scholarly journals Persistence of 5:3 plates in RE5(SixGe1-x)4 alloys

2006 ◽  
Vol 21 (10) ◽  
pp. 2669-2674 ◽  
Author(s):  
O. Ugurlu ◽  
L.S. Chumbley ◽  
C.R. Fisher

Studies of RE5(SixGe1-x)4 alloys, where RE equals rare earth, have revealed a second-phase having a thin-plate morphology in essentially every alloy examined, independent of exact composition and matrix crystal structure. Identified as having a composition approximating Gd5(SixGe1-x)3 and a hexagonal crystal structure in the Gd-based system, it has been suggested that the observed thin-plate second phases seen in this family of rare earth alloys are all most likely of the form RE5(SixGe1-x)3. A number of interesting observations suggest that the formation of these second-phase plates is somewhat unusual. The purpose of this article is to investigate the stability of this second phase in Gd- and Er-based compounds. The stability was investigated as a function of thermal cycling and large-scale composition fluctuations. The results of scanning and transmission electron microscopy (SEM, TEM) studies indicate that the RE5(SixGe1-x)3 phase is extremely stable once it forms in a RE5(SixGe1-x)4 matrix.

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Dongmei Mo ◽  
Xiangying Li ◽  
Yong Chen ◽  
Yang Jiang ◽  
Chunfang Gan ◽  
...  

AbstractNanopesticide is one of the best pesticide formulation technologies to overcome the disadvantages of traditional pesticides, which has received great attention from the international community. Using high-speed emulsification and ultrasonic dispersion technology, an avermectin nano-delivery system (Av-NDs) with a particle size of 80–150 nm was prepared through embedding the pesticide molecule utilizing the cross-linking reaction between sodium lignosulfonate and p-phenylenediamine diazonium salt. The formulation and composition of Av-NDs were optimized, the morphology of Av-NDs was analyzed by scanning electron microscope, transmission electron microscope and dynamic light scattering, and the structure of Av-NDs was characterized by UV, IR and 1H NMR. Anti-photolysis and controlled-release tests show that the stability of Av-NDs is 3–4 times of the original avermectin (Av) and possesses the pH-responsive controlled release property. Furthermore, the insecticidal activity of Av-NDs is better than that of avermectin suspension concentrate (Av-SC). The Av-NDs with anti-photolysis and controlled-release characteristics is suitable for large-scale industrial production and is capable to be utilized as effective insecticide in the field.


1981 ◽  
Vol 8 ◽  
Author(s):  
G. B. Olson ◽  
H. C. Ling ◽  
J. S. Montgomery ◽  
J. B. Vander Sande ◽  
M. Cohen

ABSTRACTControl of alloy composition and processing to achieve grain coarsening resistance in rapidly solidified alloys is examined via the theory of grain boundary pinning and particle coarsening. The principles are illustrated for the case of manganese sulfides in steels. A thermodynamic survey of potential stable dispersed phases identifies TiN and rare-earth sulfides as particularly promising for alloy development via rapid solidification.


2014 ◽  
Vol 886 ◽  
pp. 36-40
Author(s):  
Rong Hua Zhang ◽  
Bao Hong Zhu ◽  
Xiao Ping Zheng

Heat-resistant Al-8.5Fe-1.3V-1.7Si aluminum alloys were prepared by spray forming technique. The phase transition of deposited alloys from room temperature to 500°C was measured by Differential Scanning Calorimeter. The organization and the second phases of the alloys were observed and studied by transmission electron microscopy. The research results show that No endothermic peak appears in the deposited alloys during heating process, there is no phase transition occur in the alloy during the heating process from room temperature to 500°C. The deposited alloys mainly include α-Al and α-Al12(Fe,V)3Si phase. Under the transmission electron microscopy, there are also a small amount of slug, fan-shaped, needle-like, block, strip second phases, these phases are Al12Fe3Si, Al8Fe2Si, θ-Al13Fe4, Al9FeSi3, Al6Fe.


2021 ◽  
Vol 12 (2) ◽  
pp. 2361-2372

In recent years, developing nanoparticles with green processes is gaining huge attention due to its cost-effectiveness, simplicity and non–toxic precursors. The present study utilized the potential of egg white for the synthesis of stable silver nanoparticles (EW-AgNPs). In order to characterize the EW-AgNPs, various techniques have been employed. UV-vis spectroscopy (300-700nm) was used to study the λmax, which highlighted the peak at 422nm. Further, the stability of synthesized EW-AgNPs was studied using Zeta potential, the value of -16.4 mV was obtained, indicating the stability of developed EW-AgNPs in the solution. Transmission electron microscopy was used specifically to visualize the shape and size of synthesized EW-AgNPs, the images showed spherical to the diverse shape of EW-AgNPs. In the first phase, the EW-AgNPs were studied for dye degradation along with NaBH4. The enhanced dye degradation of blue dye was obtained with EW-AgNPs+NaBH4, showing 90- 100% degradation from 100- 25 mgL-1 dye solution, respectively. Further, in the second phase, antimicrobial activity (Zone of Inhibition) of EW-AgNPs was analyzed against Escherichia coli and Staphylococcus aureus. A higher ZOI was obtained for E.coli (16mm) than S. aureus (12.4mm). The present study proved egg white's ability to develop stable silver nanoparticles, which was further found to be effective for blue dye degradation and antimicrobial activity.


