Synthesis and characterization of hybrid CdS/MEH-PPV nanocomposites for photovoltaic applications

2011 ◽  
Vol 1322 ◽  
Author(s):  
Anna M. Laera ◽  
Vincenzo Resta ◽  
Emanuela Piscopiello ◽  
Monica Schioppa ◽  
Leander Tapfer
Keyword(s):  
Annealing Temperature ◽  
Particle Density ◽  
Semiconductor Nanocrystals ◽  
Semiconducting Polymer ◽  
High Particle ◽  
Photovoltaic Applications ◽  
The Matrix ◽  
Synthesis Procedure ◽  
Very High

ABSTRACTInorganic-organic nanocomposites, with II-VI or III-V semiconductor nanocrystals (NCs) embedded in semiconducting polymer matrix, are very promising materials for photovoltaic applications.Here, we present an effective and easy synthesis procedure to obtain a hybrid nanocomposite with CdS NCs dispersed in poly[2-methoxy-5-(2-(2’-ethyl-hexyloxy)-1,4-phenylene vinylene] (MEH-PPV) conjugated polymer. CdS NCs are synthesized directly within the matrix through the decomposition of a suitable unimolecular precursor dispersed homogeneously in the polymer.We show that CdS NCs are formed at low annealing temperature avoiding structural damages and without affecting the functional properties of the MEH-PPV polymer. The NCs diameter ranges between 1.5nm and 4nm depending on the annealing temperature. In addition, no coalescence phenomena of CdS NCs were noticed in TEM observations even at very high particle density (40 wt %).

Dislocation structures around SiO2 Particles in aged Cu-Cr-SiO2

1978 ◽  
Vol 36 (1) ◽  
pp. 594-595
Author(s):  
N.J. Long ◽  
M.H. Loretto ◽  
C.H. Lloyd
Keyword(s):  
Flow Stress ◽  
Single Crystals ◽  
Room Temperature ◽  
Thin Foil ◽  
Age Hardening ◽  
Dispersion Strengthening ◽  
Accurate Picture ◽  
The Matrix ◽  
Very High ◽  
Good Agreement

IntroductionThere have been several t.e.m. studies (1,2,3,4) of the dislocation arrangements in the matrix and around the particles in dispersion strengthened single crystals deformed in single slip. Good agreement has been obtained in general between the observed structures and the various theories for the flow stress and work hardening of this class of alloy. There has been though some difficulty in obtaining an accurate picture of these arrangements in the case when the obstacles are large (of the order of several 1000's Å). This is due to both the physical loss of dislocations from the thin foil in its preparation and to rearrangement of the structure on unloading and standing at room temperature under the influence of the very high localised stresses in the vicinity of the particles (2,3).This contribution presents part of a study of the Cu-Cr-SiO2 system where age hardening from the Cu-Cr and dispersion strengthening from Cu-Sio2 is combined.

TEM characterization of reaction zone in a SiC fiber-reinforced titanium alloy

1988 ◽  
Vol 46 ◽  
pp. 738-739
Author(s):  
G. Das ◽  
R. E. Omlor
Keyword(s):  
Titanium Alloys ◽  
Reaction Zone ◽  
Carbon Layer ◽  
Fiber Reinforced ◽  
Reaction Products ◽  
Sic Fibers ◽  
Sic Fiber ◽  
The Matrix ◽  
Immense Potential

Fiber reinforced titanium alloys hold immense potential for applications in the aerospace industry. However, chemical reaction between the fibers and the titanium alloys at fabrication temperatures leads to the formation of brittle reaction products which limits their development. In the present study, coated SiC fibers have been used to evaluate the effects of surface coating on the reaction zone in the SiC/IMI829 system.IMI829 (Ti-5.5A1-3.5Sn-3.0Zr-0.3Mo-1Nb-0.3Si), a near alpha alloy, in the form of PREP powder (-35 mesh), was used a茸 the matrix. CVD grown AVCO SCS-6 SiC fibers were used as discontinuous reinforcements. These fibers of 142μm diameter contained an overlayer with high Si/C ratio on top of an amorphous carbon layer, the thickness of the coating being ∽ 1μm. SCS-6 fibers, broken into ∽ 2mm lengths, were mixed with IMI829 powder (representing < 0.1vol%) and the mixture was consolidated by HIP'ing at 871°C/0. 28GPa/4h.

