Performance of cement mortar with waste ground clay brick

MRS Advances ◽  
2018 ◽  
Vol 3 (34-35) ◽  
pp. 2041-2050
Author(s):  
Mohammed Si-Ahmed ◽  
Said Kenai ◽  
Elhem Ghorbel
Keyword(s):  
Cement Hydration ◽  
Thermo Gravimetric Analysis ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Partial Substitution ◽  
Gravimetric Analysis ◽  
Thermo Gravimetric ◽  
Cement Production ◽  
The Impact

ABSTRACTAn effective way to reduce the impact of cement production on the environment is to use supplementary cementitious materials (SCM) as a partial substitution to cement. In addition to the reduction in cost and energy saving, the use of SCM in cement for the manufacture of mortar and concrete offers technical advantages. In this paper, cement was partially substituted by fines obtained from crushed recycled bricks recovered from a brick plant. The level of substitution was either 0%, 5%, 10% or 15% by weight of cement. The results show that cement substitution by brick fines resulted in a slight loss of workability with the increase of the substitution rate. Substitutions rates of 5% and 10% produced at long-term comparable strength as control mortars. The differential thermal analysis (DTA) and thermo-gravimetric analysis (TGA) results show cement hydration improved significantly with different rates of substitutions at 28 and 180 days of age.

scholarly journals Production of Ultra-High-Performance Concrete with Low Energy Consumption and Carbon Footprint Using Supplementary Cementitious Materials Instead of Silica Fume: A Review

Energies ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 8291
Author(s):  
Mays A. Hamad ◽  
Mohammed Nasr ◽  
Ali Shubbar ◽  
Zainab Al-Khafaji ◽  
Zainab Al Masoodi ◽  
...  
Keyword(s):  
Energy Consumption ◽  
Silica Fume ◽  
High Performance ◽  
High Performance Concrete ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Ultra High Performance Concrete ◽  
Cement Production ◽  
Granulated Blast Furnace Slag ◽  
The Impact

The increase in cement production as a result of growing demand in the construction sector means an increase in energy consumption and CO2 emissions. These emissions are estimated at 7% of the global production of CO2. Ultra-high-performance concrete (UHPC) has excellent mechanical and durability characteristics. Nevertheless, it is costly and affects the environment due to its high amount of cement, which may reach 800–1000 kg/m3. In order to reduce the cement content, silica fume (SF) was utilized as a partial alternative to cement in the production of UHPC. Nevertheless, SF is very expensive. Therefore, the researchers investigated the use of supplementary cementitious materials cheaper than SF. Very limited review investigates addressed the impact of such materials on different properties of UHPC in comparison to that of SF. Thus, this study aims to summarize the effectiveness of using some common supplementary cementitious materials, including fly ashes (FA), ground granulated blast furnace slag (GGBS), metakaolin (MK) and rice husk ashes (RHA) in the manufacturing of UHPC, and comparing the performance of each material with that of SF. The comparison among these substances was also discussed. It has been found that RHA is considered a successful alternative to SF to produce UHPC with similar or even higher properties than SF. Moreover, FA, GGBS and MK can be utilized in combination with SF (as a partial substitute of SF) as a result of having less pozzolanic activity than SF.

Long-term alkali-silica mitigation of high-alkali concrete with cement replacements

2021 ◽  
pp. 1-29
Author(s):  
Douglas Hooton ◽  
Benoit Fournier
Keyword(s):  
Cementitious Materials ◽  
Outdoor Exposure ◽  
Supplementary Cementitious Materials ◽  
Concrete Prism ◽  
Different Temperatures ◽  
Concrete Blocks ◽  
High Alkali ◽  
Mortar Bar ◽  
The Impact

The impact of high-alkali Portland cements on the prescribed level of supplementary cementitious materials required in the Canadian standard for akali-silica reaction mitigation was evaluated. Based on the results, for concretes containing aggregates exhibiting moderate reactivity, the maximum allowable cement alkali limit was raised from 1.00% to 1.15%. For all levels of aggregate reactivity, cement alkali contents could be allowed up to 1.25% provided the recommended level of mitigation by supplementary cementitious materials was increased. In the initial laboratory study, mortar bars and concrete prisms were cast and monitored using two different reactive aggregates and recommended levels of fly ash and slag. For the concrete prism tests, the alkali contents of the cements were increased to 1.25%, as per the standard, or were increased by 0.25%. Instrumented outdoor exposure concrete blocks, along with additional concrete prisms stored at different temperatures, were cast from numerous mixtures made with cement alkali equivalents ranging up to 1.22%. This paper report on the long-term performance of the prisms and concrete blocks after 12 and 27 years. The performance of the outdoor blocks is also compared to predicted performance based on the accelerated mortar bar and concrete prism test results.

