Crystallization Behavior and Recoilless Fraction Determination of Amorphous and Nanocrystalline Fe56Co24Nb4B13Si2Cu1 System

MRS Advances ◽  
2017 ◽  
Vol 2 (27) ◽  
pp. 1435-1440 ◽  
Author(s):  
Monica Sorescu ◽  
Julia Limongelli ◽  
Christopher Stroh ◽  
Kevin Byerly
Keyword(s):  
Gamma Rays ◽  
Hyperfine Magnetic Field ◽  
Rapid Quenching ◽  
Boundary Phase ◽  
Vacuum Furnace ◽  
Hyperfine Parameters ◽  
Nanocrystalline State ◽  
Recoilless Fraction ◽  
Fraction Determination

ABSTRACTAmorphous ferromagnetic alloy with the composition Fe56Co24Nb4B13Si2Cu1 was obtained by rapid quenching from the melt. Samples cut from the ribbons were annealed at 450, 550, 650 and 750 °C in a vacuum furnace. 57Fe Mössbauer spectroscopy was used to identify the phases formed based on the refined values of the hyperfine parameters. The as-quenched specimen was analyzed with a hyperfine magnetic field distribution and corresponded to an in-plane orientation of the magnetic moment directions. The sample annealed at 450 °C was found to be in a nanocrystalline state due to observation of the (FeCo)-Si alloy with the DO3 structure. The balance of the composition was represented by a metalloid-enriched amorphous grain boundary phase. In contradistinction to this, the samples annealed at 550-750 °C were totally crystallized and the new phases formed were α-(FeCo), (FeCo)2(BSi) and (FeCo)3(BSi). These findings suggest that nanocrystallization is obtained only at select processing temperatures. A new set of Mössbauer spectra was obtained by recording simultaneously the intensity transmitted by a sandwich of the sample with the stainless steel etalon, based on the dual absorber method recently introduced by us. The values of the recoilless fraction can be derived from the relative spectral areas. The f factor value dropped from 0.6 to 0.37 for the sample annealed at 450 °C, consistent with the onset of nanocrystallization in the system. For the completely crystallized specimens, the f factor maintained values close to 0.5. This indicates that the presence of quenched-in stresses may play a role in the ability of samples to undergo recoilless emission and absorption of gamma rays.

Nanocrystallization and Recoilless Fraction Determination of Fe68.5Co5Nb3Cu1Si15.5B7 Ferromagnetic Alloy

MRS Advances ◽  
2019 ◽  
Vol 4 (25-26) ◽  
pp. 1449-1455
Author(s):  
Monica Sorescu ◽  
Kevin Byerly
Keyword(s):  
Melt Spinning ◽  
Magnetic Moments ◽  
Vacuum Furnace ◽  
Recoilless Fraction ◽  
Elastic Stresses ◽  
Annealing Temperatures ◽  
F Factor ◽  
Out Of Plane ◽  
Fraction Determination

ABSTRACTAmorphous alloy Fe68.5Co5Nb3Cu1Si15.5B7 was obtained by melt spinning. Samples cut from the foil were annealed at 450, 550, 650 and 750 °C in a vacuum furnace. 57Fe Mӧssbauer spectroscopy was used to identify the crystalline phases formed and the orientation of the magnetic moments based on the refined values of the hyperfine parameters. The spectra of the samples annealed at 550, 650 and 750 °C were indicative of nanocrystallization, with the magnetic moments reoriented out-of-plane for the last sample. This behavior is in contradistinction to that of the Co-rich system, which was totally crystallized at these annealing temperatures. Our results show that small Co additions can lead to the formation of nanostructures over a whole range of annealing temperatures. A new series of Mӧssbauer spectra was obtained by recording simultaneously the intensity transmitted by a superposition of the sample with the stainless steel etalon, based on the dual absorber method previously introduced by us. The values of the recoilless fraction could be derived from the relative spectral areas. The f factor maintained values close to 0.7 for all samples measured, but dropped to 0.37 for the sample annealed at 750 °C. This behavior could be related to the presence of elastic stresses in the system, which caused the out-of-plane reorientation of the magnetic moment directions.

