Scattering Under Shear: Alignment of a Disordered Bicontinuous Mesophase

2011 ◽  
Vol 1355 ◽  
Author(s):  
Annela M. Seddon ◽  
Gudrun Lötze ◽  
Tomás Plivelic ◽  
Adam M. Squires
Keyword(s):  
Liquid Phase ◽  
Nanostructured Materials ◽  
Protein Crystallization ◽  
Lamellar Phase ◽  
Cubic Phase ◽  
Biological Models ◽  
Two Phase ◽  
Shear Alignment ◽  
Disordered Phase ◽  
Additional Water

ABSTRACTIn this work we demonstrate that the application of shear to a disordered lyoptropic liquid phase formed by a biological lipid, monoolein formed in water and butanediol results in the formation of an aligned lamellar phase. Furthermore we show that if shear is applied to this disordered phase in the presence of additional water, an highly oriented inverse bicontinous cubic phase is created. We suggest that these two phase may have applications as biological models, as templates for nanostructured materials and in improved protein crystallization techniques.

SYNTHESIS OF HYDROGEN IN ACOUSTOPLASMA DISCHARGE IN A LIQUID-PHASE STREAM

2019 ◽  
pp. 42-48 ◽  
Author(s):  
N. A. Bulychev
Keyword(s):  
Liquid Phase ◽  
Organic Compounds ◽  
Electrode Materials ◽  
Solid Phase ◽  
Plasma Discharge ◽  
Raw Material ◽  
Two Phase ◽  
Reduced Pressure ◽  
External Power Source ◽  
Phase Medium

In this paper, the plasma discharge in a high-pressure fluid stream in order to produce gaseous hydrogen was studied. Methods and equipment have been developed for the excitation of a plasma discharge in a stream of liquid medium. The fluid flow under excessive pressure is directed to a hydrodynamic emitter located at the reactor inlet where a supersonic two-phase vapor-liquid flow under reduced pressure is formed in the liquid due to the pressure drop and decrease in the flow enthalpy. Electrodes are located in the reactor where an electric field is created using an external power source (the strength of the field exceeds the breakdown threshold of this two-phase medium) leading to theinitiation of a low-temperature glow quasi-stationary plasma discharge.A theoretical estimation of the parameters of this type of discharge has been carried out. It is shown that the lowtemperature plasma initiated under the flow conditions of a liquid-phase medium in the discharge gap between the electrodes can effectively decompose the hydrogen-containing molecules of organic compounds in a liquid with the formation of gaseous products where the content of hydrogen is more than 90%. In the process simulation, theoretical calculations of the voltage and discharge current were also made which are in good agreement with the experimental data. The reaction unit used in the experiments was of a volume of 50 ml and reaction capacity appeared to be about 1.5 liters of hydrogen per minute when using a mixture of oxygen-containing organic compounds as a raw material. During their decomposition in plasma, solid-phase products are also formed in insignificant amounts: carbon nanoparticles and oxide nanoparticles of discharge electrode materials.

Axial dispersion in the liquid phase in a horizontal two-phase tube reactor

1991 ◽  
Vol 56 (6) ◽  
pp. 1249-1252
Author(s):  
Marie Fialová ◽  
Ctirad Verner ◽  
Lothar Ebner
Keyword(s):  
Liquid Phase ◽  
Flow Regimes ◽  
Basic Flow ◽  
Axial Dispersion ◽  
Two Phase ◽  
Tube Reactor

The characteristics of axial dispersion in the liquid phase were measured for two basic flow regimes in a horizontal two-phase tube reactor. The data obtained indicate that in some flow regions, axial dispersion can be quite significant.

scholarly journals Thermodynamics and Machine Learning Based Approaches for Vapor–Liquid–Liquid Phase Equilibria in n-Octane/Water, as a Naphtha–Water Surrogate in Water Blends

Processes ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 413
Author(s):  
Sandra Lopez-Zamora ◽  
Jeonghoon Kong ◽  
Salvador Escobedo ◽  
Hugo de Lasa
Keyword(s):  
Machine Learning ◽  
Liquid Phase ◽  
Phase Equilibria ◽  
Aspen Plus ◽  
Phase Region ◽  
Two Phase ◽  
Technical Literature ◽  
Phase Liquid ◽  
Liquid Vapor ◽  
Vapor Liquid

The prediction of phase equilibria for hydrocarbon/water blends in separators, is a subject of considerable importance for chemical processes. Despite its relevance, there are still pending questions. Among them, is the prediction of the correct number of phases. While a stability analysis using the Gibbs Free Energy of mixing and the NRTL model, provide a good understanding with calculation issues, when using HYSYS V9 and Aspen Plus V9 software, this shows that significant phase equilibrium uncertainties still exist. To clarify these matters, n-octane and water blends, are good surrogates of naphtha/water mixtures. Runs were developed in a CREC vapor–liquid (VL_ Cell operated with octane–water mixtures under dynamic conditions and used to establish the two-phase (liquid–vapor) and three phase (liquid–liquid–vapor) domains. Results obtained demonstrate that the two phase region (full solubility in the liquid phase) of n-octane in water at 100 °C is in the 10-4 mol fraction range, and it is larger than the 10-5 mol fraction predicted by Aspen Plus and the 10-7 mol fraction reported in the technical literature. Furthermore, and to provide an effective and accurate method for predicting the number of phases, a machine learning (ML) technique was implemented and successfully demonstrated, in the present study.