scholarly journals Modifying Cement Hydration with NS@PCE Core-Shell Nanoparticles

2017 ◽  
Vol 2017 ◽  
pp. 1-13 ◽  
Author(s):  
Yue Gu ◽  
Qianping Ran ◽  
Wei She ◽  
Jiaping Liu
Keyword(s):  
Cement Hydration ◽  
Fine Particles ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Core Shell ◽  
Shell Nanoparticles ◽  
Pozzolanic Reactivity ◽  
Characteristic Values ◽  
Core Shell Nanoparticles ◽  
The Impact

It is generally accepted that fine particles could accelerate cement hydration process, or, more specifically, this accelerating effect can be attributed to additional surface area introduced by fine particles. In addition to this view, the surface state of fine particles is also an important factor, especially for nanoparticles. In the previous study, a series of nano-SiO2-polycarboxylate superplasticizer core-shell nanoparticles (NS@PCE) were synthesized, which have a similar particle size distribution but different surface properties. In this study, the impact of NS@PCE on cement hydration was investigated by heat flow calorimetry, mechanical property measurement, XRD, and SEM. Results show that, among a series of NS@PCE, NS@PCE-2 with a moderate shell-core ratio appeared to be more effective in accelerating cement hydration. As dosage increases, the efficiency of NS@PCE-2 would reach a plateau which is quantified by various characteristic values. Compressive strength results indicate that strength has a linear correlation with cumulative heat release. A hypothesis was proposed to explain the modification effect of NS@PCE, which highlights a balance between initial dispersion and pozzolanic reactivity. This paper provides a new understanding for the surface modification of supplementary cementitious materials and their application and also sheds a new light on nano-SiO2 for optimizing cement-based materials.

Synthesis and Biocompatibility Evaluation of Poly(HEMA-Co-MMA) Orbital Implant

2005 ◽  
Vol 288-289 ◽  
pp. 485-490 ◽  
Author(s):  
Yi Ping Shi ◽  
Don Fang Yin ◽  
Ping Hu ◽  
Yi Fei Huang ◽  
Lin Liu
Keyword(s):  
Thermo Gravimetric Analysis ◽  
Gravimetric Analysis ◽  
Hydroxyethyl Methacrylate ◽  
Subcutaneous Implantation ◽  
Short Term ◽  
Thermo Gravimetric ◽  
Orbital Implant ◽  
Orbital Implants ◽  
Electronic Microscope

Orbital implant, used for filling the space after enucleation, played an important role in the optical orthopedic operations. However, the clinical application of soft orbital implants was in a limited extent. This paper focused on the synthetic method of a new kind of soft poly (2-hydroxyethyl methacrylate) (PHEMA) orbital implant. This method included two steps, making the orbital implant with through-holes by salt leaking method and improving the compress property of PHEMA by copolymerizing it with methyl methacrylate (MMA). Scanning electronic microscope (SEM), thermo gravimetric analysis (TGA), and compress experiment were carried out to evaluate the physical properties of the implant. And to evaluate the biocompatibility of this poly (HEMA-co-MMA) orbital implant, short term and long term observations were studied after subcutaneous implantation of material blocks and implantation of orbital implants (diameter in 14mm) in rabbits’ orbits.

Coordination Compounds of Some 3d-Transition Metal Ions with N1-[4-(4-bromo-phenylsulfonyl)-benzoyl]-N4-(4-methoxyphenyl)- thiosemicarbazide

2008 ◽  
Vol 59 (7) ◽  
Author(s):  
Madalina Angelusiu ◽  
Maria Negoiu ◽  
Stefania-Felicia Barbuceanu ◽  
Tudor Rosu
Keyword(s):  
Coordination Compounds ◽  
Magnetic Moments ◽  
Thermo Gravimetric Analysis ◽  
Electronic Spectroscopy ◽  
Transition Metal Ions ◽  
Synthesis And Characterization ◽  
Gravimetric Analysis ◽  
Thermo Gravimetric ◽  
New Compounds

