Mild hydrothermal synthesis of γ-MnO2 nanostructures and their phase transformation to α-MnO2 nanowires

2011 ◽  
Vol 26 (17) ◽  
pp. 2268-2275 ◽  
Author(s):  
Yaqoob Khan ◽  
Shahid Khan Durrani ◽  
Mazhar Mehmood ◽  
Muhammad Riaz Khan

Abstract

2013 ◽  
Vol 28 (24) ◽  
pp. 3408-3416 ◽  
Author(s):  
Wei Wei ◽  
Xuejie Yue ◽  
Henglv Cui ◽  
Xiaomeng Lü ◽  
Jimin Xie

Abstract


2019 ◽  
Vol 34 (3) ◽  
pp. 465-473
Author(s):  
Satyanarayana V.N.T. Kuchibhatla ◽  
Ajay S. Karakoti ◽  
Andreas E. Vasdekis ◽  
Charles F. Windisch ◽  
Sudipta Seal ◽  
...  

Abstract


2011 ◽  
Vol 26 (1) ◽  
pp. 1-8 ◽  
Author(s):  
Hong Liang ◽  
Rodrigo Cooper ◽  
Jason Files

Abstract


1983 ◽  
Vol 21 ◽  
Author(s):  
N. Mykura ◽  
S. Murphy ◽  
Y.H. Zhu

The alloys of the ternary system Zn-Al-Cu are characterised by dimensional changes that occur on ageing in conjunction with certain phase transformations and changes in solid solubility [1]. The phase transformation that is suggested to be responsible is the four phase reactionthat occurs below 273°C [2]. The average density of the products of this reaction was hypothesised to be less than that of the reactants resulting in an increase in volume. Previous work [3] had indicated that the lattice parameters of the zinc structure cell varied considerably on ageing and this change was attributed to the change in solubility of substitutionally dissolved copper. On ageing it is hypothesised that copper tends to come out of solution in zinc, contributing to the total increase in volume. This copper may come out as ε-phase which may react to form T'-phase with a resulting change in volume.


2015 ◽  
Vol 30 (10) ◽  
pp. 1693-1700 ◽  
Author(s):  
Yang Yang ◽  
Kui Zhang ◽  
Minglong Ma ◽  
Xinggang Li

Abstract


2012 ◽  
Vol 27 (20) ◽  
pp. 2609-2614 ◽  
Author(s):  
Guang Zeng ◽  
Stuart D. McDonald ◽  
Qinfen Gu ◽  
Kazuhiro Nogita

Abstract


Nanomaterials ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 891
Author(s):  
Teodóra Nagyné-Kovács ◽  
Levente Studnicka ◽  
István Endre Lukács ◽  
Krisztina László ◽  
Pawel Pasierb ◽  
...  

Effects of different reaction parameters in the hydrothermal synthesis of molybdenum oxides (MoO3) were investigated and monoclinic (β-) MoO3 was prepared hydrothermally for the first time. Various temperatures (90/210 °C, and as a novelty 240 °C) and durations (3/6 h) were used. At 240 °C, cetyltrimethylammonium bromide (CTAB) and CrCl3 additives were also tested. Both the reaction temperatures and durations played a significant role in the formation of the products. At 90 °C, h-MoO3 was obtained, while at 240 °C the orthorhombic (α-) MoO3 formed with hexagonal rod-like and nanofibrous morphology, respectively. The phase transformation between these two phases was observed at 210 °C. At this temperature, the 3 h reaction time resulted in the mixture of h- and α-MoO3, but 6 h led to pure α-MoO3. With CTAB the product was bare o-MoO3, however, when CrCl3 was applied, pure metastable m-MoO3 formed with the well-crystallized nanosheet morphology. The gas sensing of the MoO3 polymorphs was tested to H2, which was the first such gas sensing study in the case of m-WO3. Monoclinic MoO3 was found to be more sensitive in H2 sensing than o-MoO3. This initial gas sensing study indicates that m-MoO3 has promising gas sensing properties and this MoO3 polymorph is promising to be studied in detail in the future.


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