Thermolysis of the precursor in oleylamine at 240°C gave the nanoparticles most of them are monodispersed spherical shape, few having mono and dipod structures. TEM images confirm the structures. XRD results show the thin films and nanoparticles have hexagonal phase of CdS.


2001 ◽  
Vol 18 (2) ◽  
pp. 286-288 ◽  
Author(s):  
Zhang Yu-Feng ◽  
Zhang Fan ◽  
Gao Qiao-Jun ◽  
Yu Da-Peng ◽  
Peng Xiao-Fu ◽  
...  

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