NiFe-LDH@ZnO@NF composite for photo-degradation of Rhodamine B dye

MRS Advances ◽  
2019 ◽  
Vol 4 (33-34) ◽  
pp. 1887-1893
Author(s):  
Jun Wu ◽  
Yonghui Gong ◽  
Qiang Fu ◽  
Chunxu Pan
Keyword(s):  
Rhodamine B ◽  
Photocatalytic Performance ◽  
Nickel Foam ◽  
Photogenerated Electron ◽  
Chemical Compositions ◽  
Photocatalytic Efficiency ◽  
Electron Hole ◽  
Photo Degradation ◽  
Potential Applications ◽  
Rhodamine B Dye

ABSTRACTIn this paper, a novel NiFe-LDH@ZnO composite was prepared by using a facile two-step process upon nickel foam (NF) substrate. The morphologies and chemical compositions of the samples were characterized by SEM, EDS, XRD and XPS. Photocatalytic degradation of Rhodamine B dye was tested with the samples NiFe-LDH@ZnO@NF, ZnO@NF and NiFe-LDH under the same conditions. The experimental results revealed that the NiFe-LDH@ZnO@NF composite exhibited excellent photocatalytic performance, i.e., 1.4 and 2.5 times higher than that of pure ZnO and NiFe-LDH, respectively. The reason was that the NiFe-LDH@ZnO@NF composite provided a possibility to effectively inhibit the recombination of the photogenerated electron-hole pairs, and therefore enhanced the photocatalytic efficiency. This composite is expected to have potential applications in wastewater treatment field.

scholarly journals Preparation and Photocatalytic Performance for Degradation of Rhodamine B of AgPt/Bi4Ti3O12 Composites

Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2206
Author(s):  
Gaoqian Yuan ◽  
Gen Zhang ◽  
Kezhuo Li ◽  
Faliang Li ◽  
Yunbo Cao ◽  
...  
Keyword(s):  
Visible Light ◽  
Noble Metal ◽  
Rhodamine B ◽  
Photocatalytic Performance ◽  
Bimetallic Nanoparticles ◽  
Resonance Effect ◽  
Visible Region ◽  
Photogenerated Electron ◽  
Pt Nanoparticles ◽  
Electron Hole

Loading a noble metal on Bi4Ti3O12 could enable the formation of the Schottky barrier at the interface between the former and the latter, which causes electrons to be trapped and inhibits the recombination of photoelectrons and photoholes. In this paper, AgPt/Bi4Ti3O12 composite photocatalysts were prepared using the photoreduction method, and the effects of the type and content of noble metal on the photocatalytic performance of the catalysts were investigated. The photocatalytic degradation of rhodamine B (RhB) showed that the loading of AgPt bimetallic nanoparticles significantly improved the catalytic performance of Bi4Ti3O12. When 0.10 wt% noble metal was loaded, the degradation rate for RhB of Ag0.7Pt0.3/Bi4Ti3O12 was 0.027 min−1, which was respectively about 2, 1.7 and 3.7 times as that of Ag/Bi4Ti3O12, Pt/Bi3Ti4O12 and Bi4Ti3O12. The reasons may be attributed as follows: (i) the utilization of visible light was enhanced due to the surface plasmon resonance effect of Ag and Pt in the visible region; (ii) Ag nanoparticles mainly acted as electron acceptors to restrain the recombination of photogenerated electron-hole pairs under visible light irradiation; and (iii) Pt nanoparticles acted as electron cocatalysts to further suppress the recombination of photogenerated electron-hole pairs. The photocatalytic performance of Ag0.7Pt0.3/Bi4Ti3O12 was superior to that of Ag/Bi4Ti3O12 and Pt/Bi3Ti4O12 owing to the synergistic effect between Ag and Pt nanoparticles.

scholarly journals Rationally Designed Bi2M2O9 (M = Mo/W) Photocatalysts with Significantly Enhanced Photocatalytic Activity

Molecules ◽  
2021 ◽  
Vol 26 (23) ◽  
pp. 7334
Author(s):  
Fangzhi Wang ◽  
Xiaoyan Zhou ◽  
Jing Li ◽  
Qiuyue He ◽  
Ling Zheng ◽  
...  
Keyword(s):  
Diffuse Reflectance ◽  
Photocatalytic Performance ◽  
Diffuse Reflectance Spectroscopy ◽  
Photogenerated Electron ◽  
Reflectance Spectroscopy ◽  
Active Species ◽  
Photocatalytic Efficiency ◽  
Electron Hole ◽  
Radical Trapping ◽  
Structure Morphology