1983 ◽  
Vol 28 ◽  
Author(s):  
D.G. Konitzer ◽  
R. Kirchheim ◽  
H.L. Fraser

ABSTRACTTechniques of rapid solidification processing were used to refine a dispersion of rare earth oxides in Ti. The dispersion was produced by laser surface melting and subsequent heat treatment of a Ti-Er alloy. The second phase was identified as the rare earth oxide. The stability of the dispersion was investigated analytically and experimentally and the correlation between the analysis and experiments was shown to be very good.


2013 ◽  
Vol 92 (4) ◽  
pp. 243-266 ◽  
Author(s):  
J. Sevink ◽  
E.A. Koster ◽  
B. van Geel ◽  
J. Wallinga

AbstractA unique complex of multiphased Holocene drift sands and paleosols, with at least two lacustrine phases, was discovered during a major sanitation project in the Laarder Wasmeren area near Hilversum, the Netherlands. The complex could be studied in detail, highly facilitated by the excellent and large-scale exposure of the various deposits and soils. OSL dating was used to establish ages of the phases, where possible differentiating between time of deposition and time of burial by taking into account the potential effects of bioturbation. Pollen analysis served to reconstruct the vegetation during the various phases.A first minor phase of aeolian activity already started before approx. 5,000 BC, followed around 4,000 BC by a second phase and a rather massive third phase around 3,000 BC. After a long phase of soil formation, the latest, massive drift sand phase started around the 14th to 15th century. It clearly represents the classic drift sand phase that started in the Late Middle Ages in the Netherlands. Sand drifting followed on soil forming phases during which the vegetation became increasingly dominated by ericaceous plants and culminated in heathlands. The first three aeolian phases and associated heathlands are much older than generally assumed for heathland and drift sand to occur in the Netherlands. Moreover, podzolisation was found to have started very early, true podzols already occurring before 4,000 BC.Around 3,000 BC groundwater in the area reached a maximum altitude of about 230 cm +NAP, resulting in local open water in the area. This rise is probably linked to the development of the Dutch coastal area, where at that time peat accumulated and drainage was poor, inducing a rise of the groundwater level in ‘het Gooi’. This groundwater level fell later on, to never reach this altitude again. The Groot Wasmeer was formed by local stagnation on a slowly permeable podzol and already reached a level of 320-325 cm +NAP by 400 BC, which more or less equals its 20thcentury level.The results demonstrate that earlier concepts on the occurrence and age of aeolian phases, podzols and heathland vegetations in the Netherlands are far too schematic, and that early, pre-agricultural cultures may already have had an impact on the stability of fragile cover sand landscapes, e.g. through burning. Results are in line with those from several contemporary studies on early prehistoric cultures and their impact in river dune areas in the Central and Eastern Netherlands.


Author(s):  
Xu Wang ◽  
Jun Tan ◽  
Liutao Chen ◽  
Hong Zou ◽  
Dungu Wen ◽  
...  

Zr-Nb zirconium alloy was developed at CNPRI and designated as CZ2. In this paper, the composition, size distribution and crystal structure of second phase particles (SPPs) in CZ2 have been analyzed under transmission electron microscopy (TEM). Two types of SPPs were observed in CZ2, which are bcc β-Nb and hcp Zr-Nb-Fe. To study the radiation effects on SPPs, CZ2 in two different heat treatment conditions CZ2-SRA (stress relieved) and CZ2-RXA (recrystallized) were irradiated with 3 MeV Zr++ up to 1.14×1016 Zr/cm2 (50 dpa at the damage peak) at three different temperatures 320°C, 360°C and 400°C in Texas A&M University. Commercial low-tin Zr-4 was also irradiated at the same condition as a reference. The results show that the SPPs of Zr-4 become completely amorphous after irradiation at 320°C and 360°C, while retain crystalline at 400 °C. SPPs of CZ2-RXA are partially disordered only after irradiation at 320°C. The crystal structure of SPPs in CZ2-SRA survived at all temperatures.


Author(s):  
Rémi Federicci ◽  
Benoit Baptiste ◽  
Fabio Finocchi ◽  
Florin Popa ◽  
Luc Brohan ◽  
...  

Recent results have demonstrated an exceptionally high permittivity in the range 200–330 K in crystalline titanium oxide Rb2Ti2O5. In this article, the possibility of a structural transition giving rise to ferroelectricity is carefully inspected. In particular, X-ray diffraction, high-resolution transmission electron microscopy and Raman spectroscopy are performed. The crystal structure is shown to remain invariant and centrosymmetric at all temperatures between 90 K and 450 K. The stability of the C2/m structure is confirmed by density functional theory calculations. These important findings allow the existence of a conventional ferroelectric phase transition to be ruled out as a possible mechanism for the colossal permittivity and polarization observed in this material.


2012 ◽  
Vol 1430 ◽  
Author(s):  
Fengyuan Shi ◽  
Hua Xiang ◽  
M. S. Rzchowski ◽  
Y. A. Chang ◽  
P.M. Voyles

ABSTRACTWe fabricated Fe3O4 thin films on TiN buffered Si by CO/CO2 oxidation at 160 °C. The easy saturation of the magnetization at high magnetic field and high resolution scanning transmission electron microscopy (HRSTEM) images show low defect density, smooth Fe3O4 thin films. Oxidation at 400 °C resulted in an undesirable second phase in between the TiN and the un-oxidized Fe, but changes in total gas pressure did not lead to a second phase. The crystal structure of this second phase is similar to Fe2TiO4 (ulvöspinel) from HRSTEM and STEM electron energy loss spectroscopy. Fe3O4 thin films grown at 160 °C follow a power law growth model with an exponent of 0.23±0.03.


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