Initiation and Decomposition of Tetrazole Containing Green Energetic Materials

2012 ◽  
Vol 1405 ◽  
Author(s):  
Nicholas W. Piekiel ◽  
Richard E. Cavicchi ◽  
Michael R. Zachariah
Keyword(s):  
Energetic Materials ◽  
Functional Group ◽  
Rapid Heating ◽  
Heating Rates ◽  
Lower Activation ◽  
High Heating ◽  
Jump Time ◽  
Group Placement ◽  
Decomposition Pathway ◽  
Very High

ABSTRACTA T-Jump/Time-of-Flight Mass Spectrometer (T-Jump/TOFMS) is used to probe the decomposition of several aminotetrazole containing energetic materials under very high heating rates of 105-106 K/s. Subtle differences between materials in functional group placement and anion composition allow for further understanding of the decomposition pathway of the tetrazole structure and various anions. Two decomposition pathways for the tetrazole ring are observed, which result in the primary formation of HN3 or N2. Further analysis is performed using a rapid-heating μ-DSC device, which revealed lower activation energies than previously reported.

A novel setup for wafer curvature measurement at very high heating rates

2017 ◽  
Vol 88 (2) ◽  
pp. 024709 ◽  
Author(s):  
T. Islam ◽  
J. Zechner ◽  
M. Bernardoni ◽  
M. Nelhiebel ◽  
R. Pippan
Keyword(s):  
Heating Rates ◽  
Wafer Curvature ◽  
Curvature Measurement ◽  
High Heating ◽  
Very High

Magnetic hardening by crystallization of amorphous precursors using very high heating rates

1994 ◽  
Vol 76 (10) ◽  
pp. 6840-6842 ◽  
Author(s):  
C. de Julián ◽  
J. M. González ◽  
C. Morón
Keyword(s):  
Heating Rates ◽  
High Heating ◽  
Magnetic Hardening ◽  
Very High

Microwave sintering of ZnO at ultra high heating rates

2001 ◽  
Vol 16 (10) ◽  
pp. 2850-2858 ◽  
Author(s):  
Geng-fu Xu ◽  
Isabel K. Lloyd ◽  
Yuval Carmel ◽  
Tayo Olorunyolemi ◽  
Otto C. Wilson
Keyword(s):  
Grain Size ◽  
Heating Rate ◽  
Microwave Heating ◽  
Grain Growth ◽  
Rapid Heating ◽  
Microwave Sintering ◽  
Complete Suppression ◽  
Heating Rates ◽  
High Heating ◽  
Size Uniformity

In this paper, a unique processing approach for producing a tailored, externally controlled microstructure in zinc oxide using very high heating rates (to 4900 °C/min) in a microwave environment is discussed. Detailed data on the densification, grain growth, and grain size uniformity as a function of heating rate are presented. With increasing heating rate, the grain size decreased while grain size uniformity increased. At extremely high heating rates, high density can be achieved with almost complete suppression of grain growth. Ultrarapid microwave heating of ZnO also enhanced densification rates by up to 4 orders of magnitude compared to slow microwave heating. The results indicate that the densification mechanisms are different for slow and rapid heating rates. Since the mechanical, thermal, dielectric, and optical properties of ceramics depend on microstructure, ultrarapid heating may lead to advanced ceramics with tailored microstructure and enhanced properties.

Comparing fast inductive tempering and conventional tempering: Effects on microstructure and mechanical properties

2018 ◽  
Vol 115 (4) ◽  
pp. 407 ◽  
Author(s):  
Annika Eggbauer Vieweg ◽  
Gerald Ressel ◽  
Peter Raninger ◽  
Petri Prevedel ◽  
Stefan Marsoner ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Impact Energy ◽  
Charpy Impact ◽  
Heat Treating ◽  
Processing Route ◽  
High Heating Rate ◽  
Heating Rates ◽  
High Heating ◽  
Tempering Treatment ◽  
Carbide Distribution

Induction heating processes are of rising interest within the heat treating industry. Using inductive tempering, a lot of production time can be saved compared to a conventional tempering treatment. However, it is not completely understood how fast inductive processes influence the quenched and tempered microstructure and the corresponding mechanical properties. The aim of this work is to highlight differences between inductive and conventional tempering processes and to suggest a possible processing route which results in optimized microstructures, as well as desirable mechanical properties. Therefore, the present work evaluates the influencing factors of high heating rates to tempering temperatures on the microstructure as well as hardness and Charpy impact energy. To this end, after quenching a 50CrMo4 steel three different induction tempering processes are carried out and the resulting properties are subsequently compared to a conventional tempering process. The results indicate that notch impact energy raises with increasing heating rates to tempering when realizing the same hardness of the samples. The positive effect of high heating rate on toughness is traced back to smaller carbide sizes, as well as smaller carbide spacing and more uniform carbide distribution over the sample.