Novel Bi2W2O9 and Bi2Mo2O9 with irregular polyhedron structure were successfully synthesized by a hydrothermal method. Compared to ordinary Bi2WO6 and Bi2MoO6, the modified structure of Bi2W2O9 and Bi2Mo2O9 were observed, which led to an enhancement of photocatalytic performance. To investigate the possible mechanism of enhancing photocatalytic efficiency, the crystal structure, morphology, elemental composition, and optical properties of Bi2WO6, Bi2MO6, Bi2W2O9, and Bi2Mo2O9 were examined. UV-Vis diffuse reflectance spectroscopy revealed the visible-light absorption ability of Bi2WO6, Bi2MO6, Bi2W2O9, and Bi2Mo2O9. Photoluminescence (PL) and photocurrent indicated that Bi2W2O9 and Bi2Mo2O9 pose an enhanced ability of photogenerated electron–hole pairs separation. Radical trapping experiments revealed that photogenerated holes and superoxide radicals were the main active species. It can be conjectured that the promoted photocatalytic performance related to the modified structure, and a possible mechanism was discussed in detail.

scholarly journals Construction of Ag3PO4/SnO2 Heterojunction on Carbon Cloth with Enhanced Visible Light Photocatalytic Degradation

2020 ◽  
Vol 10 (9) ◽  
pp. 3238
Author(s):  
Min Liu ◽  
Guangxin Wang ◽  
Panpan Xu ◽  
Yanfeng Zhu ◽  
Wuhui Li
Keyword(s):  
Visible Light ◽  
Photocatalytic Performance ◽  
Separation Efficiency ◽  
Photogenerated Electron ◽  
Carbon Cloth ◽  
Electron Hole ◽  
Step Process ◽  
Photogenerated Electrons ◽  
Rapid Transfer ◽  
Visible Light Photocatalytic

In this study, the Ag3PO4/SnO2 heterojunction on carbon cloth (Ag3PO4/SnO2/CC) was successfully fabricated via a facile two-step process. The results showed that the Ag3PO4/SnO2/CC heterojunction exhibited a remarkable photocatalytic performance for the degradation of Rhodamine B (RhB) and methylene blue (MB), under visible light irradiation. The calculated k values for the degradation of RhB and MB over Ag3PO4/SnO2/CC are 0.04716 min−1 and 0.04916 min−1, which are higher than those calculated for the reactions over Ag3PO4/SnO2, Ag3PO4/CC and SnO2/CC, respectively. The enhanced photocatalytic activity could mainly be attributed to the improved separation efficiency of photogenerated electron-hole pairs, after the formation of the Ag3PO4/SnO2/CC heterojunction. Moreover, carbon cloth with a large specific surface area and excellent conductivity was used as the substrate, which helped to increase the contact area of dye solution with photocatalysts and the rapid transfer of photogenerated electrons. Notably, when compared with the powder catalyst, the catalysts supported on carbon cloth are easier to quickly recycle from the pollutant solution, thereby reducing the probability of recontamination.

scholarly journals Synthesis and characterization of Z-scheme heterostructure CoWO4/g-C3N4 as a visible-light photocatalyst for removal of organic pollutant

2021 ◽  
Vol 10 (2) ◽  
pp. 59-63
Author(s):  
Hai Pham Viet ◽  
Anh Dao Thi Ngoc ◽  
Viet Nguyen Minh ◽  
Ha Tran Thi Viet ◽  
Dang Do Van ◽  
...  
Keyword(s):  
Visible Light ◽  
Rhodamine B ◽  
High Performance ◽  
Organic Pollutant ◽  
Photogenerated Electron ◽  
Morphological Properties ◽  
Electron Hole ◽  
Visible Light Photocatalyst ◽  
Photocatalytic Activities

In this study, direct Z–scheme heterostructure CoWO4/g-C3N4 was synthesized by a facile hydrothermal method. The structural, morphological properties of the prepared samples were characterised by XRD, SEM, UV–Vis and PL measurements. The as-obtained heterostructure CoWO4/g-C3N4 exhibited enhanced photocatalytic activities toward the degradation of Rhodamine B under visible light irradiation with 92% Rhodamine B removal after 80 minutes irritation, which exceeded pristine g-C3N4 and CoWO4. The enhanced photocatalytic performance ascribed to interfacial contact between g-C3N4 and CoWO4, thus further inhibiting the recombination of photogenerated electron/hole pairs. It is anticipated that the construction of Z–scheme heterostructure CoWO4/g-C3N4 is an effective strategy to develop high-performance photocatalysts for the degradation of organic pollutants in water.

