Carbon Materials as Adsorbents for the Removal of Pollutants from the Aqueous Phase

MRS Bulletin ◽  
2001 ◽  
Vol 26 (11) ◽  
pp. 890-894 ◽  
Author(s):  
Carlos Moreno-Castilla ◽  
José Rivera-Utrilla
Keyword(s):  
Water Treatment ◽  
Liquid Phase ◽  
Surface Chemistry ◽  
Surface Area ◽  
Carbon Materials ◽  
Activated Carbons ◽  
Raw Materials ◽  
World Production ◽  
Variable Surface ◽  
Materials Used

Activated carbons are the most important carbon materials used in water treatment. Their known world production is around 500,000 tons per year, of which about 80% is used for liquid-phase applications. These solids are manufactured in powder or granular form from a large variety of raw materials and are unique and versatile adsorbents due to their highly developed porosity, their large surface area (which in some cases can be up to 3000 m2/g), and their variable surface chemistry.

scholarly journals Mesoporous Activated Carbon Supported Ru Catalysts to Efficiently Convert Cellulose into Sorbitol by Hydrolytic Hydrogenation

Energies ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 4394
Author(s):  
Fatima-Zahra Azar ◽  
M. Ángeles Lillo-Ródenas ◽  
M. Carmen Román-Martínez
Keyword(s):  
Carbon Materials ◽  
Activated Carbons ◽  
One Pot ◽  
Cellulose Conversion ◽  
Hydrolytic Hydrogenation ◽  
Ru Nanoparticles ◽  
Two Samples ◽  
Materials Used ◽  
The One ◽  
By Products

Catalysts consisting of Ru nanoparticles (1 wt%), supported on mesoporous activated carbons (ACs), were prepared and used in the one-pot hydrolytic hydrogenation of cellulose to obtain sorbitol. The carbon materials used as supports are a pristine commercial mesoporous AC (named SA), and two samples derived from it by sulfonation or oxidation treatments (named SASu and SAS, respectively). The catalysts have been thoroughly characterized regarding both surface chemistry and porosity, as well as Ru electronic state and particle size. The amount and type of surface functional groups in the carbon materials becomes modified as a result of the Ru incorporation process, while a high mesopore volume is preserved upon functionalization and Ru incorporation. The prepared catalysts have shown to be very active, with cellulose conversion close to 50% and selectivity to sorbitol above 75%. The support functionalization does not lead to an improvement of the catalysts’ behavior and, in fact, the Ru/SA catalyst is the most effective one, with about 50% yield to sorbitol, and a very low generation of by-products.

scholarly journals Regeneration of Activated Carbons Spent by Waste Water Treatment Using KOH Chemical Activation

2019 ◽  
Vol 9 (23) ◽  
pp. 5132 ◽  
Author(s):  
Jung Eun Park ◽  
Gi Bbum Lee ◽  
Bum Ui Hong ◽  
Sang Youp Hwang
Keyword(s):  
Waste Water ◽  
Heat Treatment ◽  
Water Treatment ◽  
Specific Surface ◽  
Surface Area ◽  
Activated Carbons ◽  
Chemical Activation ◽  
Waste Water Treatment ◽  
Waste Water Treatment Plant ◽  
X Ray

In this study, spent activated carbons (ACs) were collected from a waste water treatment plant (WWTP) in Incheon, South Korea, and regenerated by heat treatment and KOH chemical activation. The specific surface area of spent AC was 680 m2/g, and increased up to 710 m2/g through heat treatment. When the spent AC was activated by the chemical agent potassium hydroxide (KOH), the surface area increased to 1380 m2/g. The chemically activated ACs were also washed with acetic acid (CH3COOH) to compare the effect of ash removal during KOH activation. The low temperature N2 adsorption was utilized to measure the specific surface areas and pore size distributions of regenerated ACs by heat treatment and chemical activation. The functional groups and adsorbed materials on ACs were also analyzed by X-ray photoelectron spectroscopy and X-ray fluorescence. The generated ash was confirmed by proximate analysis and elementary analysis. The regenerated ACs were tested for toluene adsorption, and their capacities were compared with commercial ACs. The toluene adsorption capacity of regenerated ACs was higher than commercial ACs. Therefore, it is a research to create high value-added products using the waste.

