The Use of Ammonium Carbamate as a High Energy Density Thermal Energy Storage Material

2011 ◽  
Vol 1325 ◽  
Author(s):  
Joel E. Schmidt ◽  
Douglas S. Dudis ◽  
Douglas J. Miller
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
Elevated Temperatures ◽  
High Energy ◽  
Heat Fluxes ◽  
High Energy Density ◽  
Low Grade ◽  
Temperature Range ◽  
Ammonium Carbamate ◽  
Thermally Conductive

ABSTRACTPhase change materials (PCMs) often have higher specific energy storage capacities at elevated temperatures. Thermal management (TM) systems capable of handling high heat fluxes in the temperature range from 20–100°C are necessary but lacking. State of the art PCMs in this temperature range are usually paraffin waxes with energy densities on the order of a few hundred kJ/kg or ice slurries with energy densities of the same magnitude. However, for applications where system weight and size are limited, it is necessary to improve this energy density by at least an order of magnitude. The compound ammonium carbamate, [NH4][H2NCOO], is a solid formed from the reaction of ammonia and carbon dioxide which endothermically decomposes back to CO2 and NH3 in the temperature range 20-100°C with an enthalpy of decomposition of ∼2,000 kJ/kg. Various methods to use this material for TM of low-grade, high-flux heat have been evaluated including: bare powder, thermally conductive carbon foams, thermally conductive metal foams, hydrocarbon based slurries, and a slurry in ethylene glycol or propylene glycol. A slurry in glycol is a promising system medium for enhancing heat and mass transfer for TM. Progress on material and system characterization is reported.

Efficient Co-Harvesting of Solar Energy and Low-Grade Heat by Molecular Photoswitches for High Energy Density, Long-Term Stable Solar Thermal Battery

2019 ◽  
Author(s):  
Zhao-Yang Zhang ◽  
Tao LI
Keyword(s):  
Energy Density ◽  
Solar Energy ◽  
High Performance ◽  
High Energy ◽  
Solar Thermal ◽  
High Energy Density ◽  
Low Grade ◽  
Thermal Battery ◽  
Low Grade Heat

Solar energy and ambient heat are two inexhaustible energy sources for addressing the global challenge of energy and sustainability. Solar thermal battery based on molecular switches that can store solar energy and release it as heat has recently attracted great interest, but its development is severely limited by both low energy density and short storage stability. On the other hand, the efficient recovery and upgrading of low-grade heat, especially that of the ambient heat, has been a great challenge. Here we report that solar energy and ambient heat can be simultaneously harvested and stored, which is enabled by room-temperature photochemical crystal-to-liquid transitions of small-molecule photoswitches. The two forms of energy are released together to produce high-temperature heat during the reverse photochemical phase change. This strategy, combined with molecular design, provides high energy density of 320-370 J/g and long-term storage stability (half-life of about 3 months). On this basis, we fabricate high-performance, flexible film devices of solar thermal battery, which can be readily recharged at room temperature with good cycling ability, show fast rate of heat release, and produce high-temperature heat that is >20<sup> o</sup>C higher than the ambient temperature. Our work opens up a new avenue to harvest ambient heat, and demonstrate a feasible strategy to develop high-performance solar thermal battery.

Efficient Co-Harvesting of Solar Energy and Low-Grade Heat by Molecular Photoswitches for High Energy Density, Long-Term Stable Solar Thermal Battery

2019 ◽  
Author(s):  
Zhao-Yang Zhang ◽  
Tao LI
Keyword(s):  
Energy Density ◽  
Solar Energy ◽  
High Performance ◽  
High Energy ◽  
Solar Thermal ◽  
High Energy Density ◽  
Low Grade ◽  
Thermal Battery ◽  
Low Grade Heat

Solar energy and ambient heat are two inexhaustible energy sources for addressing the global challenge of energy and sustainability. Solar thermal battery based on molecular switches that can store solar energy and release it as heat has recently attracted great interest, but its development is severely limited by both low energy density and short storage stability. On the other hand, the efficient recovery and upgrading of low-grade heat, especially that of the ambient heat, has been a great challenge. Here we report that solar energy and ambient heat can be simultaneously harvested and stored, which is enabled by room-temperature photochemical crystal-to-liquid transitions of small-molecule photoswitches. The two forms of energy are released together to produce high-temperature heat during the reverse photochemical phase change. This strategy, combined with molecular design, provides high energy density of 320-370 J/g and long-term storage stability (half-life of about 3 months). On this basis, we fabricate high-performance, flexible film devices of solar thermal battery, which can be readily recharged at room temperature with good cycling ability, show fast rate of heat release, and produce high-temperature heat that is >20<sup> o</sup>C higher than the ambient temperature. Our work opens up a new avenue to harvest ambient heat, and demonstrate a feasible strategy to develop high-performance solar thermal battery.

