Relationship of the nanocrystal morphology and atomistic structure with respect to the superstructure ordering within PbS- and Gold-Mesocrystals

2014 ◽  
Vol 1705 ◽  
Author(s):  
Lydia Bahrig ◽  
Danny Haubold ◽  
Falk Röder ◽  
Stephen G. Hickey ◽  
Alexander Eychmüller
Keyword(s):  
Crystal Structure ◽  
Structure Formation ◽  
Three Dimensional ◽  
Two Dimensional ◽  
Relationship Of ◽  
The Relationship ◽  
Atomistic Structure

ABSTRACTThe relationship between nanoparticle geometry and their two dimensional assembly is investigated in order to provide insights into the three dimensional arrangement of mesocrystals. The crystal structure of the nanoparticles and their homogeneity are investigated during structure formation on the mesoscale whereby effects such as fibrillation have been observed.

Graphical representation of stereochemical configuration (IUPAC Recommendations 2006)

2006 ◽  
Vol 78 (10) ◽  
pp. 1897-1970 ◽  
Author(s):  
Jonathan Brecher
Keyword(s):  
Graphical Representation ◽  
Dimensional Space ◽  
Three Dimensional ◽  
Two Dimensional ◽  
Wide Audience ◽  
Stereochemical Configuration ◽  
Stereogenic Centers ◽  
Relationship Of ◽  
Stereogenic Center ◽  
The Relationship

Stereochemical configuration is determined by the relationship of atoms in three-dimensional space, yet remains most commonly represented in two-dimensional media such as printed publications or computer screens. Recommendations are provided for the display of three-dimensional stereochemical information in two-dimensional diagrams in ways that avoid ambiguity and are likely to be understood correctly by all viewers. Examples are provided for all types of stereochemical configuration, with explanation of which styles are preferred and which should be avoided. Principal recommendations include:Know your audience: Diagrams that have a wide audience should be drawn as simply as possible.Avoid ambiguous drawing styles.Avoid the use of perspective diagrams and class-specific drawing styles (Fischer projections, Haworth projections, etc.) when structures are to be interpreted by computers.Use solid wedges to indicate bonds that project above the plane of the paper and hashed wedges to indicate bonds that project below the plane of the paper; in both cases, the bonds must be oriented with the narrow end at the stereogenic center.Avoid connecting stereogenic centers with a stereobond.

A Research on the Morphology and Composition of Flocs (Part 1: Floc Breaage Disregarded)

2013 ◽  
Vol 726-731 ◽  
pp. 1566-1572 ◽  
Author(s):  
Shi Qiang Ding ◽  
Qing Na Li ◽  
Xin Rong Pang ◽  
Ji Run Xu
Keyword(s):  
Dimensional Space ◽  
Three Dimensional ◽  
New Classification ◽  
Suspension Viscosity ◽  
Primary Particles ◽  
Long Time ◽  
Relationship Of ◽  
The Relationship ◽  
Three Dimensional Space ◽  
Floc Breakage

The characteristics of flocs aggregated in flocculation have been paid more and more attention for a long time. In this paper, a new classification and analyses method dealing with the flocs is developed. The flocs formed after flocculation is divided into four kinds, including the left primary particles, linear flocs with all component particles in a line, planar flocs with all component particles on a plane and volumetric flocs with all component particles in a three-dimensional space. By analyzing the formation approaches of different kind of flocs regardless of the floc breakage, the number of every kind of floc is analyzed to be related with the suspension concentration mathematically. After comparing the different items in the models describing the relationship of floc number and concentration, a series of simplified expressions are presented. Lastly, a mathematical equation relating the measurable suspension viscosity with the numbers of different flocs is obtained.

