Self-Assembly of a Water-Soluble Tricyclic Heterocycle into J-Type Rosette Nanotubes

2011 ◽  
Vol 1312 ◽  
Author(s):  
Gabor Borzsonyi ◽  
Rachel L. Beingessner ◽  
Takeshi Yamazaki ◽  
Jae-Young Cho ◽  
Andrew J. Myles ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Self Assembly ◽  
Pyridine Ring ◽  
Molecular Wires ◽  
Water Soluble ◽  
Hydrogen Bond Donor ◽  
Electrically Conducting ◽  
Rosette Nanotubes ◽  
Donor Acceptor ◽  
Inner Diameter

ABSTRACTThe synthesis and self-assembly of a water-soluble, tricyclic, self-complementary heterocycle that features the hydrogen bond donor-acceptor arrays of both guanine (G) and cytosine (C) juxtaposed between a pyridine ring is presented. In solution, this tricycle, which has been termed xK1, self-assembles into Rosette Nanotubes (RNTs) that have an inner diameter of 1.4 nm. Unlike the RNTs formed from the bicyclic congener K1, we demonstrate that xK1 with its extended ð system, forms a J-type RNT assembly determined through UV-Vis, CD and fluorescence spectroscopy experiments. This observation brings the possibility of developing electrically conducting RNTs for applications in the areas of photovoltaics and molecular wires.

Identifying Selective Host–Guest Interactions Based on Hydrogen Bond Donor–Acceptor Pattern in Functionalized Al-MIL-53 Metal–Organic Frameworks

2013 ◽  
Vol 117 (39) ◽  
pp. 19991-20001 ◽  
Author(s):  
Julia Wack ◽  
Renée Siegel ◽  
Tim Ahnfeldt ◽  
Norbert Stock ◽  
Luís Mafra ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Metal Organic Frameworks ◽  
Hydrogen Bond Donor ◽  
Donor Acceptor ◽  
Metal Organic

The heterobifunctional ligand 5-[4-(1,2,4-triazol-4-yl)phenyl]-1H-tetrazole and its role in the construction of a CdIImetal–organic chain structure

2012 ◽  
Vol 68 (10) ◽  
pp. m291-m294
Author(s):  
Andrey B. Lysenko
Keyword(s):  
Hydrogen Bond ◽  
Three Dimensional ◽  
Organic Ligand ◽  
Chain Structure ◽  
Polar Space ◽  
Hydrogen Bond Donor ◽  
Donor Acceptor ◽  
A Chain ◽  
Water Ligands ◽  
Hydrogen Bonded

5-[4-(1,2,4-Triazol-4-yl)phenyl]-1H-tetrazole, C9H7N7, (I), an asymmetric heterobifunctional organic ligand containing triazole (tr) and tetrazole (tz) termini linked directly through a 1,4-phenylene spacer, crystallizes in the polar space groupPc. The heterocyclic functions, serving as single hydrogen-bond donor (tz) or acceptor (tr) units, afford hydrogen-bonded zigzag chains with no crystallographic centre of inversion. In the structure ofcatena-poly[[diaquacadmium(II)]bis{μ2-5-[4-(1,2,4-triazol-4-yl)phenyl]tetrazol-1-ido-κ2N1:N1′}], [Cd(C9H6N7)2(H2O)2]n, (II), the CdIIdication resides on a centre of inversion in an octahedral {N4O2} environment. In the equatorial plane, the CdIIpolyhedron is built up from four N atoms of two kinds, namely oftrans-coordinating tr and tz fragments [Cd—N = 2.2926 (17) and 2.3603 (18) Å], and the coordinating aqua ligands occupy the two apical sites. The metal centres are separated at a distance of 11.1006 (7) Å by means of the double-bridging tetrazolate anion,L−, forming a chain structure. The water ligands and tz fragments interact with one another, like a double hydrogen-bond donor–acceptor synthon, leading to a hydrogen-bonded three-dimensional array.

A Straightforward Synthesis of Diverse Nickel Dithiolene Complexes Appended with Hydrogen-Bond Donor/Acceptor Groups

2005 ◽  
Vol 44 (10) ◽  
pp. 3380-3382 ◽  
Author(s):  
Stéphane A. Baudron ◽  
Narcis Avarvari ◽  
Patrick Batail
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bond Donor ◽  
Donor Acceptor

scholarly journals An Investigation of Five Component [3+2] Self-Assembled Cage Formation Using amidinium...carboxylate Hydrogen Bonds

2021 ◽  
Author(s):  
Chriso Thomas ◽  
Emer Foyle ◽  
Samuel Walker ◽  
Nicholas White
Keyword(s):  
Hydrogen Bond ◽  
Self Assembly ◽  
Solvent Mixtures ◽  
Hydrogen Bond Donor ◽  
Cage Structure ◽  
Hydrogen Bond Acceptor ◽  
X Ray ◽  
Hydrogen Bonding Interactions ◽  
The Individual ◽  
And Diffusion

The assembly of hydrogen bonded cages using amidinium∙∙∙carboxylate hydrogen bonding interactions was investigated. A new tris-amidinium hydrogen bond donor tecton based on a tetraphenylmethane scaffold was prepared and its self–assembly with the terephthalate anion studied, and a new tricarboxylate hydrogen bond acceptor tecton was synthesized and its assembly with the 1,3-benzenebis(amidinium) hydrogen bond donor explored. In both cases, molecular modelling indicated that the formation of the cages was geometrically feasible and 1H NMR spectroscopic evidence was consistent with interactions between the components in competitive d6- DMSO solvent mixtures. DOSY NMR spectroscopy of both systems indicated that both components diffuse at the same rate as each other, and diffusion coefficients were consistent with cage formation, and with the formation of assemblies significantly larger than the individual components. An X-ray crystal structure showed that one of the assemblies did not have the desired cage structure in the solid state

scholarly journals Conformation-Dependent Photophysics of Bifunctional Hydrogen Bond Donor/Acceptor Molecules

2007 ◽  
Vol 112 (Supplement) ◽  
pp. S-105-S-120 ◽  
Author(s):  
M. Kijak ◽  
I. Petkova ◽  
M. Toczek ◽  
G. Wiosna-Sałyga ◽  
A. Zielińska ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bond Donor ◽  
Donor Acceptor ◽  
Acceptor Molecules

scholarly journals Exploiting the Hydrogen Bond Donor/Acceptor Properties of PN‐Heterocycles: Selective Anion Receptors for Hydrogen Sulfate

2019 ◽  
Vol 131 (12) ◽  
pp. 3974-3978 ◽  
Author(s):  
Chun‐Lin Deng ◽  
Jeremy P. Bard ◽  
Jessica A. Lohrman ◽  
Joshua E. Barker ◽  
Lev N. Zakharov ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Anion Receptors ◽  
Hydrogen Sulfate ◽  
Hydrogen Bond Donor ◽  
Donor Acceptor
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