Phase Equilibria Among β/α/α2/γ Phases and Phase Transformations in Ti-Al-Cr System at Elevated Temperatures

MRS Advances ◽  
2019 ◽  
Vol 4 (25-26) ◽  
pp. 1471-1476
Author(s):  
Ali Shaaban ◽  
Hideki Wakabayashi ◽  
Hirotoyo Nakashima ◽  
Masao Takeyama
Keyword(s):  
Phase Equilibria ◽  
Tial Alloy ◽  
Elevated Temperatures ◽  
Volume Fraction ◽  
Eutectoid Reaction ◽  
Al Content ◽  
Three Phase ◽  
Cr Addition ◽  
Cr System ◽  
Tie Line

Abstract:Effects of Cr addition to TiAl alloy on the phase equilibria among β/α/α2/γ Phases and phase transformation pathways within the temperature range of 1523 K∼1073 K were investigated using several alloys in the composition of interest. In between 1473 K and 1373 K, The slope of β/α tie-line in the three-phase coexisting region of β+α+γ remains basically unchanged. However, this slope drastically rotates in a clockwise direction, in between 1373 K and 1273 K and below the eutectoid reaction temperature in the binary system (1400 K). This is a strong indication that α-phase exists even below the 1400 K, i.e. addition of Cr stabilizes α against α2 and the three-phase coexisting region of β+α2+γ at lower temperatures is formed through a ternary eutectoid reaction (α → β+α2+γ) with decreasing temperature. This three-phase tie-triangle moves towards lower Al content in phase diagram. This suggests that Cr addition results in increase of the volume fraction of γ-phase with decreasing temperature even in alloys with low Al content.

Microstructure Characterization of High Carbon Alloy from the Ni-Ta-Al-Co-Cr System / Charakterystyka Mikrostruktury Wysokowęglowego Stopu Z Układu Ni-Ta-Al-Co-Cr

2012 ◽  
Vol 57 (4) ◽  
pp. 937-941 ◽  
Author(s):  
P. Bała
Keyword(s):  
Heat Treatment ◽  
Wear Resistance ◽  
Elevated Temperatures ◽  
Chromium Content ◽  
Volume Fraction ◽  
High Carbon ◽  
Cr System ◽  
Primary Carbides ◽  
Cast Condition

In the present work results of investigations of the new high carbon alloy from the Ni-Ta-Al-Co-Cr system are presented. The alloy has been designed to have a good tribological properties at elevated temperatures. The chemical composition of this material was designed to obtain a matrix strengthening by the precipitation of γ’ phase (Ni3(Al,Ta)) and the primary carbides volume fraction above 25%. The primary carbides should remain stable in the microstructure, regardless of the heat treatment, in order to increase a wear resistance. The results of microstructure investigations in the as-cast condition are presented. The type of phases appearing in the microstructure was determined and their morphology described. The main microstructure components of the investigated Ni-based alloy with high carbon, cobalt and chromium content are: the γ phase, which constitutes a matrix, the γ’ phase, which occurs as fine globular precipitates and the primary Ta and Cr carbides (of MC and M7C3 type - respectively).

The Effect of Ti Addition on Phase Equilibria among Ni (A1), Ni3Al (L12) and Ni3V (D022) Phases

2010 ◽  
Vol 654-656 ◽  
pp. 432-435 ◽  
Author(s):  
Eiki Hayashi ◽  
Satoru Kobayashi ◽  
Kazuhisa Sato ◽  
Toyohiko J. Konno ◽  
Yasuyuki Kaneno ◽  
...  
Keyword(s):  
Binary System ◽  
Ternary System ◽  
Phase Equilibria ◽  
Eutectoid Reaction ◽  
Eds Analysis ◽  
Heat Treated ◽  
Three Phase ◽  
Rich Side ◽  
Ti Addition

The effect of Ti addition on phase equilibria among Ni (A1), Ni3Al (L12) and Ni3V (D022) phases at 950 °C was investigated through TEM/EDS analysis on heat-treated alloys. The three-phase coexisting region of A1 + L12 + D022 was found to exist around the composition of Ni-4Al-19V (at. %) in the Ni-Al-V ternary system. With addition of Ti to the ternary system the three-phase coexisting region was shifted to the Ni-rich side. Ti partitioned most into the L12 phase and least into the A1 phase. These results suggest that the addition of Ti stabilizes the L12 and D022 phases against A1 phase, and raises the temperature of eutectoid reaction in the Ni3Al-Ni3V pseudo-binary system: A1 → L12 + D022.