scholarly journals Materials and Applications for Low-Cost Ceramic Membranes

Membranes ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 105 ◽  
Author(s):  
Amanmyrat Abdullayev ◽  
Maged Bekheet ◽  
Dorian Hanaor ◽  
Aleksander Gurlo
Keyword(s):  
Water Treatment ◽  
Raw Materials ◽  
Low Cost ◽  
Temperature Stability ◽  
Ceramic Membranes ◽  
Production Costs ◽  
High Temperature Stability ◽  
Waste Products ◽  
Recent Developments ◽  
Materials Used

In water treatment applications, the use of ceramic membranes is associated with numerous advantages relative to polymer-based filtration systems. High-temperature stability, fouling resistance, and low maintenance requirements contribute to lower lifecycle costs in such systems. However, the high production costs of most commercially available ceramic membranes, stemming from raw materials and processing, are uneconomical for such systems in most water treatment applications. For this reason, there is a growing demand for new ceramic membranes based on low-cost raw materials and processes. The use of unrefined mineral feedstocks, clays, cement, sands, and ash as the basis for the fabrication of ceramic membranes offers a promising pathway towards the obtainment of effective filtration systems that can be economically implemented in large volumes. The design of effective ceramic filtration membranes based on low-cost raw materials and energy-efficient processes requires a balance of pore structure, mass flow, and robustness, all of which are highly dependent on the composition of materials used, the inclusion of various pore-forming and binding additives, and the thermal treatments to which membranes are subjected. In this review, we present recent developments in materials and processes for the fabrication of low-cost membranes from unrefined raw materials, including clays, zeolites, apatite, waste products, including fly ash and rice husk ash, and cement. We examine multiple aspects of materials design and address the challenges relating to their further development.

Influence of Surface Area on the Flowability Behaviour of Self-Flow Refractory Castables

2010 ◽  
Vol 636-637 ◽  
pp. 124-129 ◽  
Author(s):  
D.G. Pinto ◽  
Abílio P. Silva ◽  
A.M. Segadaes ◽  
T.C. Devezas
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Raw Materials ◽  
High Hardness ◽  
Size Composition ◽  
High Melting Point ◽  
Refractory Castables ◽  
Materials Used ◽  
The Relationship

Alumina, with high melting point (2050°C), high hardness and mechanical strength, and excellent abrasion resistance, is one of the most common raw materials used in self-flow refractory castables (SFRC) for monolithic linings and is commercially available in various fine to coarse size classes. However, the performance of the refractory lining depends not only on the properties of its ingredients but also on its easy installation (good flowability). The aim of this work was to evaluate the relationship between the flowability index (FI) of fresh castable and the specific surface area (SSA) of its particles, which is mostly determined by the finer particles content. The results obtained showed that, by controlling the proportion between matrix and aggregate, it is possible to control the SSA of the refractory castable and find a mathematical relationship between the specific surface area and the minimum flowability index required to obtain a self-flow refractory castable. It is, thus, possible to optimize the refractory castable size composition and obtain an estimate for FI as a function of SSA. Using a minimum 45 wt.% matrix content in the castable mixture, a SSA value above 2.215 m2/g is obtained, which leads to FI ≥ 80%, the recommended value for self-flow.

scholarly journals Surface Modification and Characterization of Coconut Shell-Based Activated Carbon Subjected to Acidic and Alkaline Treatments

2017 ◽  
Vol 4 (2) ◽  
pp. 186-194 ◽  
Author(s):  
Tan I. A. W. ◽  
Abdullah M. O. ◽  
Lim L. L. P. ◽  
Yeo T. H. C.
Keyword(s):  
Activated Carbon ◽  
Surface Morphology ◽  
Surface Chemistry ◽  
Pore Structure ◽  
Surface Area ◽  
Functional Groups ◽  
Activated Carbons ◽  
Coconut Shell ◽  
Bet Surface Area ◽  
Textural Characterization

