The Adsorption and Chemistry of Tripropyl phosphate (TPP) into Microporous and Mesoporous NaX Zeolites

2011 ◽  
Vol 1304 ◽  
Author(s):  
Qingguo Meng ◽  
David C. Doetschman ◽  
Apostolos K. Rizos ◽  
Min-Hong Lee ◽  
Jürgen T. Schulte ◽  
...  
Keyword(s):  
Solid State ◽  
Structural Properties ◽  
Nmr Spectra ◽  
Nitrogen Adsorption ◽  
X Ray Diffraction ◽  
X Ray ◽  
Nax Zeolite ◽  
Stoichiometric Amount ◽  
Polydiallyldimethylammonium Chloride ◽  
Adsorption Analysis

ABSTRACTAdsorption and chemistry of tripropylphosphate (TPP) in mesoporous NaX zeolite, which was templated by cationic templated polymer (polydiallyldimethylammonium chloride, PDADMAC) with two different length chains, was investigated. The structural properties of the zeolites were characterized by X-ray diffraction (XRD) and nitrogen adsorption analysis. The chemical activities of different zeolites toward the decomposition of TPP were determined with solid state 31P NMR spectra. After exposure of zeolites to TPP was sufficient and equilibrium was reached, a stoichiometric amount of water was also adsorbed and hydrolysis was observed. The TPP decomposition yields in different NaX zeolites were compared.

Multinuclear NMR and Powder X-ray Diffraction Studies of Si and Sn Clathrates of Alkali Metals: Vacancies, Disorder and Knight Shifts

2001 ◽  
Vol 691 ◽  
Author(s):  
Michael J. Ferguson ◽  
Igor L. Moudrakovski ◽  
Christopher I. Ratcliffe ◽  
John S. Tse
Keyword(s):  
Solid State ◽  
Solid State Nmr ◽  
Nmr Spectra ◽  
Alkali Metals ◽  
Rietveld Analysis ◽  
X Ray Diffraction ◽  
X Ray ◽  
Multinuclear Nmr ◽  
Binary Metal ◽  
Knight Shifts

ABSTRACTThe Structure I type binary metal clathrates of K/Si, Rb/Si and Cs/Sn have been synthesised and studied by powder X-ray diffraction and solid state NMR. Rietveld analysis shows that in all three materials some of the cages are empty, and that in the Cs/Sn clathrate there are vacancies in the Sn framework. The NMR results yield Knight shifts for 29Si and 39K and confirm that the Cs/Sn clathrate is not conducting. Many of the features of the NMR spectra can be understood in terms of the distributions of atom vacancies.

Solid-state structural properties of 2,4,6-trimethoxybenzene derivatives, determined directly from powder X-ray diffraction data in conjunction with other techniques

2006 ◽  
Vol 179 (10) ◽  
pp. 3214-3223 ◽  
Author(s):  
Zhigang Pan ◽  
Mingcan Xu ◽  
Eugene Y. Cheung ◽  
James A. Platts ◽  
Kenneth D.M. Harris ◽  
...  
Keyword(s):  
Solid State ◽  
Structural Properties ◽  
Diffraction Data ◽  
X Ray Diffraction ◽  
X Ray

scholarly journals Solid-state motion of OTeF5− compounds: detection by 19F NMR and IR spectroscopy and correlation with the X-ray structure of an orthorhombic crystalline modification of [C14H19N2+][OTeF5−] (C14H19N2+ = protonated 1,8-bis(dimethylamino)naphthalene)

1989 ◽  
Vol 67 (11) ◽  
pp. 2023-2029 ◽  
Author(s):  
Patti J. Kellett ◽  
Oren P. Anderson ◽  
Steven H. Strauss ◽  
Kent D. Abney
Keyword(s):  
Solid State ◽  
Nmr Spectra ◽  
Room Temperature ◽  
Variable Temperature ◽  
Structural Parameters ◽  
Crystalline Modification ◽  
X Ray Diffraction ◽  
Orthorhombic Space Group ◽  
X Ray ◽  
Triclinic Modification

An orthorhombic crystalline modification of [(PS)H+][OTeF5−] was studied by single crystal X-ray diffraction ((PS)H+ = protonated 1,8-bis(dimethylamino)naphthalene): orthorhombic, space group Cmcm, a = 8.607(2), b = 14.048(3), c = 13.365(2) Å, Z = 4, T = −130 °C. The structural parameters for the anion and cation in this modification (Mod-B) are very similar to those for the previously reported triclinic modification of this salt (Mod-A). However, variable temperature IR spectra for Mod-B suggest that the OTeF5− anion is exhibiting a two-site O/Fax interchange above −70 °C. Solid-state 19F NMR spectra suggest that this interchange may be as rapid as 104–105 s−1 at room temperature. Keywords: crystal structure of protonated 1,8-bis(dimethylamino)naphthalene)pentafluorotellurate(VI), polymorphism, solid state 19FNMR.

