Development of an ecological varnish from the resin of pine

MRS Advances ◽  
2018 ◽  
Vol 3 (63) ◽  
pp. 3827-3832
Author(s):  
Nelly Flores-Ramírez ◽  
Erandini Guzmán-Mejía ◽  
Salomón R. Vásquez-García ◽  
Lada Domratcheva-Lvova ◽  
Leandro Garcia-Gonzalez ◽  
...  

ABSTRACTRosin resin is constituted by rosin acids, in particular, abietic acid, which is an inexpensive substance. This paper concerns the study of the molecular interactions between a bifunctional monomer of abietic acid with isocyanate to form polyurethane. Polyurethane is a varnish that can be applied to any timber surface protecting it from chemical and environmental factors. Furthermore, the polar groups (OH´s) of the diol have a direction along the molecular axis thus, increasing their intermolecular interactions with the isocyanate groups. The varnish named as (PAR), was synthesized in the laboratory and applied to a timber surface whereby its functionality was evaluated. Morphological and spectroscopic studies were carried out on the diol obtained and the polyurethane. Likewise, we behaved several of physical and chemical analyses of vanish. The comparative SEM showed a homogeneous phase on the PAR surface and FTIR between the diphenylmethane, 4-4, diisocyanate (MDI) and the varnish from hydroxylated rosin resin (HAA) showed that the reaction was carried out in its entirety, exhausting the limiting reagent (MDI). The obtained varnish which was labelled as PAR has very suitable characteristics for indoor use. It has a transparent and bright appearance, a solids percentage of 44-45%, a drying time for application between layers and layers of 15-20 minutes.

2019 ◽  
Vol 958 ◽  
pp. 111-115
Author(s):  
V.A.S. Schein ◽  
G. Conte ◽  
Marilena Valadares Folgueras ◽  
L.V.O. Dalla Valentina ◽  
M.R. Medeiros

This paper discusses an environmentally-friendly destination for the residual ashes resulting from the firing of biomass (wood wastes) at the Engie Brasil Cogeneration Power Plant located in Lages, Santa Catarina, Brazil. The study proposes reusing the residue as a substitution for crushed stones in the production of concrete. Environmental, physical, and chemical analyses were performed for characterization of the ashes. Specimens prepared with ash and subjected to testing presented a compressive strength of around 18.63 Mpa (2700 psi), which is in compliance with the ACI-213R and ASTM C330-5 specifications. With pretreatment and proper mixing ratios, biomass ashes may be employed as an aggregate in the manufacture of lightweight structural concrete.


2009 ◽  
Vol 415 ◽  
pp. 45-48 ◽  
Author(s):  
Maria Giurginca ◽  
Lucretia Miu

A comprehensive investigation has been made of a set of historical leather samples from the 17th – 20th centuries. For the investigation of the degradation degree spectral techniques in IR (MID and NIR) and UV-VIS have been used, and collateral Micro Hot Table (MHT) determination as well. Changes in the physical and chemical characteristics values of the leather issues due to the interaction with the environmental factors during a long period of time were used in order to identify the possible deterioration ways.


2008 ◽  
Vol 79 (11) ◽  
pp. 111301 ◽  
Author(s):  
Anita Sengupta ◽  
James Kulleck ◽  
Norm Hill ◽  
Wayne Ohlinger

1994 ◽  
Vol 39 (4) ◽  
pp. 13675J ◽  
Author(s):  
Maria Teresa Pinorini ◽  
Christopher James Lennard ◽  
Pierre Margot ◽  
Isabelle Dustin ◽  
Patrick Furrer

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