Ionized gas kinematics and luminosity profiles of Low-z Lyman Alpha Blobs

2019 ◽  
Vol 15 (S359) ◽  
pp. 413-414
Author(s):  
María P. Agüero ◽  
Rubén Díaz ◽  
Mischa Schirmer
Keyword(s):  
Emission Line ◽  
Galactic Nuclei ◽  
Host Galaxies ◽  
Ionized Gas ◽  
Lyman Alpha ◽  
Gas Kinematics ◽  
The Universe ◽  
Very High ◽  
The Continuum

AbstractThis work is focused on the characterization of the Seyfert-2 galaxies hosting very large, ultra-luminous narrow-line regions (NLRs) at redshifts z = 0.2−0.34. With a space density of 4.4 Gcp−3 at z ∼ 0.3, these “Low Redshift Lyman-α Blob” (LAB) host galaxies are amongst the rarest objects in the universe, and represent an exceptional and short-lived phenomenon in the life cycle of active galactic nuclei (AGNs). We present the study of GMOS spectra for 13 LAB galaxies covering the rest frame spectral range 3700–6700 Å. Predominantly, the [OIII]λ5007 emission line radial distribution is as widespread as that of the continuum one. The emission line profiles exhibit FWHM between 300–700 Km s−1. In 7 of 13 cases a broad kinematical component is detected with FWHM within the range 600–1100 Km s−1. The exceptionally high [OIII]λ5007 luminosity is responsible for very high equivalent width reaching 1500 Å at the nucleus.

scholarly journals Characterization of the Structure, Mechanical Properties and Erosive Resistance of the Laser Cladded Inconel 625-Based Coatings Reinforced by TiC Particles

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2225
Author(s):  
Aleksandra Kotarska ◽  
Tomasz Poloczek ◽  
Damian Janicki
Keyword(s):  
Laser Cladding ◽  
Inconel 625 ◽  
Matrix Composites ◽  
Erosion Rates ◽  
Laser Cladding Process ◽  
Composition Variation ◽  
The Matrix ◽  
Reinforcing Material ◽  
Inconel 625 Superalloy

The article presents research in the field of laser cladding of metal-matrix composite (MMC) coatings. Nickel-based superalloys show attractive properties including high tensile strength, fatigue resistance, high-temperature corrosion resistance and toughness, which makes them widely used in the industry. Due to the insufficient wear resistance of nickel-based superalloys, many scientists are investigating the possibility of producing nickel-based superalloys matrix composites. For this study, the powder mixtures of Inconel 625 superalloy with 10, 20 and 40 vol.% of TiC particles were used to produce MMC coatings by laser cladding. The titanium carbides were chosen as reinforcing material due to high thermal stability and hardness. The multi-run coatings were tested using penetrant testing, macroscopic and microscopic observations, microhardness measurements and solid particle erosive test according to ASTM G76-04 standard. The TiC particles partially dissolved in the structure during the laser cladding process, which resulted in titanium and carbon enrichment of the matrix and the occurrence of precipitates formation in the structure. The process parameters and coatings chemical composition variation had an influence on coatings average hardness and erosion rates.

Mechanical characterization of LM25 alloy matrix composite reinforced with boron carbide

2021 ◽  
pp. 002199832110055
Author(s):  
Zeeshan Ahmad ◽  
Sabah Khan
Keyword(s):  
Tensile Strength ◽  
Boron Carbide ◽  
Mechanical Characterization ◽  
Stir Casting ◽  
Surface Mapping ◽  
Alloy Matrix ◽  
Casting Technique ◽  
The Matrix ◽  
Carbide Particles

Alumnium alloy LM 25 based composites reinforced with boron carbide at different weight fractions of 4%, 8%, and 12% were fabricated by stir casting technique. The microstructures and morphology of the fabricated composites were studied by scanning electron microscopy and energy dispersive spectroscopy. Elemental mapping of all fabricated composites were done to demonstrate the elements present in the matrix and fabricated composites. The results of microstructural analyses reveal homogenous dispersion of reinforcement particles in the matrix with some little amount of clustering found in composites reinforced with 12% wt. of boron carbide. The mechanical characterization is done for both alloy LM 25 and all fabricated composites based on hardness and tensile strength. The hardness increased from 13.6% to 21.31% and tensile strength 6.4% to 22.8% as reinforcement percentage of boron carbide particles increased from 0% to 12% wt. A fractured surface mapping was also done for all composites.