High energy density aqueous zinc–benzoquinone batteries enabled by carbon cloth with multiple anchoring effects

2021 ◽  
Author(s):  
Zhiqiang Luo ◽  
Silin Zheng ◽  
Shuo Zhao ◽  
Xin Jiao ◽  
Zongshuai Gong ◽  
...  
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
Porous Carbon ◽  
Large Scale ◽  
High Energy ◽  
High Energy Density ◽  
Carbon Cloth ◽  
Anchoring Effects ◽  
High Theoretical Capacity ◽  
Energy Storage Applications

Benzoquinone with high theoretical capacity is anchored on N-plasma engraved porous carbon as a desirable cathode for rechargeable aqueous Zn-ion batteries. Such batteries display tremendous potential in large-scale energy storage applications.

scholarly journals Designing high energy density flow batteries by tuning active-material thermodynamics

RSC Advances ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 5432-5443
Author(s):  
Shyam K. Pahari ◽  
Tugba Ceren Gokoglan ◽  
Benjoe Rey B. Visayas ◽  
Jennifer Woehl ◽  
James A. Golen ◽  
...  
Keyword(s):  
Renewable Energy ◽  
Energy Storage ◽  
Energy Density ◽  
Fossil Fuels ◽  
Active Material ◽  
High Energy ◽  
Theoretical Framework ◽  
High Energy Density ◽  
Density Flow ◽  
The Cost

With the cost of renewable energy near parity with fossil fuels, energy storage is paramount. We report a breakthrough on a bioinspired NRFB active-material, with greatly improved solubility, and place it in a predictive theoretical framework.

scholarly journals Novel Lithium-Ion Capacitor Based on a NiO-rGO Composite

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3586
Author(s):  
Qi An ◽  
Xingru Zhao ◽  
Shuangfu Suo ◽  
Yuzhu Bai
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
Power Density ◽  
High Power ◽  
Specific Capacity ◽  
Lithium Ion ◽  
High Energy ◽  
Cycle Life ◽  
High Energy Density ◽  
Lithium Ion Capacitor

Lithium-ion capacitors (LICs) have been widely explored for energy storage. Nevertheless, achieving good energy density, satisfactory power density, and stable cycle life is still challenging. For this study, we fabricated a novel LIC with a NiO-rGO composite as a negative material and commercial activated carbon (AC) as a positive material for energy storage. The NiO-rGO//AC system utilizes NiO nanoparticles uniformly distributed in rGO to achieve a high specific capacity (with a current density of 0.5 A g−1 and a charge capacity of 945.8 mA h g−1) and uses AC to provide a large specific surface area and adjustable pore structure, thereby achieving excellent electrochemical performance. In detail, the NiO-rGO//AC system (with a mass ratio of 1:3) can achieve a high energy density (98.15 W h kg−1), a high power density (10.94 kW kg−1), and a long cycle life (with 72.1% capacity retention after 10,000 cycles). This study outlines a new option for the manufacture of LIC devices that feature both high energy and high power densities.

scholarly journals Development on Thermochemical Energy Storage Based on CaO-Based Materials: A Review

2018 ◽  
Vol 10 (8) ◽  
pp. 2660 ◽  
Author(s):  
Yi Yuan ◽  
Yingjie Li ◽  
Jianli Zhao
Keyword(s):  
Renewable Energy ◽  
Energy Storage ◽  
Energy Density ◽  
Circulating Fluidized Bed ◽  
High Energy ◽  
High Energy Density ◽  
Hydration Reaction ◽  
Initial Sample ◽  
Storage Performance ◽  
Low Activity

The intermittent and inconsistent nature of some renewable energy, such as solar and wind, means the corresponding plants are unable to operate continuously. Thermochemical energy storage (TES) is an essential way to solve this problem. Due to the advantages of cheap price, high energy density, and ease to scaling, CaO-based material is thought as one of the most promising storage mediums for TES. In this paper, TES based on various cycles, such as CaO/CaCO3 cycles, CaO/Ca(OH)2 cycles, and coupling of CaO/Ca(OH)2 and CaO/CaCO3 cycles, were reviewed. The energy storage performances of CaO-based materials, as well as the modification approaches to improve their performance, were critically reviewed. The natural CaO-based materials for CaO/Ca(OH)2 TES experienced the multiple hydration/dehydration cycles tend to suffer from severe sintering which leads to the low activity and structural stability. It is found that higher dehydration temperature, lower initial sample temperature of the hydration reaction, higher vapor pressure in the hydration reactor, and the use of circulating fluidized bed (CFB) reactors all can improve the energy storage performance of CaO-based materials. In addition, the energy storage performance of CaO-based materials for CaO/Ca(OH)2 TES can be effectively improved by the various modification methods. The additions of Al2O3, Na2Si3O7, and nanoparticles of nano-SiO2 can improve the structural stabilities of CaO-based materials, while the addition of LiOH can improve the reactivities of CaO-based materials. This paper is devoted to a critical review on the development on thermochemical energy storage based on CaO-based materials in the recent years.

scholarly journals High energy density in silver niobate ceramics

2016 ◽  
Vol 4 (44) ◽  
pp. 17279-17287 ◽  
Author(s):  
Ye Tian ◽  
Li Jin ◽  
Hangfeng Zhang ◽  
Zhuo Xu ◽  
Xiaoyong Wei ◽  
...  
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Energy Density ◽  
High Power ◽  
High Energy ◽  
High Energy Density ◽  
Super Capacitors

Solid-state dielectric energy storage is the most attractive and feasible way to store and release high power energy compared to chemical batteries and electrochemical super-capacitors.

Highly interconnected hollow graphene nanospheres as an advanced high energy and high power cathode for sodium metal batteries

2018 ◽  
Vol 6 (21) ◽  
pp. 9846-9853 ◽  
Author(s):  
Ranjith Thangavel ◽  
Aravindaraj G. Kannan ◽  
Rubha Ponraj ◽  
Xueliang Sun ◽  
Dong-Won Kim ◽  
...  
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
High Power ◽  
Storage Systems ◽  
High Energy ◽  
High Energy Density ◽  
Next Generation ◽  
Energy Storage Systems ◽  
Sodium Metal ◽  
Energy Demands

Developing sodium based energy storage systems that retain high energy density at high power along with stable cycling is of paramount importance to meet the energy demands of next generation applications.

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