The paper presents the synthesis and characterization of Cu(II), Co(II), Ni(II), Cd(II), Zn(II) and Hg(II) complexes with N1-[4-(4-bromo-phenylsulfonyl)-benzoyl]-N4-(4-methoxyphenyl)-thiosemicarbazide. The new compounds were characterized by IR, EPR, electronic spectroscopy, magnetic moments, thermo-gravimetric analysis and elemental analysis.

scholarly journals Special Issue: Supplementary Cementitious Materials in Concrete, Part I

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2291
Author(s):  
Alessandro P. Fantilli ◽  
Daria Jóźwiak-Niedźwiedzka
Keyword(s):  
Environmental Impact ◽  
Portland Cement ◽  
Building Materials ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Special Issue ◽  
Cement Production ◽  
Concrete Part

The environmental impact of the Portland cement production and the large use of cement-based building materials is a growing problem [...]

scholarly journals Development of Nervilia fordii Extract-Loaded Electrospun PVA/PVP Nanocomposite for Antioxidant Packaging

Foods ◽  
2021 ◽  
Vol 10 (8) ◽  
pp. 1728
Author(s):  
Peng Wen ◽  
Teng-Gen Hu ◽  
Yan Wen ◽  
Ke-Er Li ◽  
Wei-Peng Qiu ◽  
...  
Keyword(s):  
Food Packaging ◽  
Thermo Gravimetric Analysis ◽  
Xrd Analysis ◽  
Sem Analysis ◽  
Poly Vinyl Alcohol ◽  
Total Phenolic ◽  
Gravimetric Analysis ◽  
Thermo Gravimetric ◽  
Phenolic And Flavonoid ◽  
Thermal Stability Of

An ethyl acetate extract from of Nervilia fordii (NFE) with considerable suppression activity on lipid peroxidation (LPO) was first obtained with total phenolic and flavonoid contents and anti-LPO activity (IC50) of 86.67 ± 2.5 mg GAE/g sample, 334.56 ± 4.7 mg RE/g extract and 0.307 mg/mL, respectively. In order to improve its stability and expand its application in antioxidant packaging, the nano-encapsulation of NFE within poly(vinyl alcohol) (PVA) and polyvinyl(pyrrolidone) (PVP) bio-composite film was then successfully developed using electrospinning. SEM analysis revealed that the NFE-loaded fibers exhibited similar morphology to the neat PVA/PVP fibers with a bead-free and smooth morphology. The encapsulation efficiency of NFE was higher than 90% and the encapsulated NFE still retained its antioxidant capacity. Fourier transform infrared spectroscopy (FTIR) and X-ray powder diffraction (XRD) analysis confirmed the successful encapsulation of NFE into fibers and their compatibility, and the thermal stability of which was also improved due to the intermolecular interaction demonstrated by thermo gravimetric analysis (TGA). The ability to preserve the fish oil’s oxidation and extend its shelf-life was also demonstrated, suggesting the obtained PVA/PVP/NFE fiber mat has the potential as a promising antioxidant food packaging material.

The Experimental Study on Combustion Characteristics of Corn Straw and Coal Gangue

2011 ◽  
Vol 135-136 ◽  
pp. 1057-1059
Author(s):  
Heng Tao Zhou ◽  
Yong Wei
Keyword(s):  
Thermo Gravimetric Analysis ◽  
Combustion Characteristics ◽  
Combustion Characteristic ◽  
Gravimetric Analysis ◽  
Characteristic Parameters ◽  
Corn Straw ◽  
Kinetics Analysis ◽  
Thermo Gravimetric ◽  
Ignition Characteristic ◽  
Coal Residue

With a thermo gravimetric analysis apparatus combustion characteristics experiments of coal residue cornstalk and mixtures of them were done at 20 C/min heating rate. Then the combustion characteristic Parameters were obtained by above experiments. The c combustion activation energies were acquired by kinetics analysis. The results show those: the ignition characteristic and synthesis combustion characteristic of coal residue are bad. The ignition characteristic and synthesis combustion characteristic of cornstalk are better. The combustion characteristics of the mixture of coal residue and cornstalk are determined by mixing ratio. The ratio of cornstalk is more and the synthesis combustion characteristic is better.

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