Rheological Properties of Multi-Block Associative Polyelectrolytes Obtained by Nitroxide-Mediated Solution Polymerization

2014 ◽  
Vol 1613 ◽  
pp. 143-149
Author(s):  
Alejandro Coronado ◽  
Areli I. Velazquez ◽  
Enrique J. Jiménez
Keyword(s):  
Rheological Properties ◽  
Creep Compliance ◽  
Viscoelastic Behavior ◽  
Degree Of Polymerization ◽  
Shear Rates ◽  
Linear Response Regime ◽  
Copolymer Structure ◽  
Rheological Experiments ◽  
Polymer Bearing ◽  
Low Shear

ABSTRACTA multi-block associative polyelectrolyte based on poly(methacrylic acid-ra-styrene) [MAA-S] and poly(octadecyl methacrylate) [ODMA] was synthesized through stepwise nitroxide-mediated solution polymerizations. The obtained polymer has a heptablock copolymer structure, alternating MAA-S as hydrophilic blocks (theoretical degree of polymerization [DPT] of 250), and ODMA as hydrophobic blocks (DPT = 15). Rheological properties, in the linear-response regime, of aqueous solutions (polymer content = 1.5 wt.%) were studied as a function of the amount of blocks on the polymer using steady-shear and creep-compliance experiments. Rheological experiments demonstrate that the viscoelastic behavior of the polymer bearing an ODMA block in terminal position greatly differs from that of the polymer with MAA-S block terminations. The former behaves as a newtonian fluid on a wider range of shear rates than the latter, which exhibit a shear-thinning behavior, even at low shear rates, independently of the molecular weight and number of blocks.

Effect of Film Thickness on the Rheological Properties of Asphalts in Contact with Aggregate Surface

1998 ◽  
Vol 1638 (1) ◽  
pp. 31-39 ◽  
Author(s):  
Shin-Che Huang ◽  
Jan F. Branthaver ◽  
Raymond E. Robertson ◽  
Sang-Soo Kim
Keyword(s):  
Thin Films ◽  
Film Thickness ◽  
Rheological Properties ◽  
Thickness Effect ◽  
Asphalt Binders ◽  
Shear Rates ◽  
Service Environment ◽  
Asphalt Mix ◽  
Plate Geometry ◽  
Low Shear

The effect of the interaction between aggregate and asphalt on asphalt mix properties has been a subject of many studies. However, studies using compacted mixtures cannot isolate the pure effects of the asphalt-aggregate interactions, while studies using mixtures of asphalt and fines cannot determine the asphalt rheology at the interface. In this study, direct measurement of asphalt rheology at the interface is investigated using the sliding plate geometry with machined aggregate plates. Significant differences in the behavior of asphalts in contact with aggregate plates have been observed, especially at low shear rates. One asphalt shows substantial aggregate surface-induced structuring, while another asphalt shows essentially none. In addition, the film thickness effect on the rheological properties of asphalt binders and asphalt aggregate mixtures was investigated. The results strongly show that thin films of asphalt on an aggregate surface have substantially changed rheological properties that are asphalt composition–dependent, and that asphalts that are graded alike as bulk materials do not have the same rheological properties as thin films, in this service environment.

Effect of Aggregation on the Rheological Properties of Carbon Nanotube Dispersions

2006 ◽  
Vol 953 ◽  
Author(s):  
Sameer Sharad Rahatekar ◽  
Jeffrey W Gilman ◽  
K K Koziol ◽  
Simon Butler ◽  
James A Elliott ◽  
...  
Keyword(s):  
Shear Rate ◽  
Rheological Properties ◽  
Optical Observations ◽  
Interconnected Network ◽  
Shear Rates ◽  
High Shear Rates ◽  
Suspension Viscosity ◽  
The Matrix ◽  
Viscosity Enhancement ◽  
Low Shear

ABSTRACTIn this pape effect of nanotube aggrates on the rheological properties of multiwall carbonanntube abd epoxy suspension in epoxy resin.The base epoxy resin was found to be essentially Newtonian, and the progressive incorporation of nanotubes enhanced the low shear rate viscosity of the suspension by nearly two decades. At higher shear rates, the suspension viscosity asymptotically thinned to the viscosity of the matrix alone. The low shear rate viscosity enhancement was correlated with the optical observations of interconnected aggregates of carbon nanotubes, which themselves were induced by the low shear conditions. Intermediate shear rates resulted in a reduction in the size of the aggregates. High shear rates appeared to cause near complete dispersal of the aggregates. From these results it is conjectured that for this suspension, shear thinning is connected with the breaking of the interconnected network between aggregates of nanotubes, and not by nanotube alignment.

scholarly journals Role of Electrostatic Interactions on Supramolecular Organization in Calf-Thymus DNA Solutions under Flow

Polymers ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1204 ◽  
Author(s):  
L. Bravo-Anaya ◽  
Denis Roux ◽  
J. Soltero Martínez ◽  
Francisco Carvajal Ramos ◽  
Frédéric Pignon ◽  
...  
Keyword(s):  
Shear Rate ◽  
Salt Concentration ◽  
Liquid Crystalline ◽  
Rheological Parameters ◽  
Supramolecular Organization ◽  
High Shear ◽  
Electrostatic Forces ◽  
Shear Rates ◽  
Rheological Experiments ◽  
Low Shear