Phase Equilibria among γ-Fe, γ-Fe and Fe2Mo Phases and Stability of the Laves Phase in Fe-Mo-Ni Ternary System at Elevated Temperatures

2006 ◽  
Vol 980 ◽  
Author(s):  
Shigehiro Ishikawa ◽  
Takashi Matsuo ◽  
Masao Takeyama
Keyword(s):  
Ternary System ◽  
Phase Equilibria ◽  
Elevated Temperatures ◽  
Phase Region ◽  
Homogeneity Region ◽  
Nickel Concentration ◽  
Peritectoid Reaction ◽  
Two Phase ◽  
Three Phase ◽  
Binary Edge

AbstractPhase equilibria among the bcc Fe(α), fcc Fe(γ) and Fe2Mo(λ)_phases in Fe-Mo-Ni ternary system, particularly paying attention to the existence of the γ+λ two-phase region, have been examined at elevated temperatures below Tc (1200 K), the peritectoid reaction temperature in Fe-Mo binary system: λ?α+Fe7Mo6 (μ). At 1173 K the α+γ+μ three-phase coexisting region exists near the Fe-Mo binary edge and no λ phase region was identified. At 1073 K the λ phase in equilibrium with α and γ phases exists, although the composition homogeneity region of the ternary λ phase was limited to its binary edge toward the equi-nickel concentration direction up to about 3at % Ni. Instead, large two-phase region of γ+μ was extended along the same direction up to 20 at% Ni. The γ+λ two-phase region appears below Tc through a transition peritectoid reaction: α+μ¨γ+λ. The γ phase in equilibrium with λ phase is stable only at elevated temperatures, and it transforms martensitically to α phase during cooling. The addition of Ni stabilizes γ and μ phases against α and λ phases, thereby decreasing the relative stability of the λ phase.

Polymer-derived Ceramics as Innovative Oxidation Barrier Coatings for Mo-Si-B Alloys

2015 ◽  
Vol 1760 ◽  
Author(s):  
Manja Krüger ◽  
Georg Hasemann ◽  
Torben Baumann ◽  
Sebastian Dieck ◽  
Stefan Rannabauer
Keyword(s):  
Mechanical Properties ◽  
Elevated Temperatures ◽  
Silicon Oxide ◽  
Volume Fraction ◽  
Protective Coatings ◽  
High Volume ◽  
Dip Coating ◽  
Solid Solution Phase ◽  
Polymer Derived Ceramics ◽  
Three Phase

ABSTRACTThree phase Mo-Mo3Si-Mo5SiB2 alloys possess excellent mechanical properties over a wide temperature range. The Mo solid solution phase is needed for balanced mechanical properties at room temperature. However, this phase suffers from catastrophic oxidation behavior at high temperatures caused by the formation and evaporation of MoO3. The oxidation resistance of three phase alloys benefits from a high volume fraction of intermetallic phases. In particular Mo5SiB2 leads to the formation of a borosilicate protective glassy layer on the material’s surface while exposed to air at elevated temperatures. Hence, it is unlikely to identify alloy compositions that will yield both optimum mechanical and oxidation performance.Different coating systems and techniques, such as pack cementation, magnetron sputtering and plasma spraying are discussed in the literature to control the oxidation properties of Mo-based alloys. A different approach is to apply coating systems based on polymer derived ceramics (PDCs). Our present work introduces PDCs as a new type of promising and innovative oxidation-protective coatings for high temperature Mo-based alloys. After dip-coating with perhydropolysilazane (PHPS) and pyrolysis at 800 °C, dense and well-adhered SiNO ceramic layers could be achieved. These were investigated by scanning electron microscopy. Cyclic oxidation tests at 800 °C and 1100 °C were performed to investigate mass changes due to the thermal treatment. Indeed, even thin pyrolyzed PHPS layers with a thickness of around 70 nm to 175 nm protected the Mo-Si-B substrate during the initial stage of oxidation. By increasing the silicon oxide concentration at the material’s surface a first oxidation barrier was provided and thus, the strong initial mass loss could be decreased as compared to uncoated alloys. Furthermore, first results of the ongoing optimization process on PDC-coatings applied to Mo-Si-B alloys will be presented, involving the enhancement of the coating´s thickness or varying pyrolysis atmospheres.

Assessment of the Phase Equilibria among γ-Fe/ Fe2Nb/ Ni3Nb Phases in Fe-Ni-Nb Ternary System at Elevated Temperatures

2011 ◽  
Vol 1295 ◽  
Author(s):  
Y. Hasebe ◽  
K. Hashimoto ◽  
T. Matsuo ◽  
M. Takeyama
Keyword(s):  
Isothermal Section ◽  
Ternary System ◽  
Phase Equilibria ◽  
Ternary Compound ◽  
Elevated Temperatures ◽  
Composition Range ◽  
Interaction Parameters ◽  
Three Phase ◽  
Good Agreement