Activated carbon derived from agricultural biomass has been increasingly recognized as a multifunctional material for various applications according to its physicochemical characteristics. The application of activated carbon in adsorption process mainly depends on the surface chemistry and pore structure which is greatly influenced by the treatment method. This study aims to compare the textural characteristics, surface chemistry and surface morphology of coconut shell-based activated carbon modified using chemical surface treatments with hydrochloric acid (HCl) and sodium hydroxide (NaOH). The untreated and treated activated carbons were characterized for their physical and chemical properties including the Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and textural characterization. The FTIR spectra displayed bands confirming the presence of carboxyl, hydroxyl and carbonyl functional groups. The Brunauer–Emmett–Teller (BET) surface area of the untreated activated carbon was 436 m2/g whereas the surface area of the activated carbon modified using 1M NaOH, 1M HCl and 2M HCl was 346, 525 and 372 m2/g, respectively. SEM micrographs showed that many large pores in a honeycomb shape were clearly found on the surface of 1M HCl sample. The pore structure of the activated carbon treated with 2M HCl and NaOH was partially destroyed or enlarged, which decreased the BET surface area. The modification of the coconut shell-based activated carbon with acidic and alkaline treatments has successfully altered the surface functional groups, surface morphology and textural properties of the activated carbon which could improve its adsorptive selectivity on a certain adsorbate.

scholarly journals THE EFFECT OF LONG EXPOSURE OF BIRCH, ASPEN AND PINE SAWDUST IN WATER ON YIELD AND SPECIF-IC SURFACE AREA OF THE CARBON PRODUCT

2019 ◽  
pp. 33-40
Author(s):  
Svetlana Ivanovna Tsyganova ◽  
Yelena Valentinovna Mazurova ◽  
Galina Nikolayevna Bondarenko ◽  
Ol'ga Yur'yevna Fetisova
Keyword(s):  
Water Treatment ◽  
Surface Area ◽  
Carbon Materials ◽  
Prolonged Exposure ◽  
Cellulose Fiber ◽  
Degree Of Crystallinity ◽  
Carbon Product ◽  
Pine Wood ◽  
Pine Sawdust ◽  
Crystalline Component

The article presented researches concerning the effect of prolonged exposure in water of wood of different species - birch, aspen and pine, on the formation of carbon materials structure during carbonization. The possibility of using wood waste of different species, subject to long exposure in water, to obtain more porous carbon materials than using original wood is shown. It was established that the aging of different species in water stimulates the disclosure of the porous structure of the carbon product. This particularly applies to the carbon product of pine wood, the specific surface area which increases from 10 to 455 m2 g-1. It was shown that the yield of the carbon product, increases by 15–25 wt.% using wood prolonged exposure in water. Using XRD and electron microscopy, features of the structural transformation of birch, aspen and pine wood subjected to water treatment were revealed. Prolonged exposure of different wood species in the water affects the degree of crystallinity of the cellulose fiber in wood. The crystalline component of pine is exposed to the greatest destruction under the action of water. It was noted that after water treatment of wood, the part of the amorphous component in the carbon product increases, regardless of the type of wood used.

Production of High Surface Area Activated Carbon from Coconut Husk

2014 ◽  
Vol 1644 ◽  
Author(s):  
Paul R. Armstrong ◽  
Zachary J. Morchesky ◽  
Dustin T. Hess ◽  
Kofi W. Adu ◽  
David. K. Essumang ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Surface Area ◽  
Activated Carbons ◽  
Raw Materials ◽  
Chemical Activation ◽  
High Surface ◽  
Waste Product ◽  
High Surface Area ◽  
Coconut Husk ◽  
Porosity Analysis

ABSTRACTWe present preliminary results on a processing protocol by chemical activation that transforms organic waste product such as coconut husk into high surface area activated carbon. Dried raw materials of the coconut husk were carbonized anaerobically into char. The char was impregnated with KOH of different ratios and were activated at 800°C and 900°C. The transmission electron microscope was used to acquire structural and morphological information of the activated carbon, and the surface area and porosity analysis were performed using Micromeritics ASAP 2020 analyzer. The activated carbons show both micropores and mesopores with specific surface area as high as 2900m2/g.

scholarly journals Porous Carrageenan-Derived Carbons for Efficient Ciprofloxacin Removal from Water

