Fluorescent Carbon Particles formed from Concentrated Glucose Solutions

MRS Advances ◽  
2019 ◽  
Vol 4 (2) ◽  
pp. 67-72
Author(s):  
Tomilola Obadiya ◽  
Harsh Uppala ◽  
David Sidebottom

AbstractSimple glucose solutions were heat treated in an attempt to produce carbon nanodots (CNDTs) with a monodisperse size distribution using a bottom-up approach. Absorption and fluorescence properties of the heat-treated solutions display remarkable similarity to CNDTs reported in the literature. However, particle-sizing and AFM measurements indicate the increasing fluorescence is accompanied by the growth of particles that are larger than most CNDTs discussed in the literature (a concentrated population of monodisperse 30 nm particles and a low concentration of much larger, roughly 500 nm, particles). A dialysis study, shows these larger particles are not responsible for the bulk of the optical properties but, rather the optical properties likely stem from molecular by-products that accompany the heating and caramelization of the sugar.

2020 ◽  
Vol 44 (30) ◽  
pp. 13118-13124 ◽  
Author(s):  
Long Chen ◽  
Yang Wu ◽  
Heyong Huo ◽  
Bin Tang ◽  
Yuhua Fu ◽  
...  

BaFBr:Eu2+ with narrow size distribution and good dispersion is fabricated via a precipitation method. After annealing, it shows excellent optical properties.


2016 ◽  
Vol 16 (14) ◽  
pp. 9435-9455 ◽  
Author(s):  
Matthew J. Alvarado ◽  
Chantelle R. Lonsdale ◽  
Helen L. Macintyre ◽  
Huisheng Bian ◽  
Mian Chin ◽  
...  

Abstract. Accurate modeling of the scattering and absorption of ultraviolet and visible radiation by aerosols is essential for accurate simulations of atmospheric chemistry and climate. Closure studies using in situ measurements of aerosol scattering and absorption can be used to evaluate and improve models of aerosol optical properties without interference from model errors in aerosol emissions, transport, chemistry, or deposition rates. Here we evaluate the ability of four externally mixed, fixed size distribution parameterizations used in global models to simulate submicron aerosol scattering and absorption at three wavelengths using in situ data gathered during the 2008 Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) campaign. The four models are the NASA Global Modeling Initiative (GMI) Combo model, GEOS-Chem v9-02, the baseline configuration of a version of GEOS-Chem with online radiative transfer calculations (called GC-RT), and the Optical Properties of Aerosol and Clouds (OPAC v3.1) package. We also use the ARCTAS data to perform the first evaluation of the ability of the Aerosol Simulation Program (ASP v2.1) to simulate submicron aerosol scattering and absorption when in situ data on the aerosol size distribution are used, and examine the impact of different mixing rules for black carbon (BC) on the results. We find that the GMI model tends to overestimate submicron scattering and absorption at shorter wavelengths by 10–23 %, and that GMI has smaller absolute mean biases for submicron absorption than OPAC v3.1, GEOS-Chem v9-02, or GC-RT. However, the changes to the density and refractive index of BC in GC-RT improve the simulation of submicron aerosol absorption at all wavelengths relative to GEOS-Chem v9-02. Adding a variable size distribution, as in ASP v2.1, improves model performance for scattering but not for absorption, likely due to the assumption in ASP v2.1 that BC is present at a constant mass fraction throughout the aerosol size distribution. Using a core-shell mixing rule in ASP overestimates aerosol absorption, especially for the fresh biomass burning aerosol measured in ARCTAS-B, suggesting the need for modeling the time-varying mixing states of aerosols in future versions of ASP.


2014 ◽  
Vol 92 (9) ◽  
pp. 1021-1025 ◽  
Author(s):  
Bandar Ali Al-Asbahi ◽  
Mohammad Hafizuddin Haji Jumali

The influence of colloidal TiO2 nanoparticle contents on the optical properties of poly (9,9′-di-n-octylfluorenyl-2,7-diyl) conjugated polymer (PFO) has been investigated. The solution blending method was used to prepare homogenous PFO/TiO2 nanocomposite. The nanocomposite films were prepared on glass substrates using the spin-coating technique. The films were divided into two groups, the first was left to dry at room temperature while the second was heat-treated at 120 °C for 1 h. Absorption and emission spectra showed that the PFO existed in α- and β-phases morphology having monomeric, excimeric, and double excimeric states. In addition, both spectra revealed that TiO2 contents and heat treatment temperature extended the conjugation length of PFO. Finally, emission spectra for both cases exhibited decreasing in the line width of zero-phonon emission spectra and increasing in the vibronic splitting energy, upon increment of the TiO2, led to a significant increase in π-electron delocalization and lower degree in chain disorder.


2005 ◽  
Vol 5 (6) ◽  
pp. 11703-11728 ◽  
Author(s):  
V. Aaltonen ◽  
H. Lihavainen ◽  
V.-M. Kerminen ◽  
M. Komppula ◽  
J. Hatakka ◽  
...  