ABSTRACTPhase equilibria among γ-Fe, ε-Fe2Nb Laves and δ-Ni3Nb phases in Fe-Ni-Nb ternary system at 1473 K and 1373 K were experimentally examined, and also assessed by calculation in order to calculate the phase equilibria among these phases at 973 K. A ternary compound with hP24 structure with its limited composition range of Fe-21.5Nb- (56.8-59.8) Ni exists between Fe2Nb and Ni3Nb phase regions at both temperatures. Including the hP24 phase, the calculated isotherms at both temperatures are in good agreement with experimental ones. By using the optimized interaction parameters among the three elements in each phase, the isothermal section calculated at 973 K revealed a γ-Fe+ Fe2Nb + Ni3Nb three-phase coexisting region extended to Fe-rich composition of 80 at. % Fe. This suggests a possibility to develop austenitic heatresistant steels strengthened by both intermetallics phases.

scholarly journals Design of Low-Cost and High-Strength Titanium Alloys Using Pseudo-Spinodal Mechanism through Diffusion Couple Technology and CALPHAD

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2910
Author(s):  
Chaoyi Ding ◽  
Chun Liu ◽  
Ligang Zhang ◽  
Di Wu ◽  
Libin Liu
Keyword(s):  
Diffusion Couple ◽  
Titanium Alloys ◽  
High Throughput ◽  
Volume Fraction ◽  
Raw Materials ◽  
Low Cost ◽  
High Strength ◽  
High Yield ◽  
Α Phase ◽  
Cr System

The high cost of development and raw materials have been obstacles to the widespread use of titanium alloys. In the present study, the high-throughput experimental method of diffusion couple combined with CALPHAD calculation was used to design and prepare the low-cost and high-strength Ti-Al-Cr system titanium alloy. The results showed that ultra-fine α phase was obtained in Ti-6Al-10.9Cr alloy designed through the pseudo-spinodal mechanism, and it has a high yield strength of 1437 ± 7 MPa. Furthermore, application of the 3D strength model of Ti-6Al-xCr alloy showed that the strength of the alloy depended on the volume fraction and thickness of the α phase. The large number of α/β interfaces produced by ultra-fine α phase greatly improved the strength of the alloy but limited its ductility. Thus, we have demonstrated that the pseudo-spinodal mechanism combined with high-throughput diffusion couple technology and CALPHAD was an efficient method to design low-cost and high-strength titanium alloys.

scholarly journals Application of Artificial Intelligence and Gamma Attenuation Techniques for Predicting Gas–Oil–Water Volume Fraction in Annular Regime of Three-Phase Flow Independent of Oil Pipeline’s Scale Layer

Mathematics ◽  
2021 ◽  
Vol 9 (13) ◽  
pp. 1460
Author(s):  
Abdulaziz S. Alkabaa ◽  
Ehsan Nazemi ◽  
Osman Taylan ◽  
El Mostafa Kalmoun
Keyword(s):  
Gamma Radiation ◽  
Volume Fraction ◽  
Phase Flow ◽  
Gas Oil ◽  
Oil Pipeline ◽  
Intelligent Technique ◽  
Scale Layer ◽  
Three Phase ◽  
Three Phase Flow ◽  
Annular Regime

To the best knowledge of the authors, in former studies in the field of measuring volume fraction of gas, oil, and water components in a three-phase flow using gamma radiation technique, the existence of a scale layer has not been considered. The formed scale layer usually has a higher density in comparison to the fluid flow inside the oil pipeline, which can lead to high photon attenuation and, consequently, reduce the measuring precision of three-phase flow meter. The purpose of this study is to present an intelligent gamma radiation-based, nondestructive technique with the ability to measure volume fraction of gas, oil, and water components in the annular regime of a three-phase flow independent of the scale layer. Since, in this problem, there are several unknown parameters, such as gas, oil, and water components with different amounts and densities and scale layers with different thicknesses, it is not possible to measure the volume fraction using a conventional gamma radiation system. In this study, a system including a 241Am-133Ba dual energy source and two transmission detectors was used. The first detector was located diametrically in front of the source. For the second detector, at first, a sensitivity investigation was conducted in order to find the optimum position. The four extracted signals in both detectors (counts under photo peaks of both detectors) were used as inputs of neural network, and volume fractions of gas and oil components were utilized as the outputs. Using the proposed intelligent technique, volume fraction of each component was predicted independent of the barium sulfate scale layer, with a maximum MAE error of 3.66%.

Large-scale deformation of a single-phase TiAl alloy at elevated temperatures

1993 ◽  
Vol 14 (1) ◽  
pp. 61-63 ◽  
Author(s):  
J.C.F. Millett ◽  
J.W. Brooks ◽  
I.P. Jones
Keyword(s):  
Large Scale ◽  
Single Phase ◽  
Tial Alloy ◽  
Elevated Temperatures
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