Structure, Magnetic Properties and Hyperfine Parameters of Nd-Substituted Ni-Fe-Ga Heusler Alloys

MRS Advances ◽  
2017 ◽  
Vol 2 (25) ◽  
pp. 1341-1346
Author(s):  
Monica Sorescu ◽  
Felicia Tolea ◽  
Mihaela Valeanu ◽  
Mihaela Sofronie
Keyword(s):  
Melt Spinning ◽  
Magnetic Measurements ◽  
Heusler Alloys ◽  
Hyperfine Magnetic Field ◽  
Rapid Quenching ◽  
Linear Least Squares ◽  
X Ray Diffraction ◽  
Hyperfine Parameters ◽  
X Ray ◽  
Field Distributions

ABSTRACTSamples of Ni57-xNdxFe18Ga25 with x=2 and 4 were prepared in ribbon form by rapid quenching via melt spinning route. The samples were analyzed by X-ray diffraction (XRD), magnetic measurements and Mössbauer spectroscopy, both in the as-quenched form and after thermal annealing at 900 oC for 2 min and 400 °C for 2 hours. For x=2 the Nd atoms are completely dissolved in the Ni-Fe-Ga matrix, while for x=4 the additional occurrence of the secondary 2:17 phase could be resolved. These findings were supported by the analysis of hyperfine magnetic field distributions obtained from the non-linear least-squares fitting of the Mössbauer spectra.

A New Method for Direct Determination of the Recoilless Fraction with Application to Magnetic Nanoparticles

2002 ◽  
Vol 721 ◽  
Author(s):  
Monica Sorescu
Keyword(s):  
Room Temperature ◽  
Average Particle Size ◽  
Direct Determination ◽  
Average Particle ◽  
Lattice Method ◽  
Recoilless Fraction ◽  
Single Room ◽  
Magnetite Particles ◽  
Physical Mixtures

AbstractWe propose a two-lattice method for direct determination of the recoilless fraction using a single room-temperature transmission Mössbauer measurement. The method is first demonstrated for the case of iron and metallic glass two-foil system and is next generalized for the case of physical mixtures of two powders. We further apply this method to determine the recoilless fraction of hematite and magnetite particles. Finally, we provide direct measurement of the recoilless fraction in nanohematite and nanomagnetite with an average particle size of 19 nm.

THE MEASUREMENT AND ANALYSIS OF TRIPLE CORRELATIONS

1964 ◽  
Vol 42 (6) ◽  
pp. 1101-1115 ◽  
Author(s):  
Philip B. Smith
Keyword(s):  
Gamma Rays ◽  
Heavy Particle ◽  
Original Data ◽  
Population Parameters ◽  
True Solution ◽  
Error Matrix ◽  
Mixing Ratios ◽  
Triple Correlation ◽  
Measurement And Analysis

The measurement and analysis of the intensity–direction correlation of gamma rays emitted in cascade following heavy-particle capture are treated. A procedure is discussed which is based upon the expansion of the triple-correlation intensity in terms of the set of angular functions orthogonal over the space of the emission (or absorption) directions. This is in contrast to the usual method which expresses the correlation in terms of Legendre polynomials. In the analysis procedure proposed, the population parameters are found directly from the original data, with the gamma-radiation mixing ratios assigned. The least-squares equations representing the best fit to the data contain the population parameters linearly and are solved by a standard computer program which also gives the value of χ2. The true solution is then found by varying the mixing ratios until a minimum in χ2 is reached. In addition to the determination of the population parameters of the decaying state and the mixing ratios of the gamma rays in the cascade, the calculation of the error matrix of these quantities, and the calculation of the formation parameters in simple capture, are described.

Determination of stable isotope ratios using nuclear reaction analysis coupled with a particle–gamma coincidence method

2021 ◽  
Author(s):  
Paula Rangel Pestana Allegro ◽  
Márcia de Almeida Rizzutto ◽  
Nemitala Added ◽  
Vitor Ângelo Paulino de Aguiar ◽  
Dennis Lozano Toufen ◽  
...  
Keyword(s):  
Nuclear Reaction ◽  
Gamma Rays ◽  
Charged Particles ◽  
Isotope Ratios ◽  
Nuclear Reaction Analysis ◽  
Stable Isotope Ratios ◽  
Coincidence Method ◽  
Medium Energy ◽  
Gamma Coincidence

This study presents an alternative method to determine isotope ratios using a medium energy accelerator and simultaneously measuring the charged particles and gamma-rays produced in a nuclear reaction.

scholarly journals Determination of the hyperfine magnetic field in magnetic carbon-based materials: DFT calculations and NMR experiments

2015 ◽  
Vol 5 (1) ◽  
Author(s):  
Jair C. C. Freitas ◽  
Wanderlã L. Scopel ◽  
Wendel S. Paz ◽  
Leandro V. Bernardes ◽  
Francisco E. Cunha-Filho ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Dft Calculations ◽  
Hyperfine Magnetic Field ◽  
Magnetic Carbon ◽  
Carbon Based
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