Abstract. Three years of continuous measurements of aerosol optical properties and simultaneous aerosol number size distribution measurements at Pallas GAW station, a remote subarctic site in the northern border of the boreal forest zone, have been analysed. The scattering coefficient at 550 nm varied from 0.2 to 94.4 Mm−1 with an average of 7.1±8.6 Mm−1. Both the scattering and backscattering coefficients had a clear seasonal cycle with an autumn minimum and a 4–5 times higher summer maximum. The scattering was dominated by submicron aerosols and especially so during late summer and autumn. The Ångström exponent had a clear seasonal pattern with maximum values in late summer and minimum values during wintertime. The highest hemispheric backscattering fraction values were observed in autumn, indicating clean air with few scattering particles and a particle size distribution strongly dominated by ultrafine particles. To analyse the influence of air mass origin on the aerosol optical properties a trajectory climatology was applied to the Pallas aerosol data. The most polluted trajectory patterns represented air masses from the Kola Peninsula, Scandinavia and Russia as well as long-range transport from Britain and Eastern Europe. These air masses had the largest average scattering and backscattering coefficients for all seasons. Higher than average values of the Ångström exponent were also observed in connection with transport from these areas.


2018 ◽  
Vol 6 (2) ◽  
pp. 256-263 ◽  
Author(s):  
Andrey Danilov ◽  
Andrey Danilov ◽  
Bayana Bazhenova ◽  
Bayana Bazhenova ◽  
Michail Danilov ◽  
...  

In the current conditions of import substitution, the effective use of secondary raw materials in the meat industry is a relevant issue. A significant source of animal proteins is by-products, the yield of which is about 10% of livestock weight. Some by-products, including beef rumen, contain collagen-containing tissues which require modification for tenderization and deodorization. In order to modify rumen tissues, the biotechnological method of treatment with an enzyme solution, lysate, obtained from a whole bovine abomasum was preferred to the known method where enzyme solution is prepared from an abomasal mucosa. The purpose of this project was to study the activity of lysate from a whole bovine abomasum for the modification of rumen tissue to use it in cooked sausage formulations. We have suggested the method of obtaining enzyme solution based on infusing the minced abomasum in a reaction mixture – water, chlorohydric acid, and sodium tripolyphosphate – followed by filtering. The dependence of proteolytic and collagenase activities of the solution obtained from phosphate dose introduced have been studied; it have been revealed that 1.5% of tripolyphosphate is the optimal dose for efficient extraction of enzymes from the whole abomasum. Besides, an effect of the enzyme solution on functional and technological properties of a heat-treated rumen has been studied, and the improvement of hydro- and lipophilic characteristics has been revealed. Paste with modified rumen has been developed and found that the maximum possible dose of rumen for use in cooked sausage from horsemeat is 15%. The color on the cut of sausage developed was identical to that of beef sausage. Thus, paste made on the basis of modified rumen contributes to the formation of functional and technological properties, the stabilization of the color characteristics of the final product, as well as the effective use of basic meat raw materials and the expansion of the range of economy class high-protein sausage production.


2020 ◽  
Author(s):  
Kirk Knobelspiesse ◽  
Amir Ibrahim ◽  
Bryan Franz ◽  
Sean Bailey ◽  
Robert Levy ◽  
...  

Abstract. Since early 2000, NASA's Multi-angle Imaging SpectroRadiometer (MISR) instrument has been performing remote sensing retrievals of aerosol optical properties from the polar orbiting Terra spacecraft. A noteworthy aspect of MISR observations over the ocean is that, for much of the Earth, some of the multi-angle views have contributions from solar reflection by the ocean surface (glint, or glitter), while others do not. Aerosol retrieval algorithms often discard these glint influenced observations because they can overwhelm the signal and are difficult to predict without knowledge of the (wind speed driven) ocean surface roughness. However, theoretical studies have shown that multi-angle observations of a location at geometries with and without reflected sun glint can be a rich source of information, sufficient to support simultaneous retrieval of both the aerosol state and the wind speed at the ocean surface. We are in the early stages of creating such an algorithm. In this manuscript, we describe our assessment of the appropriate level of parameterization for simultaneous aerosol and ocean surface property retrievals using sun glint. For this purpose, we use Generalized Nonlinear Retrieval Analysis (GENRA), an information content assessment (ICA) technique employing Bayesian inference, and simulations from the Ahmad-Fraser iterative radiative transfer code. We find that four parameters are suitable: aerosol optical depth (τ), particle size distribution (expressed as the fine mode fraction f of small particles in a bimodal size distribution), surface wind speed (w), and relative humidity (r, to define the aerosol water content and complex refractive index). None of these parameters define ocean optical properties, as we found that the aerosol state could be retrieved with the nine MISR near-infrared views alone, where the ocean body is black in the open ocean. We also found that retrieval capability varies with observation geometry, and that as τ increases so does the ability to determine aerosol intensive optical properties (r and f, while it decreases for w). Increases in wind speed decrease the ability to determine the true value of that parameter, but have minimal impact on retrieval of aerosol properties. We explored the benefit of excluding the two most extreme MISR view angles for which radiative transfer with the plane parallel approximation is less certain, but found no advantage in doing so. Finally, the impact of treating wind speed as a scalar parameter, rather than as a two parameter directional wind, was tested. While the simpler scalar model does contribute to overall aerosol uncertainty, it is not sufficiently large to justify the addition of another dimension to parameter space. An algorithm designed upon these principles is in development. It will be used to perform an atmospheric correction with MISR for coincident ocean color (OC) observations by the Moderate Resolution Imaging Spectroradiometer (MODIS) instrument, also on the NASA Terra spacecraft. Unlike MISR, MODIS is a single view angle instrument, but it has a more complete set of spectral channels ideal for determination of ocean optical properties. The atmospheric correction of MODIS OC data can therefore benefit from MISR aerosol retrievals. Furthermore, higher spatial resolution data from coincident MISR observations may also improve glint screening.


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