scholarly journals Exploring the in meso crystallization mechanism by characterizing the lipid mesophase microenvironment during the growth of single transmembrane α-helical peptide crystals

2016 ◽  
Vol 374 (2072) ◽  
pp. 20150125 ◽  
Author(s):  
Leonie van 't Hag ◽  
Konstantin Knoblich ◽  
Shane A. Seabrook ◽  
Nigel M. Kirby ◽  
Stephen T. Mudie ◽  
...  
Keyword(s):  
Crystal Growth ◽  
Self Assembly ◽  
Lamellar Phase ◽  
Cubic Phase ◽  
Supporting Evidence ◽  
X Ray ◽  
X Ray Scattering ◽  
Standard Procedures ◽  
Helical Peptide ◽  
Saxs Analysis

The proposed mechanism for in meso crystallization of transmembrane proteins suggests that a protein or peptide is initially uniformly dispersed in the lipid self-assembly cubic phase but that crystals grow from a local lamellar phase, which acts as a conduit between the crystal and the bulk cubic phase. However, there is very limited experimental evidence for this theory. We have developed protocols to investigate the lipid mesophase microenvironment during crystal growth using standard procedures readily available in crystallography laboratories. This technique was used to characterize the microenvironment during crystal growth of the DAP12-TM peptide using synchrotron small angle X-ray scattering (SAXS) with a micro-sized X-ray beam. Crystal growth was found to occur from the gyroid cubic mesophase. For one in four crystals, a highly oriented local lamellar phase was observed, providing supporting evidence for the proposed mechanism for in meso crystallization. A new observation of this study was that we can differentiate diffraction peaks from crystals grown in meso , from peaks originating from the surrounding lipid matrix, potentially opening up the possibility of high-throughput SAXS analysis of in meso grown crystals. This article is part of the themed issue ‘Soft interfacial materials: from fundamentals to formulation’.

Hydrocyclone Two Phase Flow Experimental Research Based on Fluid Mechanics

2012 ◽  
Vol 625 ◽  
pp. 117-120
Author(s):  
Hui Xu ◽  
Xiao Hong Chen
Keyword(s):  
Numerical Simulation ◽  
Liquid Phase ◽  
Fluid Mechanics ◽  
Production Capacity ◽  
Phase Flow ◽  
Input Flow ◽  
Two Phase ◽  
Output Flow ◽  
Input Pressure ◽  
Solid Liquid

The liquid phase experiment is finished ,and the relation curve of input- pressure and input-flow、output-flow、distributary rate are worked out.We are bout to calculate the production capacity and define the best distribution rate of the operation parameters.At the same time , the solid-liquid phase separating experiment are made too and we conclude the relation curve of input-pressure and consistency 、separating efficiency .Comparing with the numerical simulation ,the result is reasonable.

On the performance of a cascade of turbine rotor tip section blading in wet steam Part 3: Wake traverses

1997 ◽  
Vol 211 (8) ◽  
pp. 639-648 ◽  
Author(s):  
F Bakhtar ◽  
H Mashmoushy ◽  
O C Jadayel
Keyword(s):  
Liquid Phase ◽  
Two Phase Flow ◽  
Turbine Rotor ◽  
Phase Flow ◽  
Wet Steam ◽  
Flow Conditions ◽  
Two Phase ◽  
Blow Down ◽  
The Third ◽  
Phase Mixture

During the course of expansion of steam in turbines the fluid first supercools and then nucleates to become a two-phase mixture. The liquid phase consists of a large number of extremely small droplets which are difficult to generate except by nucleation. To reproduce turbine two-phase flow conditions requires a supply of supercooled vapour which can be achieved under blow-down conditions by the equipment employed. This paper is the third of a set describing an investigation into the performance of a cascade of rotor tip section profiles in wet steam and presents the results of the wake traverses.

scholarly journals The Effect of Salts on the Liquid–Liquid Phase Equilibria of PEG600 + Salt Aqueous Two-Phase Systems

2013 ◽  
Vol 58 (12) ◽  
pp. 3528-3535 ◽  
Author(s):  
Sara C. Silvério ◽  
Oscar Rodríguez ◽  
José A. Teixeira ◽  
Eugénia A. Macedo
Keyword(s):  
Liquid Phase ◽  
Phase Equilibria ◽  
Two Phase ◽  
Aqueous Two Phase Systems ◽  
Phase Systems

Textures of the Hot-Forged Ti6Al4V Alloy

2013 ◽  
Vol 203-204 ◽  
pp. 111-114
Author(s):  
Adam Bunsch ◽  
Wiktoria Ratuszek ◽  
Małgorzata Witkowska ◽  
Joanna Kowalska ◽  
Aneta Łukaszek-Sołek
Keyword(s):  
Deformation Temperature ◽  
Phase State ◽  
Hexagonal Phase ◽  
Ti6al4v Alloy ◽  
The Body ◽  
Cubic Phase ◽  
Body Centered Cubic ◽  
Two Phase ◽  
Different Temperatures

This paper presents the results of the texture investigation in the hexagonal phase and the body-centered cubic  phase of the Ti6Al4V alloy hot-deformed by forging. Forging was performed at two different temperatures on the occurrence of the single  and in the two-phase  +  state. It was found that after deformation both  and  phases are textured and their textures strongly depends on deformation temperature.

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