From Transistors to Lasers and Light-Emitting Diodes

MRS Bulletin ◽  
2005 ◽  
Vol 30 (7) ◽  
pp. 509-515 ◽  
Author(s):  
Nick Holonyak

AbstractThis article is based on the 2004 Von Hippel Award address by Nick Holonyak Jr. (University of Illinois at Urbana-Champaign). Holonyak received the award for “his many contributions to research and development in the field of semiconductors, not least for the first development of semiconductor lasers in the useful visible portion of the optical spectrum.” The talk was presented on Holonyak's behalf by Russell Dupuis on December 1, 2004, at the Materials Research Society Fall Meeting in Boston.With the discovery of the transistor by Bardeen and Brattain in 1947, and as a consequence of carrier injection and collection, the hole indeed became equal to the electron. The semiconductor took on new importance, as did the study of electron–hole recombination, first in the transistor materials Ge and Si, and then in III–V crystals (e.g., GaAs and GaP). Beyond Si and its indirect-gap and heterojunction limitations, the directgap III–V materials, particularly III–V alloys, made possible lasers and light-emitting diodes (LEDs)—and thus optoelectronics.The direct-gap III–V alloy LED after four decades of development exceeds in performance the incandescent lamp (as well as other forms of lamps) in much of the visible range. Beyond growing display applications, it has put conventional lighting under longrange threat with a semiconductor lamp—an “ultimate lamp” that promises unusual performance and energy savings. In principle, the LED or laser, basically a p–n junction, is an ultimate lamp that cannot be exceeded.

Nanomaterials ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 154
Author(s):  
Ming-Ru Wen ◽  
Sheng-Hsiung Yang ◽  
Wei-Sheng Chen

Copper thiocyanate (CuSCN) has been gradually utilized as the hole injection layer (HIL) within optoelectronic devices, owing to its high transparency in the visible range, moderate hole mobility, and desirable environmental stability. In this research, we demonstrate quantum dot light-emitting diodes (QLEDs) with high brightness and current efficiency by doping 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4TCNQ) in CuSCN as the HIL. The experimental results indicated a smoother surface of CuSCN upon F4TCNQ doping. The augmentation in hole mobility of CuSCN and carrier injection to reach balanced charge transport in QLEDs were confirmed. A maximum brightness of 169,230 cd m−2 and a current efficiency of 35.1 cd A−1 from the optimized device were received by adding 0.02 wt% of F4TCNQ in CuSCN, revealing promising use in light-emitting applications.


2000 ◽  
Vol 660 ◽  
Author(s):  
Thomas M. Brown ◽  
Ian S. Millard ◽  
David J. Lacey ◽  
Jeremy H. Burroughes ◽  
Richard H. Friend ◽  
...  

ABSTRACTThe semiconducting-polymer/injecting-electrode heterojunction plays a crucial part in the operation of organic solid state devices. In polymer light-emitting diodes (LEDs), a common fundamental structure employed is Indium-Tin-Oxide/Polymer/Al. However, in order to fabricate efficient devices, alterations to this basic structure have to be carried out. The insertion of thin layers, between the electrodes and the emitting polymer, has been shown to greatly enhance LED performance, although the physical mechanisms underlying this effect remain unclear. Here, we use electro-absorption measurements of the built-in potential to monitor shifts in the barrier height at the electrode/polymer interface. We demonstrate that the main advantage brought about by inter-layers, such as poly(ethylenedioxythiophene)/poly(styrene sulphonic acid) (PEDOT:PSS) at the anode and Ca, LiF and CsF at the cathode, is a marked reduction of the barrier to carrier injection. The electro- absorption results also correlate with the electroluminescent characteristics of the LEDs.


2016 ◽  
Vol 10 (12) ◽  
pp. 782-787 ◽  
Author(s):  
T. H. Chung ◽  
G. Juska ◽  
S. T. Moroni ◽  
A. Pescaglini ◽  
A. Gocalinska ◽  
...  

2012 ◽  
Vol 717-720 ◽  
pp. 87-92
Author(s):  
Mikael Syväjärvi ◽  
Rositza Yakimova ◽  
Motoaki Iwaya ◽  
Tetsuya Takeuchi ◽  
Isamu Akasaki ◽  
...  

The LED technology started to developed many years ago with red light emitting diodes. To achieve the blue LED, novel growth technologies and process steps were explored, and made it possible to demonstrate efficient blue LED performance from nitrides. The efficiency was further developed and blue LEDs were commercially introduced in the 1990’s. The white LED became possible by the use of the blue LED and a phosphor that converts a part of the blue light to other colors in the visible range to combine into white light. However, even today there are limitations in the phosphor-based white LED technology, in particular for general lighting, and new solutions should be explored to speed the pace when white LEDs will be able to make substantial energy savings. In this paper we overview gallium nitride materials evolution and growth concepts for LEDs. We describe the fluorescent silicon carbide material prepared by a novel growth technology for a new type of white LED in general lighting with pure white light. This paper introduces an interesting research in fundamental growth and optical properties of light emitting silicon carbide.


2013 ◽  
Vol 1 (33) ◽  
pp. 5110 ◽  
Author(s):  
Jwo-Huei Jou ◽  
Hui-Huan Yu ◽  
You-Xing Lin ◽  
Jing-Ru Tseng ◽  
Shiang-Hau Peng ◽  
...  

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