High-Rate Performance of LiCoO2 Epitaxial Thin Films with Various Surface Conditions

MRS Advances ◽  
2018 ◽  
Vol 3 (22) ◽  
pp. 1243-1247 ◽  
Author(s):  
Sou Yasuhara ◽  
Shintaro Yasui ◽  
Tomoyasu Taniyama ◽  
Mitsuru Itoh

ABSTRACTLithium ion batteries with high-rate performance have been demanded since electric and hybrid vehicles are released. It is known that high interfacial resistance between electrode and electrolyte prevents intercalation of lithium ions. We investigated high-rate capability of typical LiCoO2 cathode with various surface morphologies using epitaxial thin films prepared by pulsed laser deposition. As a result, high-rate performance in (104)LiCoO2 thin films was enhanced by an increase of (110)LiCoO2 facet density because diffusion coefficient of (110)LiCoO2 was larger than that of (104)LiCoO2. Therefore, a control of crystal plane at the surface is a key point for high-rate performance.

2020 ◽  
Vol 7 (9) ◽  
pp. 1900-1908 ◽  
Author(s):  
Xiaoxia Xu ◽  
Lingjie Li ◽  
Huiqing Chen ◽  
XiaoSong Guo ◽  
Zhonghua Zhang ◽  
...  

Heterostructured porous FeS2/CuS nanospheres exhibit enhanced reaction kinetics, excellent rate capability and desirable long-term cycling stability performance.


RSC Advances ◽  
2021 ◽  
Vol 11 (24) ◽  
pp. 14495-14503
Author(s):  
Christopher N. Chervin ◽  
Ryan H. DeBlock ◽  
Joseph F. Parker ◽  
Bethany M. Hudak ◽  
Nathaniel L. Skeele ◽  
...  

Substituting electroinactive Al3+ into vanadium ferrite aerogels boosts capacity to battery-relevant levels but in a material that expresses pseudocapacitive character and high-rate performance.


RSC Advances ◽  
2016 ◽  
Vol 6 (49) ◽  
pp. 43551-43555 ◽  
Author(s):  
Mengmeng Zhen ◽  
Xiao Zhang ◽  
Lu Liu

Novel bi-component-active hierarchical ZnO/ZnCo2O4 nanosheets with mesostructures presented a good high-rate performance for lithium ion batteries.


2017 ◽  
Vol 52 (12) ◽  
pp. 7140-7148 ◽  
Author(s):  
Lijuan Wang ◽  
Xiaojie Wang ◽  
Zhaohui Meng ◽  
Hongjiang Hou ◽  
Baokuan Chen

2016 ◽  
Vol 4 (24) ◽  
pp. 9593-9599 ◽  
Author(s):  
Gaihua Li ◽  
Hao Yang ◽  
Fengcai Li ◽  
Jia Du ◽  
Wei Shi ◽  
...  

Utilizing the adsorption properties of MOFs, a nanostructured NiP2@C was successfully synthesized, which exhibited enhanced capability for lithium storage in terms of both the reversible specific capacity and high-rate performance.


2018 ◽  
Vol 212 ◽  
pp. 198-201 ◽  
Author(s):  
Xiaochuan Chen ◽  
Renpin Liu ◽  
Lingxing Zeng ◽  
Xiaoxia Huang ◽  
Yixing Fang ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (61) ◽  
pp. 49651-49656 ◽  
Author(s):  
Y. L. Wang ◽  
X. Huang ◽  
F. Li ◽  
J. S. Cao ◽  
S. H. Ye

Pristine LNCM and LNCMA as Li-rich cathode materials for lithium ion batteries were synthesized via a sol–gel route. The Al-substituted LNCM sample exhibits an enhanced high rate performance and superior cyclability.


Ionics ◽  
2021 ◽  
Author(s):  
Li Wang ◽  
Li Sheng ◽  
Jin Wang ◽  
Hong Xu ◽  
Guangyu Tian ◽  
...  

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