Developments in characterizing soft matter

MRS Bulletin ◽  
2010 ◽  
Vol 35 (9) ◽  
pp. 702-707 ◽  
Author(s):  
Athene M. Donald

Soft matter—also known as complex fluids—is a field of growing interest and importance, spanning many classes of materials, including polymers, biopolymers, colloids, and liquid crystals. Different approaches for microstructural characterization are more appropriate than those used for hard (and usually fully crystallized) materials such as metals and inorganic materials because of the time and length scales involved. This article discusses a range of techniques applicable to the characterization of soft matter, including environmental scanning electron microscopy (SEM) and microrheology. The former offers two key advantages for this class of material over conventional SEM because it requires neither a high vacuum—which is a problem for hydrated samples—nor that an insulator be coated with a conductive material. Microrheology is well suited to small volumes of fluid with low moduli that may be heterogeneous; it is capable of measuring gelation in real time.

2001 ◽  
Vol 707 ◽  
Author(s):  
Ian C. Bache ◽  
Catherine M. Ramsdale ◽  
D. Steve Thomas ◽  
Ana-Claudia Arias ◽  
J. Devin MacKenzie ◽  
...  

ABSTRACTCharacterising the morphology of thin films for use in device applications requires the ability to study both the structure within the plane of the film, and also through its thickness. Environmental scanning electron microscopy has proved to be a fruitful technique for the study of such films both because contrast can be seen within the film without the need for staining (as is conventionally done for electron microscopy), and because cross-sectional images can be obtained without charging artefacts. The application of ESEM to a particular blend of relevance to photovoltaics is described.


1999 ◽  
Vol 5 (S2) ◽  
pp. 286-287
Author(s):  
Christopher J. Gilpin ◽  
Mohamed S. Baguneid

Environmental scanning electron microscopy (ESEM) has matured into a mainstream technique in many areas of microscopy. Instrumentation has evolved and our understanding of some of the imaging mechanisms has progressed. However the majority of laboratories where ESEMs are located are based around the materials sciences. Despite the fact that ESEM is the only SEM instrument that permits liquid water to be present whilst imaging, the housing of such a microscope in biological EM units has been relatively rare. This authors laboratory is a multi-user EM unit based in a School of Biological Sciences. There exists the opportunity for basic biological scientists, clinical and pre-clinical medical and dental researchers to make use of such a resource. Indeed as the ESEM is housed alongside a conventional high vacuum instrument and a cryo high vacuum instrument there exists the ideal opportunity to carry out comparative studies.This study will examine a range of biological samples using ESEM, cryo SEM and dry high vacuum SEM.


1997 ◽  
Vol 3 (S2) ◽  
pp. 381-382
Author(s):  
Stuart McKernan

The possibility of performing scanning electron microscopy under “environmental” conditions (ESEM); where the specimen does not have to be under high-vacuum conditions, or even coated to make it conductive, has existed for several years[l]. Several different flavors of environmental scanning electron microscope now exist, as well as a newer generation of microscope which is capable of imaging at very low accelerating voltages. Techniques for rapidly freezing hydrated specimens and obtaining very high resolution images from them in the SEM have also been improved recently. As a result of all this innovation, it is now possible to examine many classes of specimens in the SEM that were previously thought to be impossible to image (or at least not worthwhile frying).Among the advantages of the environmental SEM are the fact that images of non-conductive surfaces can be obtained without the necessity for additional sample coating. This can be especially important in dynamic experiments, and hot-stage work, where the presence of a surface coating may substantially affect the samples behavior


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