The Functional TiO2-Biodegradable Plastic Composite Material Produced by HVOF Spraying Process

2007 ◽  
Vol 7 (11) ◽  
pp. 3830-3833 ◽  
Author(s):  
Hee-Seon Bang ◽  
Han-Sur Bang ◽  
Yoon-Ki Lee
Keyword(s):  
Photocatalytic Performance ◽  
Xrd Analysis ◽  
Gas Pressure ◽  
Photocatalytic Efficiency ◽  
Hvof Spraying ◽  
Photo Degradation ◽  
Fuel Gas ◽  
Plastic Composite ◽  
Polybutylene Succinate ◽  
Spraying Process

Photocatalytic TiO2 coatings on bio-degradable plastic(polybutylene succinate: PBS) were prepared by HVOF spraying using three kinds of agglomerated powders (P200: 200 nm, P30: 30 nm, P7: 7 nm). The microstructures of the coatings were characterized with SEM and XRD analysis, and the photocatalytic efficiency of the coatings was evaluated by photo degradation of gaseous acetaldehyde. For both the HVOF sprayed P200 and P30 coatings, high anatase ratio of 100% was achieved, regardless of the fuel gas pressure. On the other hand, for the HVOF sprayed P7 coating, the anatase ratio decreased from 100% to 49.1% with increasing fuel gas pressure. This decrease may be attributed to the much higher susceptibility to heat of the 7 nm agglomerated powders than the 30 nm and 200 nm agglomerated powders. In terms of the photocatalytic efficiency, HVOF sprayed P200 and P30 coatings seemed to outperform the P7 coatings because of their higher anatase ratios. However, the HVOF sprayed P7 coatings did not show photocatalytic activity possibly because of the extremely small reaction surface area to the photo-catalytic activity and low anatase ratio. Therefore, the present study found that functional PBS plastic with photocatalytic performance could be produced by spraying of ceramics such as TiO2.

Temperature and Salinity Effects on Photocatalytic Performance of Cerium Doped Zinc Oxide

2020 ◽  
Vol 307 ◽  
pp. 223-228
Author(s):  
Wan Rafizah Wan Abdullah ◽  
Lee Chia Siang ◽  
Maishara Syazrinni Rooshde ◽  
Mohd Sabri Mohd Ghazali
Keyword(s):  
Photocatalytic Performance ◽  
Catalyst Surface ◽  
Uv Light ◽  
Operating Temperature ◽  
Chloride Ions ◽  
Photocatalytic Efficiency ◽  
Electron Hole ◽  
Doped Zno ◽  
The Stability ◽  
Uv C

Cerium (Ce) doped ZnO is a promising material for advanced photocatalysis. It is useful for inducing the treatment of many organic pollutants in water. However, the stability of its performance under varying temperature and saline condition has never been not fully assessed. In this study, powder form photocatalyst comprising 99.0 mol% ZnO and 1 mol% CeO2 has been synthesized via modified citrate gelation technique and solid-state sintering at 1200 °C for 5 hours. The conversion of Ce doped ZnO from its precursors has been confirmed using XRD, SEM, and EDX techniques. The photocatalytic efficiency of the synthesized Ce doped ZnO under UV-C light (λ=265 nm) was determined. In the experiment, the operating temperature was varied between 25 to 40 °C, and the salinity of the treated solution was increased from 0 to 40 g/L NaCl. The findings revealed that the photocatalytic efficiency of Ce doped ZnO under UV light improved from 78.2% to 88.6% as the temperature increased from 25 to 40 °C. The performance of Ce doped ZnO decreased from 86.7% to 36.7% when the salinity increased from 0 g/L to 40 g/L. The elevation of temperature encouraged the photogeneration of electron-hole pairs on catalyst surface while the presence of chloride ions in treated medium caused scavenging of hydroxyl radicals or hole.

scholarly journals A Laboratory-based Experiment on the Efficacy of Graphitic Carbon Nitride Doped with Tungsten Chloride in the Purification of Industrial Wastewater through Degradation of Organic Dye Pollutant

2019 ◽  
Vol 8 (2) ◽  
pp. 62
Author(s):  
Sheila Moraa Ngare ◽  
Juliet Nzula ◽  
Donde Oscar Omondi
Keyword(s):  
Rhodamine B ◽  
Industrial Wastewater ◽  
Carbon Nitride ◽  
Synergetic Effect ◽  
Organic Dye ◽  
Graphitic Carbon ◽  
Graphitic Carbon Nitride ◽  
Photo Degradation ◽  
Rhodamine B Dye ◽  
Tungsten Chloride

