Direct synthesis of tin oxide nanotubes on microhotplates using carbon nanotubes as templates

2011 ◽  
Vol 26 (3) ◽  
pp. 430-436 ◽  
Author(s):  
Prahalad Parthangal ◽  
Richard E. Cavicchi ◽  
Douglas C. Meier ◽  
Andrew Herzing ◽  
Michael R. Zachariah

Abstract

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2550
Author(s):  
Yingchun Wang ◽  
Jinxu Liu ◽  
Min Yang ◽  
Lijuan Hou ◽  
Tingting Xu ◽  
...  

By evenly mixing polytetrafluoroethylene-silicon energetic materials (PTFE-Si EMs) with tin oxide (SnO2) particles, we demonstrate a direct synthesis of graphene-encapsulated SnO2 (Gr-SnO2) nanoparticles through the self-propagated exothermic reaction of the EMs. The highly exothermic reaction of the PTFE-Si EMs released a huge amount of heat that induced an instantaneous temperature rise at the reaction zone, and the rapid expansion of the gaseous SiF4 product provided a high-speed gas flow for dispersing the molten particles into finer nanoscale particles. Furthermore, the reaction of the PTFE-NPs with Si resulted in a simultaneous synthesis of graphene that encapsulated the SnO2 nanoparticles in order to form the core-shell nanostructure. As sodium storage material, the graphene-encapsulated SnO2 nanoparticles exhibit a good cycling performance, superior rate capability, and a high initial Coulombic efficiency of 85.3%. This proves the effectiveness of our approach for the scalable synthesis of core-shell-structured graphene-encapsulated nanomaterials.


2011 ◽  
Vol 20 (03) ◽  
pp. 687-695 ◽  
Author(s):  
DOMINICK J. BINDL ◽  
MICHAEL S. ARNOLD

A photovoltaic photodetector harnessing near infrared band gap absorption by thin films of post-synthetically sorted semiconducting single walled carbon nanotubes ( s -SWCNTs) is described. Peak specific detectivity of 6×1011 Jones at -0.1 V bias at 1210 nm is achieved using a heterojunction device architecture: indium tin oxide/ ca. 5 nm s -SWCNT / 120 nm C60 / 10 nm 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP) / Ag. The photodiodes are characterized by a series resistance of 2.9 Ω cm2 and a rectification ratio of 104 at ±1V. These results are expected to guide the exploration of new classes of solution-processable, mechanically flexible, integrable, thin film photovoltaic photodetectors with tunable sensitivity in the visible and infrared spectra based on semiconducting carbon nanotubes.


2019 ◽  
Vol 131 (29) ◽  
pp. 10033-10037 ◽  
Author(s):  
Pierrick Clément ◽  
Xinzhao Xu ◽  
Craig T. Stoppiello ◽  
Graham A. Rance ◽  
Antonio Attanzio ◽  
...  

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