“Beholding the Man”: Viewing (or is it Marking?) John’s Trial Scene alongside Kitsch Art

2016 ◽  
Vol 24 (2) ◽  
pp. 245-264
Author(s):  
Andrew P. Wilson
Keyword(s):  
Two Dimensional ◽  
Devotional Art ◽  
The People ◽  
Subject And Object ◽  
Ecce Homo ◽  
Small Stories ◽  
John's Gospel ◽  
Relationship Of ◽  
The Relationship ◽  
Point Of Departure

One of the grand scenes of the Passion narratives can be found in John’s Gospel where Pilate, presenting Jesus to the people, proclaims “Behold the man”: “Ecce Homo.” But what exactly does Pilate mean when he asks the reader to “Behold”? This paper takes as its point of departure a roughly drawn picture of Jesus in the “Ecce Homo” tradition and explores the relationship of this picture to its referent in John’s Gospel, via its capacity as kitsch devotional art. Contemporary scholarship on kitsch focuses on what kitsch does, or how it functions, rather than assessing what it is. From this perspective, when “beholding” is understood not for what it reveals but for what it does, John’s scene takes on a very different significance. It becomes a scene that breaks down traditional divisions between big and small stories, subject and object as well as text and context. A kitsch perspective opens up possibilities for locating John’s narrative in unexpected places and experiences. Rather than being a two-dimensional departure from the grandeur of John’s trial scene, kitsch “art” actually provides a lens through which the themes and dynamics of the narrative can be re-viewed with an expansiveness somewhat lacking from more traditional commentary.


scholarly journals Estimation for Two-Dimensional Nonsymmetric Coherently Distributed Source in L-Shaped Arrays

2018 ◽  
Vol 2018 ◽  
pp. 1-16
Author(s):  
Tao Wu ◽  
Zhenghong Deng ◽  
Qingyue Gu ◽  
Jiwei Xu
Keyword(s):  
Expectation Maximization ◽  
Two Dimensional ◽  
Signal Distribution ◽  
Distributed Source ◽  
One Dimensional ◽  
Least Squares Estimators ◽  
Iterative Calculation ◽  
Symmetric Source ◽  
Relationship Of ◽  
The Relationship

We explore the estimation of a two-dimensional (2D) nonsymmetric coherently distributed (CD) source using L-shaped arrays. Compared with a symmetric source, the modeling and estimation of a nonsymmetric source are more practical. A nonsymmetric CD source is established through modeling the deterministic angular signal distribution function as a summation of Gaussian probability density functions. Parameter estimation of the nonsymmetric distributed source is proposed under an expectation maximization (EM) framework. The proposed EM iterative calculation contains three steps in each cycle. Firstly, the nominal azimuth angles and nominal elevation angles of Gaussian components in the nonsymmetric source are obtained from the relationship of rotational invariance matrices. Then, angular spreads can be solved through one-dimensional (1D) searching based on nominal angles. Finally, the powers of Gaussian components are obtained by solving least-squares estimators. Simulations are conducted to verify the effectiveness of the nonsymmetric CD model and estimation technique.

scholarly journals Heart Rate Dependency and Inter-Lead Variability of the T Peak – T End Intervals

2020 ◽  
Vol 11 ◽  
Author(s):  
Irena Andršová ◽  
Katerina Hnatkova ◽  
Martina Šišáková ◽  
Ondřej Toman ◽  
Peter Smetana ◽  
...  
Keyword(s):  
Heart Rate ◽  
Three Dimensional ◽  
Rate Dependency ◽  
Rate Dependent ◽  
Heart Rate Correction ◽  
Ecg Leads ◽  
Relationship Of ◽  
The Relationship ◽  
Vector Magnitude

The electrocardiographic (ECG) assessment of the T peak–T end (Tpe) intervals has been used in many clinical studies, but several related physiological aspects have not been reported. Specifically, the sources of the Tpe differences between different ECG leads have not been systematically researched, the relationship of Tpe duration to underlying heart rate has not been firmly established, and little is known about the mutual correspondence of Tpe intervals measured in different ECG leads. This study evaluated 796,620 10-s 12-lead ECGs obtained from long-term Holters recorded in 639 healthy subjects (311 female) aged 33.8 ± 9.4 years. For each ECG, transformation to orthogonal XYZ lead was used to measure Tpe in the orthogonal vector magnitude (used as a reference for lead-to-lead comparisons) and to construct a three-dimensional T wave loop. The loop roundness was expressed by a ratio between its circumference and length. These ratios were significantly related to the standard deviation of Tpe durations in different ECG leads. At the underlying heart rate of 60 beats per minute, Tpe intervals were shorter in female than in male individuals (82.5 ± 5.6 vs 90.0 ± 6.5 ms, p < 0.0001). When studying linear slopes between Tpe intervals measured in different leads and the underlying heart rate, we found only minimal heart rate dependency, which was not systematic across the ECG leads and/or across the population. For any ECG lead, positive Tpe/RR slope was found in some subjects (e.g., 79 and 25% of subjects for V2 and V4 measurements, respectively) and a negative Tpe/RR slope in other subjects (e.g., 40 and 65% for V6 and V5, respectively). The steepest positive and negative Tpe/RR slopes were found for measurements in lead V2 and V4, respectively. In all leads, the Tpe/RR slope values were close to zero, indicating, on average, Tpe changes well below 2 ms for RR interval changes of 100 ms. On average, longest Tpe intervals were measured in lead V2, the shortest in lead III. The study concludes that the Tpe intervals measured in different leads cannot be combined. Irrespective of the measured ECG lead, the Tpe interval is not systematically heart rate dependent, and no heart rate correction should be used in clinical Tpe investigations.