Synthesis and Crystal Structures of Dimethylsilylene-Bridged (Amidocyclopentadienyl)dichlorotitanium(IV) Complexes with Various Substituents on the Cyclopentadienyl Ligand

2001 ◽  
Vol 66 (4) ◽  
pp. 605-620 ◽  
Author(s):  
Jaroslav Zemánek ◽  
Petr Štěpnička ◽  
Karla Fejfarová ◽  
Róbert Gyepes ◽  
Ivana Císařová ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Solid State ◽  
Single Crystal ◽  
Spectral Methods ◽  
Nmr Spectra ◽  
Bulky Substituent ◽  
State Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
Cyclopentadienyl Ligand

(Amidocyclopentadienyl)dichlorotitanium(IV) complexes of the general formula [TiCl2{η5:η1(N)-C5(1-SiMe2Nt-Bu-2,3,4-Me3-5-R)}], where R = H (6b), Ph (6c), 4-fluorophenyl (6d) and 1-methylallyl (6e) were synthesized and characterized by spectral methods. Solid-state structure of [TiCl2{η5:η1(N)-C5Me4(SiMe2Nt-Bu)}] (6a) and 6d determined by single-crystal X-ray diffraction showed that variation of the ring substituent R has only a negligible effect on the molecular structure of the complexes. The NMR spectra indicate that motion of the bulky substituent R in compounds 6c, 6d and 6e is hindered below ca 50 °C.

Influence of Zirconium Doped Titanium Oxide towards Photocatalytic Activity of Paraquat

2015 ◽  
Vol 1107 ◽  
pp. 377-382 ◽  
Author(s):  
Nur Afiqah Badli ◽  
Rusmidah Ali ◽  
Leny Yuliati
Keyword(s):  
Photocatalytic Activity ◽  
Working Condition ◽  
Sol Gel ◽  
Nitrogen Adsorption ◽  
Treatment Method ◽  
X Ray Diffraction ◽  
X Ray ◽  
Calcination Temperatures ◽  
Adsorption Analysis ◽  
Scanning Electron

The heterogeneous photocatalyst based on titanium dioxide has been widely investigated as an attractive treatment method for water pollution. Herbicide like paraquat dichloride is one of the toxic organic pollutants which is harmful to human and animal and is still being used in agricultural sectors. TiO2doped with zirconium element has been proven to enhance the photocatalytic activity of TiO2from the previous study. Therefore in this study, photodegradation of paraquat dichloride (1,1-dimethyl-4,4’-bipyridylium dichloride) under UV irradiation was studied using TiO2and Zr doped TiO2prepared via modified sol gel method as photocatalysts. The photocatalytic activity was increased in the presence of zirconium as dopant compared to TiO2. Various calcination temperatures range from 450°C to 1000°C and dopant ratio (10:90, 20:80 and 30:70) were applied to optimize the working condition. Significant enhancement was obtained using Zr doped TiO2(20:80) calcined at 750°C which gave 79.63% degradation of paraquat compared to TiO2calcined at 450°C and 750°C which were 22.31% and 11.57%. X-ray diffraction (XRD) diffratogram of Zr doped TiO2photocatalyst showed a mixture of anatase/rutile TiO2crystalline structures at 750°C. Nanosized photocatalyst with spherical morphology was observed by Field Emission Scanning Electron Microscopy (FESEM). The surface area measured by nitrogen adsorption analysis showed an increment from 8.43m2/g to 46.35m2/g compared to undoped catalyst calcined at 450°C.

Structures of the 2:1 adducts of benzyne with 2-methylanisole and benzene

2007 ◽  
Vol 85 (7-8) ◽  
pp. 461-465
Author(s):  
Christopher O Bender ◽  
René T Boeré ◽  
Peter W Dibble ◽  
Ryan T McKay
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Gas Phase ◽  
Nmr Spectra ◽  
X Ray Diffraction ◽  
Dft Methods ◽  
X Ray ◽  
X Ray Crystallography ◽  
H Nmr ◽  
Data Points

The 2:1 adduct of benzyne with 2-methylanisole is shown to have the bisbenzotricyclic structure 6,6a,11,11a-tetrahydro-5-methoxy-6-methyl-5,6,11-metheno-5H-benzo[a]fluorene by a single-crystal X-ray diffraction study (C20H18O: Pca21, a = 15.0497(17), b = 9.87783(11), c = 9.6846(11); Z = 4; 1672 data points, R1 = 0.0325). This structure is compared to an unpublished crystal structure of the parent hydrocarbon 6,6a,11,11a-tetrahydro-5,6,11-metheno-5H-benzo[a]fluorene, C18H14. Both structures have also been computed by DFT methods at the B3LYP/6-311(d,p) level of theory. Bond distances and angles between the solid-state measurements and gas-phase calculations are found to agree well; average deviations are well below 1%. The 1H NMR spectra show surprisingly small 3JHH couplings in the central tricyclic cage, but can be assigned using 2D spectroscopy.Key words: Hydrocarbon cages, strained rings, cyclopropane, X-ray crystallography, NMR.

