Thermomechanical evaluation of new geopolymer binder from demolition waste and ignimbrite slits for application in the construction industry

MRS Advances ◽  
2019 ◽  
Vol 4 (54) ◽  
pp. 2951-2958
Author(s):  
D.L. Mayta-Ponce ◽  
P. Soto-Cruz ◽  
F.A. Huamán-Mamani

ABSTRACTGeopolymeric mortars with volumetric fractions of 0.6:1:0.3 for a binder powder, fine sand and sodium hydroxide solution (12M), respectively; have been fabricated by mixing the solid materials and the subsequent addition of sodium hydroxide solution 12M to form a workable paste, to later be cured for 28 days at room temperature. The microstructures of the fabricated materials reveal the existence of two phases with notable difference, one continuous to the geopolymer binder phase and another discontinuous of fine sand particles agglutinated by the binder phase. Mechanical compression tests are performed at a constant compression rate of 0.05 mm/min and at temperatures ranged from room temperature to 500°C. The mechanical results are ranged from 19 and 69 MPa for all the materials studied. On the other hand, there was an increase in mechanical resistance up to test temperatures of 200°C and the progressive reduction of resistance at temperatures above 200°C, with a fragile-ductile transition zone between 400 and 500°C and completely ductile behavior from test temperatures of 500°C.

2019 ◽  
Vol 303 ◽  
pp. 01005
Author(s):  
D.L. Mayta-Ponce ◽  
P. Soto-Cruz ◽  
F.A. Huamán-Mamani

Geopolymeric mortars with volumetric fractions of 0.6:1:0.3 for a binder powder, fine sand and sodium hydroxide solution (12M), respectively; have been fabricated by mixing the solid materials and the subsequent addition of sodium hydroxide solution 12M to form a workable paste, to later be cured for 28 days at room temperature. The microstructures of the fabricated materials reveal the existence of two phases with notable difference, one continuous to the geopolymer binder phase and another discontinuous of fine sand particles agglutinated by the binder phase. Mechanical compression tests are performed at a constant compression rate of 0.05 mm/min and at temperatures ranged from room temperature to 500°C. The mechanical results are ranged from 19 and 69 MPa for all the materials studied. On the other hand, there was an increase in mechanical resistance up to test temperatures of 200°C and the progressive reduction of resistance at temperatures above 200°C, with a fragile-ductile transition zone between 400 and 500°C and completely ductile behavior from test temperatures of 500°C.


1970 ◽  
Vol 48 (9) ◽  
pp. 1404-1413 ◽  
Author(s):  
K. B. Shaw ◽  
R. M. Heggie ◽  
R. K. Miller

When N-(2-methylsulfonylphenyl)hydroxylamine (4) was treated with dilute sodium hydroxide solution the major product was always 2,2′-di(methylsulfonyl)azoxybenzene (5). At room temperature other significant products were 2-hydroxy-2′-methylsulfonylazoxybenzene (6a) and 2-methylsulfonylnitrobenzene (2), while 6a was also formed at reflux together with small amounts of 2-hydroxy-2′-methylsulfonylazobenzene (8), 2-methylsulfonylaniline (7), 3-methylsulfonyl-3′-nitro-4-amino-4′-hydroxybiphenyl (3), and 2. The compounds 5, 6a, and 7 were also obtained when 2-methylsulfonylnitrosobenzene (9) was boiled with alkali. The decomposition of N-(4-methylsulfonylphenyl)hydroxylamine (16) in dilute alkali at room temperature gave a quantitative yield of 4,4′-di(methylsulfonyl)azoxybenzene (17) and at reflux, mixtures of 17 and 4,4′-di(methylsulfonyl)azobenzene (18) were obtained. The modes of formation of the various products from the two hydroxylamines are discussed.


1982 ◽  
Vol 35 (8) ◽  
pp. 1727 ◽  
Author(s):  
J Rosevear ◽  
JFK Wilshire

The sodium salt of 4-amino-3-nitrobenzenesulfonic acid (O-nitroaniline-p-sulfonic acid) has been prepared by the action of dilute sodium hydroxide solution on ethyl [(4-chlorosulfonyl-2-nitro)- phenyllcarbamate. Central to this synthesis is the finding that the N-ethoxycarbonyl group, when located ortho to a nitro group (but not to a bromo group), is readily removed by dilute sodium hydroxide solution.


2015 ◽  
Vol 22 (12) ◽  
pp. 4545-4550 ◽  
Author(s):  
Chong-qing Wang ◽  
Hui Wang ◽  
Guo-hua Gu ◽  
Jian-gang Fu ◽  
You-nian Liu

1997 ◽  
Vol 1997 (Supplement94) ◽  
pp. 217-225
Author(s):  
Tatsuya Fujiyoshi ◽  
Hiroyuki Masuda ◽  
Tokuji Nishinaka ◽  
Tetsuo Futami ◽  
Hiromi Shibuya

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