Lithium-Ion Capacitors and Hybrid Lithium-Ion Capacitors—Evaluation of Electrolyte Additives Under High Temperature Stress

MRS Advances ◽  
2019 ◽  
Vol 4 (49) ◽  
pp. 2641-2649
Author(s):  
Jonathan Boltersdorf ◽  
Jin Yan ◽  
Samuel A. Delp ◽  
Ben Cao ◽  
Jianping P. Zheng ◽  
...  
Keyword(s):  
High Temperature ◽  
Lithium Iron Phosphate ◽  
Extreme Environments ◽  
Lithium Ion ◽  
High Temperature Stress ◽  
Design Factor ◽  
Electrolyte Additive ◽  
Electrolyte Additives ◽  
Additive Formulation ◽  
Composite Cathodes

ABSTRACTLithium-ion capacitors (LICs) and Hybrid LICs (H-LICs) were assembled as three-layered pouch cells in an asymmetric configuration employing Faradaic pre-lithiated hard carbon anodes and non-Faradaic ion adsorption-desorption activated carbon (AC) cathodes for LICs and lithium iron phosphate (LiFePO4-LFP)/AC composite cathodes for H-LICs. The room temperature rate performance was evaluated after the initial LIC and H-LIC cell formation as a function of the electrolyte additives. The capacity retention was measured after charging at high temperature conditions, while the design factor explored was electrolyte additive formulation, with a focus on their stability. The high temperature potential holds simulate electrochemical energy materials under extreme environments and act to accelerate the failure mechanisms associated with cell degradation to determine robust electrolyte/additive combinations.

scholarly journals Investigating the lithium ion battery electrolyte additive tris (2,2,2-trifluoroethyl) phosphite by gas chromatography with a flame ionization detector (GC-FID)

RSC Advances ◽  
2017 ◽  
Vol 7 (84) ◽  
pp. 53048-53055 ◽  
Author(s):  
Tim Dagger ◽  
Jonas Henschel ◽  
Babak Rad ◽  
Constantin Lürenbaum ◽  
Falko M. Schappacher ◽  
...  
Keyword(s):  
Gas Chromatography ◽  
Lithium Ion Battery ◽  
Analytical Methods ◽  
Flame Retardants ◽  
Lithium Ion ◽  
Ionization Detector ◽  
Electrolyte Additive ◽  
Electrolyte Additives ◽  
Flame Ionization ◽  
Battery Electrolyte

The quantification of lithium ion battery electrolyte additives like flame retardants is both important and challenging. Here, different analytical methods were applied to investigate detection phenomena when applying GC-FID for the quantification.

scholarly journals Realizing a high-performance LiNi0.6Mn0.2Co0.2O2/silicon–graphite full lithium ion battery cell via a designer electrolyte additive

2020 ◽  
Vol 8 (37) ◽  
pp. 19573-19587 ◽  
Author(s):  
Felix Aupperle ◽  
Gebrekidan Gebresilassie Eshetu ◽  
Kevin W. Eberman ◽  
Ang Xioa ◽  
Jean-Sebastien Bridel ◽  
...  
Keyword(s):  
High Temperature ◽  
Lithium Ion Battery ◽  
High Performance ◽  
Lithium Ion ◽  
Battery Cell ◽  
Electrolyte Additive ◽  
Electrolyte Interface

The dosage of (2-cyanoethyl)triethoxysilane (TEOSCN) is investigated as the electrode/electrolyte interface modulating electrolyte additive to improve the performance of LiN0.6Mn0.2Co0.2O2/silicon–graphite batteries at a high temperature (45 °C).

1-(2-Cyanoethyl)pyrrole enables excellent battery performance at high temperature via the synergistic effect of Lewis base and CN functional groups

2020 ◽  
Vol 56 (60) ◽  
pp. 8420-8423
Author(s):  
Kaijia Duan ◽  
Jingrong Ning ◽  
Lai Zhou ◽  
Wenjia Xu ◽  
Chuanqi Feng ◽  
...  
Keyword(s):  
High Temperature ◽  
Synergistic Effect ◽  
Lithium Ion Batteries ◽  
Functional Groups ◽  
High Performance ◽  
Lithium Ion ◽  
Lewis Base ◽  
Electrolyte Additive

1-(2-Cyanoethyl)pyrrole electrolyte additive via a capturing strategy enables high-performance of lithium-ion batteries at high temperature.

Assessment of wheat (Triticum aestivum L.) genotypes for high temperature stress tolerance using physico-chemical analysis

2020 ◽  
Vol 53 (2) ◽  
Author(s):  
Khalil Ahmed Laghari ◽  
Abdul Jabbar Pirzada ◽  
Mahboob Ali Sial ◽  
Muhammad Athar Khan ◽  
Jamal Uddin Mangi
Keyword(s):  
Triticum Aestivum ◽  
High Temperature ◽  
Chemical Analysis ◽  
Stress Tolerance ◽  
Temperature Stress ◽  
Triticum Aestivum L ◽  
High Temperature Stress ◽  
Physico Chemical

Genome-wide identification and analysis of maize PAL gene family and its expression profile in response to high-temperature stress

2020 ◽  
Vol 52 (5) ◽  
Author(s):  
De-Gong Wu ◽  
Qiu-Wen Zhan ◽  
Hai-Bing Yu ◽  
Bao-Hong Huang ◽  
Xin-Xin Cheng ◽  
...  
Keyword(s):  
High Temperature ◽  
Gene Family ◽  
Temperature Stress ◽  
Expression Profile ◽  
High Temperature Stress ◽  
Genome Wide

Impact of Metal Pad Etch-Induced Plasma Damage on Dynamic Retention Time Degradation during High Temperature Stress in High Density DRAM Technology

2005 ◽  
Author(s):  
D-J Kim ◽  
I-G Kim ◽  
J-Y Noh ◽  
H-J Lee ◽  
S-H Park ◽  
...  
Keyword(s):  
High Temperature ◽  
Temperature Stress ◽  
Retention Time ◽  
High Temperature Stress ◽  
High Density ◽  
Cell Junction ◽  
Antenna Effect ◽  
Plasma Damage ◽  
Root Cause ◽  
Wafer Processing

Abstract As DRAM technology extends into 12-inch diameter wafer processing, plasma-induced wafer charging is a serious problem in DRAM volume manufacture. There are currently no comprehensive reports on the potential impact of plasma damage on high density DRAM reliability. In this paper, the possible effects of floating potential at the source/drain junction of cell transistor during high-field charge injection are reported, and regarded as high-priority issues to further understand charging damage during the metal pad etching. The degradation of block edge dynamic retention time during high temperature stress, not consistent with typical reliability degradation model, is analyzed. Additionally, in order to meet the satisfactory reliability level in volume manufacture of high density DRAM technology, the paper provides the guidelines with respect to plasma damage. Unlike conventional model as gate antenna effect, the cell junction damage by the exposure of dummy BL pad to plasma, was revealed as root cause.

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