The Collagenic Molecular Structural Unit of Solid State Complexes

1971 ◽  
Vol 29 ◽  
pp. 478-479
Author(s):  
Kenneth M. Richter ◽  
John A. Schilling
Keyword(s):  
Molecular Weight ◽  
Solid State ◽  
Structural Unit ◽  
X Ray Diffraction ◽  
X Ray ◽  
Naoh Treatment

The structural unit of solid state collagen complexes has been reported by Porter and Vanamee via EM and by Cowan, North and Randall via x-ray diffraction to be an ellipsoidal unit of 210-270 A. length by 50-100 A. diameter. It subsequently was independently demonstrated by us in dog tendon, dermis, and induced complexes. Its detailed morphologic, dimensional and molecular weight (MW) aspects have now been determined. It is pear-shaped in long profile with m diameters of 57 and 108 A. and m length of 263 A. (Fig. 1, tendon, KMnO4 fixation, Na-tungstate; Fig. 2a, schematic of unit in long, C, and x-sectional profiles of its thin, xB, and bulbous, xA portions; Fig. 2b, tendon essentially unmodified by ether and 0.4 N NaOH treatment, Na-tungstate). The unit consists of a uniquely coild cable, c, of ṁ 22.9 A. diameter and length of 2580-3316 A. The cable consists of three 2nd-strands, s, each of m 10.6 A.

TEM studies of solid-state reactions in sputter-deposited Nb/Al multilayer thin films

1996 ◽  
Vol 54 ◽  
pp. 1020-1021
Author(s):  
F. Ma ◽  
S. Vivekanand ◽  
K. Barmak ◽  
C. Michaelsen
Keyword(s):  
Thin Films ◽  
Solid State ◽  
Stoichiometric Composition ◽  
Analytical Electron Microscopy ◽  
Grain Structure ◽  
Solid State Reactions ◽  
Multilayer Thin Films ◽  
X Ray Diffraction ◽  
X Ray ◽  
Sputter Deposited

Solid state reactions in sputter-deposited Nb/Al multilayer thin films have been studied by transmission and analytical electron microscopy (TEM/AEM), differential scanning calorimetry (DSC) and X-ray diffraction (XRD). The Nb/Al multilayer thin films for TEM studies were sputter-deposited on (1102)sapphire substrates. The periodicity of the films is in the range 10-500 nm. The overall composition of the films are 1/3, 2/1, and 3/1 Nb/Al, corresponding to the stoichiometric composition of the three intermetallic phases in this system.Figure 1 is a TEM micrograph of an as-deposited film with periodicity A = dA1 + dNb = 72 nm, where d's are layer thicknesses. The polycrystalline nature of the Al and Nb layers with their columnar grain structure is evident in the figure. Both Nb and Al layers exhibit crystallographic texture, with the electron diffraction pattern for this film showing stronger diffraction spots in the direction normal to the multilayer. The X-ray diffraction patterns of all films are dominated by the Al(l 11) and Nb(l 10) peaks and show a merging of these two peaks with decreasing periodicity.

Fabrication and study the effect of the laser on the properties of the compound Tl2-xHgxBa2-ySryCa2Cu3O10+δ superconductor

2018 ◽  
pp. 168
Author(s):  
A. Kareem Dahash Ali ◽  
Nihad Ali Shafeek
Keyword(s):  
Transition Temperature ◽  
Solid State ◽  
Hydrostatic Pressure ◽  
Electrical Properties ◽  
Co2 Laser ◽  
Temperature Shift ◽  
Unit Cell ◽  
X Ray Diffraction ◽  
X Ray ◽  
Structural And Electrical Properties

This study included the fabrication of    compound (Tl2-xHgxBa2-ySryCa2Cu3O10+δ) in a manner solid state and under hydrostatic pressure ( 8 ton/cm2) and temperature annealing(850°C), and determine the effect of the laser on the structural and electrical properties elements in the compound, and various concentrations of x where (x= 0.1,0.2,0.3 ). Observed by testing the XRD The best ratio of compensation for x is 0.2 as the value of a = b = 5.3899 (A °), c = 36.21 (A °) show that the installation of four-wheel-based type and that the best temperature shift is TC= 142 K  .When you shine a CO2 laser on the models in order to recognize the effect of the laser on these models showed the study of X-ray diffraction of these samples when preparing models with different concentrations of the values ​​of x, the best ratio of compensation is 0.2 which showed an increase in the values ​​of the dimensions of the unit cell a=b = 5.3929 (A °), c = 36.238 (A°). And the best transition temperature after shedding laser is TC=144 K. 

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