Previous investigations were conducted on two concentrations of DNA solution: 4 mg/mL, for which it has been shown that no supramolecular organization is induced under flow at low shear rates; and 10 mg/mL, in which a liquid crystalline-type texture is formed under flow at low shear rates, attesting to an orientation of pre-organized chains. Rheological experiments are discussed and their results supported by small-angle X-ray scattering (SAXS) and flow birefringence visualization experiments. Scattering from polyelectrolytes has a characteristic signal, which is here observed in SAXS, showing a strong correlation peak between charged chains in water, for both concentrations. This peak is weaker in the presence of 0.01 M NaCl and suppressed in salt excess at 0.1 M NaCl. No plateau in the σ( γ ˙ ) plot was observed in analysis of rheological experiments on low DNA concentration (4 mg/mL). As typically observed in polyelectrolyte systems both the dynamic moduli and shear viscosity were higher in water as electrostatic forces dominate, than in the presence of salt, especially at low shear rates. The rheological results for concentrations of 0.01 M NaCl are lower than in water as expected due to partial screening of electrostatic repulsions. Rheological data for concentrations of 0.1 M NaCl are unexpected. Electrostatic forces are partially screened in the low salt concentration, leading to a drop in the rheological values. For high salt concentration there are no longer interchain repulsions and so steric interactions dominate within the entangled network leading to the subsequent increase in rheological parameters. Regardless of the solvent, at high shear rates the solutions are birefringent. In the 10 mg/mL case, under flow, textures are formed at relatively low shear rate before all the chains align going to a pseudonematic liquid crystalline phase at high shear rate. The electrostatic repulsion between semi-rigid chains induces a correlation between the chains leading to an electrostatic pseudo-gel in water and loosely in 0.01 M NaCl at low stress applied. To the best of our knowledge, this is the first time that such behavior is observed. In 0.1 M NaCl, DNA behavior resembles the corresponding neutral polymer as expected for polyelectrolyte in salt excess, exhibiting a yield stress. When texture appears in water and in 0.01 M NaCl, a critical transition is observed in rheological curves, where the viscosity decreases sharply at a given critical shear stress corresponding to a plateau in the σ( γ ˙ ) plot also observed in creep transient experiment.

scholarly journals Rheological Properties of Wood–Plastic Composites by 3D Numerical Simulations: Different Components

Forests ◽  
2021 ◽  
Vol 12 (4) ◽  
pp. 417
Author(s):  
Xingcong Lv ◽  
Xiaolong Hao ◽  
Rongxian Ou ◽  
Tao Liu ◽  
Chuigen Guo ◽  
...  
Keyword(s):  
Flow Field ◽  
Rheological Properties ◽  
Wood Fiber ◽  
Velocity Shear ◽  
Wood Plastic Composites ◽  
Shear Rates ◽  
Plastic Composites ◽  
Power Law Fluids ◽  
Field Information ◽  
Computational Fluid Dynamics Cfd

The rheological properties of wood–plastic composites (WPCs) with different wood fiber contents were investigated using a rotational rheometer under low shear rates. The flow field information was analyzed and simulated by Ansys Polyflow software. The results showed that the WPCs with different wood fiber contents behaved as typical power-law fluids. A higher wood fiber content increased the shear thinning ability and pseudoplasticity of the WPCs. The pressure, velocity, shear rate, and viscosity distributions of the WPC during extrusion could be predicted by computational fluid dynamics (CFD) Ansys Polyflow software to explore the effects of different components on the flow field of WPCs.

scholarly journals Rheological properties of hydroxypropylmethyl cellulose/sodium dodecylsulfate mixtures

2014 ◽  
Vol 79 (4) ◽  
pp. 457-468 ◽  
Author(s):  
Jaroslav Katona ◽  
Sandra Njaradi ◽  
Verica Sovilj ◽  
Lidija Petrovic ◽  
Brankica Marceta ◽  
...  
Keyword(s):  
Rheological Properties ◽  
Sodium Dodecylsulfate ◽  
Shear Thinning ◽  
Cellulose Ether ◽  
Flow Profile ◽  
Hydroxypropylmethyl Cellulose ◽  
Shear Rates ◽  
Newtonian Liquids ◽  
Shear Induced Structure ◽  
Induced Structure

Rheological properties of mixtures of hydroxypropylmethyl cellulose (HPMC), a nonionic associative cellulose ether, and sodium dodecylsulfate (SDS), an anionic surfactant, were investigated by viscosity measurements performed at different shear rates (0.1-6000 s-1). HPMC/SDS mixtures containing different concentrations of SDS (CSDS=0.00-3.50 % w/w) and HPMC concentrations which corresponded to the overlap parameter c/c*=3, 6, and 12 were prepared. All HPMC/SDS mixtures were found to be shear-thinning when examined in a low-end-to mid-range of the applied shear rates. The degree of shear-thinning, n, and viscosity of the mixtures were influenced by composition of HPMC/SDS mixtures and HPMC-SDS complex formation. The changes in n ranged from values typical for highly shear thinning to almost perfectly Newtonian liquids, and were more pronounced as c/c* was increased from 3 to 6 and 12. A change in flow profile and a buildup of the first normal stress difference (N1) was observed in HPMC/SDS mixtures with c/c*=6 and 12 and CSDS 0.55-1.00 % and 0.55-2.50 %, respectively, when a critical shear rate, crit. was exceeded, suggesting that a shear-induced structure formation in the mixtures took place.

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