Nanomaterials ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 1004 ◽  
Author(s):  
João Nogueira ◽  
Maria António ◽  
Sergey Mikhalev ◽  
Sara Fateixa ◽  
Tito Trindade ◽  
...  
Keyword(s):  
Specific Surface ◽  
Surface Area ◽  
Specific Surface Area ◽  
Porous Carbon ◽  
Carbon Materials ◽  
Activated Carbons ◽  
Chemical Activation ◽  
High Specific Surface Area ◽  
High Porosity ◽  
Porous Carbon Materials

Porous carbon materials derived from biopolymers are attractive sorbents for the removal of emerging pollutants from water, due to their high specific surface area, high porosity, tunable surface chemistry, and reasonable cost. However, carrageenan biopolymers were scarcely investigated as a carbon source to prepare porous carbon materials. Herein, hydrochars (HCs) and porous activated carbons (ACs) derived from natural occurring polysaccharides with variable sulfate content (κ-, ι- and λ-carrageenan) were prepared and investigated in the uptake of ciprofloxacin, which is an antibiotic detected in water sources and that poses serious hazards to public health. The materials were prepared using hydrothermal carbonization and subsequent chemical activation with KOH to increase the available surface area. The activated carbons were markedly microporous, presenting high specific surface area, up to 2800 m2/g. Activated carbons derived from κ- and λ-carrageenan showed high adsorption capacity (422 and 459 mg/g, respectively) for ciprofloxacin and fast adsorption kinetics, reaching the sorption equilibrium in approximately 5 min. These features place the ACs investigated here among the best systems reported in the literature for the removal of ciprofloxacin from water.

Effect of Base Material on the Pore Size Distribution and Surface Area of Activated Carbon

2009 ◽  
Vol 62-64 ◽  
pp. 352-356 ◽  
Author(s):  
O.O. Ojo
Keyword(s):  
Activated Carbon ◽  
Pore Size ◽  
Surface Area ◽  
Surface Properties ◽  
Activated Carbons ◽  
Palm Kernel ◽  
Adsorptive Capacity ◽  
Corn Cobs ◽  
Base Materials ◽  
Materials Used

Powdered activated carbons were produced from palm kernel shells, corn cobs and cow bones by carbonization, pulverization and activation. The resulting granule has a surface area of 430.04 m2/g, 4022.15 m2/g and 733.60 m2/g respectively with controlled pore size. The characterized surface area enables the carbon to absorb vapors from gases, and substances from liquids. The surface properties are function of the base materials used in the preparation. Determinations of their adsorptive capacities show that activated carbon prepared from corn cobs has the highest adsorptive capacity. The surface properties are function of the base materials used in the preparation. Determinations of their adsorptive capacities show that activated carbon prepared from corn cobs has the highest adsorptive capacity.

scholarly journals Obtaining of high porous carbon material using thermochemical conversion of wood biomass under pressure

2021 ◽  
Vol 66 (1) ◽  
pp. 76-83
Author(s):  
S. V. Vasilevich ◽  
M. V. Malko ◽  
D. V. Degterov ◽  
A. N. Asadchyi
Keyword(s):  
Water Vapor ◽  
Carbon Content ◽  
Porous Carbon ◽  
Carbon Materials ◽  
Activated Carbons ◽  
Raw Materials ◽  
Thermochemical Conversion ◽  
Physical Activation ◽  
Porous Carbon Materials ◽  
Highly Porous

A method is presented for obtaining activated carbons (highly porous carbon materials) based on plant (wood) raw materials using a developed and manufactured experimental setup, consisting of a steam generator, a superheater, a pyrolysis and activation chamber and a cooler with a heat exchanger with forced convection. The analysis of the features of chemical and physical activation of charcoal, obtained by pyrolysis of wood raw materials, is carried out, and a conclusion is made about the advantage of physical activation, based on the use of water vapor as an activating agent. A description of the results of experimental studies carried out using the developed installation is given. These results confirm the conclusions of other studies that excessive pressure increases the mass yield of solid products formed during the thermochemical conversion of plant biomass. It was found that an increase in pressure, at which pyrolysis occurs, leads to an increase in the carbon content in charcoal. So, with an increase in pressure at which pyrolysis was carried out, from 1 to 8 atm, the carbon content in charcoal increased from 88.3 to 93.7 wt.%. Data on the efficiency of physical activation of solid products of pyrolysis of woody biomass using water vapor are presented and a conclusion is made that this direction is promising in the development of the foundations for the production of highly porous carbon materials.

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