Phase Diagram of LiF-Li3PO4 System: A New Mechanism of Heterovalent Anionic Isomorphism

MRS Advances ◽  
2017 ◽  
Vol 3 (23) ◽  
pp. 1309-1317
Author(s):  
G.V. Zimina ◽  
M. Tsygankova ◽  
M. Sadykova ◽  
F.M. Spiridonov ◽  
V.V. Fomichev ◽  
...  
Keyword(s):  
Phase Diagram ◽  
Solid Solution ◽  
Lithium Phosphate ◽  
System A ◽  
Heterovalent Isomorphism

ABSTRACTThe phase diagram of LiF-Li3PO4 system is studied. The eutectic coordinates are 800±5°C, 8±1 mol% Li3PO4. A region of a solid solution based on lithium phosphate with a length of up to 11±2 mol% LiF was discovered. It is assumed that there is heterovalent isomorphism where anionic tetrahedron (PO4)3- is replaced by tetrahedron (LiF4)3-.

Intermetallic Formation in the Aluminum–Copper System

2003 ◽  
Vol 10 (04) ◽  
pp. 677-683 ◽  
Author(s):  
E. B. Hannech ◽  
N. Lamoudi ◽  
N. Benslim ◽  
B. Makhloufi
Keyword(s):  
Electron Microscopy ◽  
Phase Diagram ◽  
Solid Solution ◽  
Intermetallic Layer ◽  
Equilibrium Phase ◽  
Equilibrium Phase Diagram ◽  
Diffusion Couples ◽  
Intermetallic Formation ◽  
Parabolic Law ◽  
Scanning Electron

Intermetallic formation at 425°C in the aluminum–copper system has been studied by scanning electron microscopy using welded diffusion couples. Several Al–Cu phases predicted by the equilibrium phase diagram of the elements and voids taking place in the diffusion zone have been detected in the couples. The predominant phases were found to be Al 2 Cu 3 and the solid solution of Al in Cu, α. The growth of the intermetallic layer obeyed the parabolic law.

scholarly journals Formation of Intermediate Phases and Supersaturated Solid Solution in Al-Cu System during Diffusion

2018 ◽  
Vol 383 ◽  
pp. 31-35 ◽  
Author(s):  
Alexey Rodin ◽  
Nataliya Goreslavets
Keyword(s):  
Phase Diagram ◽  
Solid Solution ◽  
High Temperature ◽  
Chemical Composition ◽  
Low Temperature ◽  
Supersaturated Solid Solution ◽  
Diffusion Processes ◽  
Equilibrium Phase ◽  
Equilibrium Phase Diagram ◽  
Intermediate Phases

The study of diffusion processes in the aluminum - copper system was carried out at the temperature 350 and 520 °C. Special attention was paid on the chemical composition of the system near Al/Cu interface. It was determined that the intermediate phases in the system, corresponding to the equilibrium phase diagram, were not formed at low temperature. At high temperature the intermediate phases forms starting with Cu - rich phases. In both cases supersaturated solid solution of copper in aluminum could be observed near the interface.

Quaternary phase diagrams as a tool for ionic cocrystallization: the case of a solid solution between a racemic and enantiopure ionic cocrystal

CrystEngComm ◽  
2020 ◽  
Vol 22 (14) ◽  
pp. 2537-2542
Author(s):  
Lixing Song ◽  
Fucheng Leng ◽  
Koen Robeyns ◽  
Tom Leyssens
Keyword(s):  
Phase Diagram ◽  
Solid Solution ◽  
Phase Diagrams ◽  
Solid Solution Formation ◽  
Quaternary Phase ◽  
Solution Formation ◽  
Contour Lines

Quaternary phase diagram of ionic cocrystals with solid solution formation is generated and dissolution surface is depicted clearly by contour lines.

scholarly journals The phase diagram of a mixed halide (Br, I) hybrid perovskite obtained by synchrotron X-ray diffraction

RSC Advances ◽  
2019 ◽  
Vol 9 (20) ◽  
pp. 11151-11159 ◽  
Author(s):  
Frederike Lehmann ◽  
Alexandra Franz ◽  
Daniel M. Többens ◽  
Sergej Levcenco ◽  
Thomas Unold ◽  
...  
Keyword(s):  
Phase Diagram ◽  
Solid Solution ◽  
Phase Separation ◽  
Structural Changes ◽  
X Ray Diffraction ◽  
X Ray ◽  
Hybrid Perovskite

The phase diagram elucidates structural changes and phase separation effects, induced by halide substitution in hybrid perovskite MAPb(I,Br)3 solid solution.

Complete phase diagram of a charged colloidal system: A synchro- tron x-ray scattering study

1989 ◽  
Vol 62 (13) ◽  
pp. 1524-1527 ◽  
Author(s):  
E. B. Sirota ◽  
H. D. Ou-Yang ◽  
S. K. Sinha ◽  
P. M. Chaikin ◽  
J. D. Axe ◽  
...  
Keyword(s):  
Phase Diagram ◽  
Colloidal System ◽  
X Ray ◽  
Complete Phase Diagram ◽  
System A ◽  
X Ray Scattering ◽  
Scattering Study ◽  
Ray Scattering

Structure, phase diagram and magnetic properties of Bi1−La FeO3 solid solution

2016 ◽  
Vol 42 (5) ◽  
pp. 6100-6106 ◽  
Author(s):  
Q.R. Yao ◽  
Y.H. Shen ◽  
P.C. Yang ◽  
H.Y. Zhou ◽  
G.H. Rao ◽  
...  
Keyword(s):  
Phase Diagram ◽  
Solid Solution ◽  
Magnetic Properties ◽  
Structure Phase
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