Probing boron thermite energy release at rapid heating rates

2021 ◽  
Vol 231 ◽  
pp. 111491
Author(s):  
Jennifer L. Gottfried ◽  
Elliot R. Wainwright ◽  
Sidi Huang ◽  
Yue Jiang ◽  
Xiaolin Zheng
Keyword(s):  
Energy Release ◽  
Rapid Heating ◽  
Heating Rates

Effect of low and high heating rates on reaction path of Ni(V)/Al multilayer

2017 ◽  
Vol 193 ◽  
pp. 244-252 ◽  
Author(s):  
Łukasz Maj ◽  
Jerzy Morgiel ◽  
Maciej Szlezynger ◽  
Piotr Bała ◽  
Grzegorz Cios
Keyword(s):  
Reaction Path ◽  
Heating Rates ◽  
High Heating

A FUNDAMENTAL STUDY ON THE COMBUSTION CHARACTERISTICS OF MUNICIPAL WASTE PLASTICS UNDER HIGH HEATING RATES

1995 ◽  
Author(s):  
Θωμαή Παναγιώτου
Keyword(s):  
Combustion Characteristics ◽  
Municipal Waste ◽  
Waste Plastics ◽  
Heating Rates ◽  
Fundamental Study ◽  
High Heating

ΑΥΤΗ Η ΕΡΓΑΣΙΑ ΕΙΝΑΙ ΜΙΑ ΒΑΣΙΚΗ ΕΡΕΥΝΑ ΕΠΑΝΩ ΣΤΗΝ ΚΑΥΣΗ ΠΛΑΣΤΙΚΩΝ ΠΟΥ ΒΡΙΣΚΟΝΤΑΙ ΣΤΑ ΑΠΟΡΡΙΜΑΤΑ (ΠΟΛΥ-ΣΤΥΡΕΝΙΟ (PS), ΠΟΛΥ-ΕΘΥΛΕΝΙΟ (ΡΕ) ΚΑΙ PVC). ΣΦΑΙΡΙΚΑ ΣΩΜΑΤΙΔΙΑ ΠΛΑΣΤΙΚΩΝ ΙΣΟΥ ΜΕΓΕΘΟΥΣ ΔΗΜΙΟΥΡΓΗΘΗΚΑΝ ΣΤΟ ΕΡΓΑΣΤΗΡΙΟ ΚΑΙ ΚΑΗΚΑΝ ΕΝΑ, ΕΝΑ ΣΕ ΗΛΕΚΤΡΙΚΟ ΦΟΥΡΝΟ ΚΑΙ ΘΕΡΜΟΚΡΑΣΙΕΣ 1040 -1400 Κ. Η ΚΑΥΣΗ ΤΩΝ ΣΩΜΑΤΙΔΙΩΝ ΜΕΛΕΤΗΘΗΚΕ ΜΕ ΕΝΑ ΤΡΙΧΡΩΜΑΤΙΚΟ ΠΥΡΟΜΕΤΡΟ ΚΑΙ ΜΙΑ ΥΨΗΛΗΣ ΤΑΧΗΤΗΤΑΣ ΚΙΝΗΜΑΤΟΓΡΑΦΙΚΗ ΜΗΧΑΝΗ, ΩΣΤΕ ΝΑ ΣΥΛΛΕΧΘΟΥΝ ΟΙ ΕΞΗΣ ΠΛΗΡΟΦΟΡΙΕΣ: Α) Ο ΧΡΟΝΟΣ ΤΗΣ ΚΑΥΣΗΣ, Β) ΤΟ ΕΙΔΟΣ ΤΗΣ ΚΑΥΣΗΣ (ΟΜΟΙΟΓΕΝΗΣ Η ΕΤΕΡΟΓΕΝΗΣ), Γ) ΤΟ ΠΑΧΟΣ ΤΗΣ ΦΛΟΓΑΣ ΚΑΙ Δ) Η ΤΑΧΥΤΗΤΑ ΠΤΩΣΗΣ ΤΩΝ ΣΩΜΑΤΙΔΙΩΝ. ΟΙ ΠΛΗΡΟΦΟΡΙΕΣ ΑΥΤΕΣ ΧΡΗΣΙΜΟΠΟΙΗΘΗΚΑΝ ΓΙΑ ΤΟΝ ΥΠΟΛΟΓΙΣΜΟ ΤΗΣ ΣΤΙΓΜΙΑΙΑΣ ΠΕΡΙΕΚΤΙΚΟΤΗΤΑΣ ΤΗΣ ΦΛΟΓΑΣ ΣΕ ΑΙΘΑΛΗ ΚΑΙ ΤΗΣ ΠΡΩΤΕΥΟΥΣΑΣ ΦΥΣΙΚΗΣ ΚΑΙ ΧΗΜΙΚΗΣ ΔΙΕΡΓΑΣΙΑΣ ΚΑΤΑ ΤΗΝ ΚΑΥΣΗ ΤΩΝ ΣΩΜΑΤΙΔΙΩΝ. ΚΑΘΕ ΥΛΙΚΟ ΠΑΡΟΥΣΙΑΣΕ ΜΟΝΑΔΙΚΑ ΧΑΡΑΚΤΗΡΙΣΤΙΚΑ ΚΑΥΣΗΣ. ΟΙ ΦΛΟΓΕΣ ΤΩΝ PVC ΣΩΜΑΤΙΔΙΩΝ ΕΙΧΑΝ ΤΗΝ ΜΕΓΑΛΥΤΕΡΗ ΠΕΡΙΕΚΤΙΚΟΤΗΤΑ ΣΕ ΑΙΘΑΛΗ, ΕΝΩ ΤΩΝ ΡΕ ΤΗΝ ΜΙΚΡΟΤΕΡΗ. Η ΤΑΧΥΤΗΤΑ ΚΑΥΣΗΣ ΤΩΝ PS ΣΩΜΑΤΙΔΙΩΝ ΒΡΕΘΗΚΕ ΟΤΙ ΕΞΑΡΤΑΤΑΙ ΑΠΟ ΤΗΝ ΤΑΧΥΤΗΤΑ ΔΙΑΧΥΣΗΣ ΣΤΗΝ ΑΕΡΙΑ ΦΑΣΗ, ΕΝΩ ΤΩΝ ΡΕ ΑΠΟ ΤΗΝ ΤΑΧΥΤΗΤΑ ΠΥΡΟΛΥΣΗΣ ΤΩΝ ΣΩΜΑΤΙΔΙΩΝ. Η ΑΝΑΦΛΕΞΗ ΤΩΝ PVC ΣΩΜΑΤΙΔΙΩΝ ΕΜΠΟΔΙΣΤΗΚΕ ΑΠΟ ΤΗΝ ΥΠΑΡΞΗ ΤΗΣ ΧΛΩΡΙΝΗΣ ΠΟΥ ΔΙΕΦΥΓΕ ΑΡΧΙΚΑ. ΟΤΑΝ Η ΚΑΥΣΗ ΑΡΧΙΣΕ, ΔΗΜΙΟΥΡΓΗΘΗΚΕ ΜΙΑ ΠΑΧΙΑ ΚΑΙ ΠΡΟΑΝΑΜΙΓΜΕΝΗ ΦΛΟΓΑ ΓΥΡΩΑΠΟ ΤΟ ΣΩΜΑΤΙΔΙΟ.

PTFE–Al2O3 reactive interaction at high heating rates

2014 ◽  
Vol 119 (1) ◽  
pp. 245-251 ◽  
Author(s):  
M. A. Hobosyan ◽  
Kh. G. Kirakosyan ◽  
S. L. Kharatyan ◽  
K. S. Martirosyan
Keyword(s):  
Heating Rates ◽  
High Heating ◽  
Reactive Interaction
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