scholarly journals The crystal structure of a Polerovirus exoribonuclease-resistant RNA shows how diverse sequences are integrated into a conserved fold

2020 ◽  
Author(s):  
Anna-Lena Steckelberg ◽  
Quentin Vicens ◽  
David A. Costantino ◽  
Jay C. Nix ◽  
Jeffrey S. Kieft
Keyword(s):  
Crystal Structure ◽  
Three Dimensional ◽  
Rna Structures ◽  
Discrete Elements ◽  
Protein Coding ◽  
Sequence Elements ◽  
Conservation Patterns ◽  
Function Relationship ◽  
Relationship Of ◽  
Folded Rna

ABSTRACTExonuclease-resistant RNAs (xrRNAs) are discrete elements that block the progression of 5’ to 3’ exonucleases using specifically folded RNA structures. A recently discovered class of xrRNA is widespread in several genera of plant-infecting viruses, within both noncoding and protein-coding subgenomic RNAs. The structure of one such xrRNA from a dianthovirus revealed three-dimensional details of the resistant fold but did not answer all questions regarding the conservation and diversity of this xrRNA class. Here, we present the crystal structure of a representative polerovirus xrRNA that contains sequence elements that diverge from the previously solved structure. This new structure rationalizes previously unexplained sequence conservation patterns and shows interactions not present in the first structure. Together, the structures of these xrRNAs from dianthovirus and polerovirus genera support the idea that these plant virus xrRNAs fold through a defined pathway that includes a programmed intermediate conformation. This work deepens our knowledge of the structure-function relationship of xrRNAs and shows how evolution can craft similar RNA folds from divergent sequences.

Aerodynamic Characteristics Analysis of High-Speed Train on Cutting under Crosswinds

2013 ◽  
Vol 300-301 ◽  
pp. 62-67
Author(s):  
Kun Ye ◽  
Ren Xian Li
Keyword(s):  
High Speed ◽  
Three Dimensional ◽  
Aerodynamic Characteristics ◽  
High Speed Train ◽  
Aerodynamic Forces ◽  
Cutting Depth ◽  
Cutting Slope ◽  
Characteristics Analysis ◽  
Relationship Of ◽  
The Relationship

Cutting is an effective device to reduce crosswind loads acting on trains. The cutting depth, width and gradient of slope are important factors for design and construction of cutting. Based on numerical analysis methods of three-dimensional viscous incompressible aerodynamics equations, aerodynamic side forces and yawing moments acting on the high-speed train, with different depths and widths of cutting，are calculated and analyzed under crosswinds，meanwhile the relationship of the gradient of cutting slope and transverse aerodynamic forces acting on trains are also studied. Simulation results show that aerodynamic side forces and yawing moments acting on the train（the first, middle and rear train）decrease with the increase of cutting depth. The relationship between transverse forces (moments) coefficients acting on the three sections and the cutting depth basically is the three cubed relation. The bigger is cutting width，the worse is running stability of train. The relationship between yawing moments coefficients acting each body of the train and the cutting width approximately is the three cubed relation. The transverse Aerodynamic forces decreased gradually with the increase of the gradient of cutting slope, the relationship between yawing moments coefficients acting each body of the train and the gradient of cutting slope basically is the four cubed relation.

Sign in / Sign up

Export Citation Format

Share Document