scholarly journals Thermo-Mechanical behavior at Nano-Scale and Size Effects in Shape Memory Alloys

2011 ◽  
Vol 1297 ◽  
Author(s):  
Jose San Juan ◽  
Maria L. Nó ◽  
Christopher A. Schuh

ABSTRACTShape Memory Alloys (SMA) undergo reversible martensitic transformation in response to changes in temperature or applied stress, exhibiting specific properties of superelasticity and shape memory. At present there is a high scientific and technological interest to develop these properties at small scale, to apply SMA as sensors and actuators in MEMS technologies. In order to study the thermo-mechanical properties of SMA at micro and nano scale, instrumented nano indentation is being widely used for nano compression tests. By using this technique, superelasticity and shape memory at the nano-scale has been demonstrated in micro and nano pillars of Cu-Al-Ni SMA. However the martensitic transformation seems to exhibit a different behavior at small scale than in bulk materials and a size effect on superelasticity has been recently reported. In the present work we will overview the thermo-mechanical properties of Cu-Al-Ni SMA at the nano-scale, with special emphasis on size effects. Finally, the above commented size effects will be discussed on the light of the microscopic mechanisms controlling the martensitic transformation at nano scale.

2013 ◽  
Vol 1581 ◽  
Author(s):  
Lifeng Liu ◽  
Yumei Zhou ◽  
Lan Lv

ABSTRACTThe transformation plateau on the strain-stress curve is the characteristic of superelasticity of bulk shape memory alloys upon tension/compression loading. However, recent studies show that such transformation plateau is hard to see when the sample size of shape memory alloys decreases to submicrons. In order to see what happened in such small scale samples during loading, in-situ compression test has been done with single crystal Cu-14.2Al-4.0Ni (wt %) submicron pillars. Our in-situ observation during compression demonstrates that the stress-induced martensitic transformation indeed occurs in submicron pillars, but is not suppressed. Furthermore, the transformation proceeds in a sequential nucleation-growth-nucleation dominated mode, but not the transient way like that in bulk materials. As a result, the stress keeps increasing throughout the transformation and no obvious transformation plateau can be detected. However, the underlying reason for such contrast transformation behaviors between our submicron pillars and bulk materials still needs further investigation.


2017 ◽  
Vol 10 (01) ◽  
pp. 1740003 ◽  
Author(s):  
I. López-Ferreño ◽  
J. San Juan ◽  
T. Breczewski ◽  
G. A. López ◽  
M. L. Nó

Shape memory alloys (SMAs) have attracted much attention in the last decades due to their thermo-mechanical properties such as superelasticity and shape memory effect. Among the different families of SMAs, Cu–Al–Ni alloys exhibit these properties in a wide range of temperatures including the temperature range of 100–200[Formula: see text]C, where there is a technological demand of these functional materials, and exhibit excellent behavior at small scale making them more competitive for applications in Micro Electro-Mechanical Systems (MEMS). However, polycrystalline alloys of Cu-based SMAs are very brittle so that they show their best thermo-mechanical properties in single-crystal state. Nowadays, conventional Bridgman and Czochralski methods are being applied to elaborate single-crystal rods up to a minimum diameter of 1[Formula: see text]mm, but no works have been reported for smaller diameters. With the aim of synthesizing very thin single-crystals, the Micro-Pulling Down ([Formula: see text]-PD) technique has been applied, for which the capillarity and surface tension between crucible and the melt play a critical role. The [Formula: see text]-PD method has been successfully applied to elaborate several cylindrical shape thin single-crystals down to 200[Formula: see text][Formula: see text]m in diameter. Finally, the martensitic transformation, which is responsible for the shape memory properties of these alloys, has been characterized for different single-crystals. The experimental results evidence the good quality of the grown single-crystals.


2016 ◽  
Vol 72 ◽  
pp. 30-35 ◽  
Author(s):  
G.C. Wang ◽  
K.P. Hu ◽  
Y.X. Tong ◽  
B. Tian ◽  
F. Chen ◽  
...  

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