Water is an essential commodity whose quantity and quality needs to be secured for easier accessibility at both the industrial, public and household levels. However, its availability in adequate quality and quantity has continued to decline worldwide. Indeed, rise in human population coupled with the climate change phenomena have greatly impacted on the quality of water resources through increased organic and inorganic pollution. Rhodamine B (RhB) dye is a common organic pollutant majorly in industrial wastewater and with numerous environmental and human health effects. The application of graphitic carbon nitride (G-C3N4) in the purification of industrial wastewater to enhance the removal of RhB is a technology of interest to most environmental quality regulators and agencies. The study was therefore aimed at investigating the performance of graphitic carbon nitride doped with tungsten chloride in the degradation of organic dye pollutant rhodamine B dye from industrial wastewater. The study showed that the as-prepared hybrid photo catalyst exhibits an improved photo degradation performance because of its synergetic effect. Indeed, the photo excited electrons from g-C3N4 were able to efficiently separate and are injected to the conductive band of WO3. The optimum photo activity occurred at the optimum ratio of 0.25WO3/g- C3N4. There was also stability and efficiency within the hybrid catalyst within the photo degradation process. Indeed, the composite indicates a high activity for degradation of RhB under visible light irradiation. The presence of g-C3N4 proved to be beneficial for enhancement in photo catalytic activity of the g-C3N4-WO3 composite and proved to be one of the best alternative modes of n the degrading organic dye pollutant Rhodamine B dye from wastewater.

scholarly journals Improved Photo Degradation of Rhodamine B Dye using Iron Oxide/Carbon Nanocomposite by Photo-Fenton Reaction

2008 ◽  
Vol 9 (3) ◽  
pp. 195-199 ◽  
Author(s):  
Min-Il Kim ◽  
Ji-Sun Im ◽  
Se-Jin In ◽  
Hyuk Kim ◽  
Jong-Gyu Kim ◽  
...  
Keyword(s):  
Iron Oxide ◽  
Rhodamine B ◽  
Fenton Reaction ◽  
Photo Degradation ◽  
Rhodamine B Dye ◽  
Carbon Nanocomposite

scholarly journals Synthesis and characterization of black TiO2/graphene composites with enhanced photocatalysis

2020 ◽  
Author(s):  
Zhaoqing Li ◽  
Zhufeng Liu ◽  
Xiao Yang ◽  
Peng Chen ◽  
Lei Yang ◽  
...  
Keyword(s):  
Visible Light ◽  
Photocatalytic Performance ◽  
Sol Gel ◽  
Photogenerated Electron ◽  
Catalytic Performance ◽  
Attractive Potential ◽  
Electron Hole ◽  
Hole Recombination

Abstract According to the composite design, a series of black TiO2/graphene composites were synthesized to improve its photocatalytic activity. TiO2 is generated in situ on the surface of graphene by a facile sol-gel method. The combination of graphene and TiO2 was beneficial for eliminating the opportunity of photogenerated electron-hole recombination due to the excellent conductivity of graphene. In the subsequent hydrogenation process, the self-doping Ti3+ was introduced accompanied by the crystallization of amorphous TiO2. The narrowed bandgap caused by self-doping Ti3+ enhanced the visible light absorption and make the composites appear black. Both of them improved the photocatalytic performance of the synthesized black TiO2/graphene composites. The band structure of the composite was analyzed by valence band XPS, revealing the reason for the high visible light catalytic performance of the composite. The results proved that the black TiO2/graphene composites synthesized show attractive potential for applications in environmental and energy issues.

Surface oxygen vacancy and defect engineering of WO3 for improved visible light photocatalytic performance

2018 ◽  
Vol 8 (17) ◽  
pp. 4399-4406 ◽  
Author(s):  
Qi Liu ◽  
Fengjiao Wang ◽  
Huaxiang Lin ◽  
Yanyu Xie ◽  
Na Tong ◽  
...  
Keyword(s):  
Oxygen Vacancy ◽  
Visible Light ◽  
Photocatalytic Performance ◽  
Photogenerated Electron ◽  
Vacancy Defect ◽  
Surface Oxygen ◽  
Defect Engineering ◽  
Electron Hole ◽  
Surface Oxygen Vacancy ◽  
Visible Light Photocatalytic

Compared to the pristine WO3, the oxygen vacancy defect levels of the sub-stoichiometric WO3−X narrow the bandgap and promote the separation of photogenerated electron–hole pairs.

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