Da eine oder mehrere betroffen …

2020 ◽  
Vol 48 (1) ◽  
pp. 47-100
Author(s):  
Melitta Gillmann
Keyword(s):  
High Frequency ◽  
Formal Language ◽  
Subordinate Clause ◽  
Matrix Clause ◽  
Very High Frequency ◽  
Corpus Study ◽  
Causal Relations ◽  
Legal Texts ◽  
The Matrix ◽  
Very High

AbstractBased on a corpus study conducted using the GerManC corpus (1650–1800), the paper sketches the functional and sociosymbolic development of subordinate clause constructions introduced by the subjunctor da ‘since’ in different text genres. In the second half of the 17th and the first half of the 18th century, the da clauses were characterized by semantic vagueness: Besides temporal, spatial and causal relations, the subjunctor established conditional, concessive, and adversative links between clauses. The corpus study reveals that different genres are crucial to the readings of da clauses. Spatial and temporal usages, for example, occur more often in sermons than in other genres. The conditional reading, in contrast, strongly tends to occur in legal texts, where it displays very high frequency. This could be the reason why da clauses carry indexical meaning in contemporary German and are associated with formal language. Over the course of the 18th century, the causal usages increase in all genres. Surprisingly, these causal da clauses tend to be placed in front of the matrix clause despite the overall tendency of causal clauses to follow the matrix clause.

scholarly journals Halogenated Volatile Organic Compounds in Water Samples and Inorganic Elements Levels in Ores for Characterizing a High Anthropogenic Polluted Area in the Northern Latium Region (Italy)

2021 ◽  
Vol 18 (4) ◽  
pp. 1628
Author(s):  
Mario Vincenzo Russo ◽  
Ivan Notardonato ◽  
Alberto Rosada ◽  
Giuseppe Ianiri ◽  
Pasquale Avino
Keyword(s):  
Organic Compounds ◽  
Mean Value ◽  
Greenhouse Crops ◽  
River Waters ◽  
Liquid Liquid Extraction ◽  
Volatile Organic ◽  
High Concentrations ◽  
Very High ◽  
Inorganic Fraction

This paper shows a characterization of the organic and inorganic fraction of river waters (Tiber and Marta) and ores/soil samples collected in the Northern Latium region of Italy for evaluating the anthropogenic/natural source contribution to the environmental pollution of this area. For organic compounds, organochloride volatile compounds in Tiber and Marta rivers were analyzed by two different clean-up methods (i.e., liquid–liquid extraction and static headspace) followed by gas chromatography–electron capture detector (GC-ECD) analysis. The results show very high concentrations of bromoform (up to 1.82 and 3.2 µg L−1 in Tiber and Marta rivers, respectively), due to the presence of greenhouse crops, and of chloroform and tetrachloroethene, due to the presence of handicrafts installations. For the qualitative and quantitative assessment of the inorganic fraction, it is highlighted the use of a nuclear analytical method, instrumental neutron activation analysis, which allows having more information as possible from the sample without performing any chemical-physical pretreatment. The results have evidenced high levels of mercury (mean value 88.6 µg g−1), antimony (77.7 µg g−1), strontium (12,039 µg g−1) and zinc (103 µg g−1), whereas rare earth elements show levels similar to the literature data. Particular consideration is drawn for arsenic (414 µg g−1): the levels found in this paper (ranging between 1 and 5100 µg g−1) explain the high content of such element (as arsenates) in the aquifer, a big issue in this area.

scholarly journals Reliability Assessment of a Multi-State HVDC System by Combining Markov and Matrix-Based Methods

Energies ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3097
Author(s):  
Roberto Benato ◽  
Antonio Chiarelli ◽  
Sebastian Dambone Sessa
Keyword(s):  
Current System ◽  
Estimation Method ◽  
Reliability Estimation ◽  
Voltage Source ◽  
Voltage Source Converter ◽  
Hvdc System ◽  
Critical Elements ◽  
The Matrix ◽  
The Impact

The purpose of this paper is to highlight that, in order to assess the availability of different HVDC cable transmission systems, a more detailed characterization of the cable management significantly affects the availability estimation since the cable represents one of the most critical elements of such systems. The analyzed case study consists of a multi-terminal direct current system based on both line commutated converter and voltage source converter technologies in different configurations, whose availability is computed for different transmitted power capacities. For these analyses, the matrix-based reliability estimation method is exploited together with the Monte Carlo approach and the Markov state space one. This paper shows how reliability analysis requires a deep knowledge of the real installation conditions. The impact of these conditions on the reliability evaluation and the involved benefits are also presented.

Elaboration and Characterization of Mg-Doped ZnO Thin Films by Thermal Evaporation: Annealing Temperature Effect

2021 ◽  
Author(s):  
Fouaz Lekoui ◽  
Salim Hassani ◽  
Mohammed Ouchabane ◽  
Hocine Akkari ◽  
Driss Dergham ◽  
...  
Keyword(s):  
Thin Films ◽  
Temperature Effect ◽  
Annealing Temperature ◽  
Thermal Evaporation ◽  
Zno Thin Films ◽  
Doped Zno ◽  
Mg Doped
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