Improving Supercapacitor Energy Density via Nanocarbon Electrode Functionalization and Increasing Electrolyte Electrochemical Window

MRS Advances ◽  
2016 ◽  
Vol 1 (19) ◽  
pp. 1377-1382
Author(s):  
Uladzimir Novikau ◽  
Sviatlana Filipovich ◽  
Ihar Razanau

ABSTRACTThe present report is dedicated to a study of possible ways of increasing the energy density of the supercapacitor and thus, bridging the gap between the supercapacitor and the battery. Chemical functionalization of carbon nanomaterials, such as carbon nanotubes, activated carbon cloth, and activated carbon powder used as supercapacitor electrodes as well as novel aqueous electrolytes with the electrochemical window of up to 2 V are described. The hybrid approaches to energy storage mechanism in electrochemical energy storage devices are discussed. The first experimental results on the discussed hybrid energy storage devices are presented.

2021 ◽  
Vol 289 ◽  
pp. 116734 ◽  
Author(s):  
Feng Wang ◽  
Lin Zhang ◽  
Qian Zhang ◽  
Jinjiang Yang ◽  
Gaigai Duan ◽  
...  

Author(s):  
Chandra Chowdhury ◽  
Pranab Gain ◽  
Ayan Datta

Utilization of multivalent ions such as Ca(II), Mg(II), Al(III) in the energy storage devices opens up new opportunities to store energy density in a more efficient manner rather than monovalent...


Author(s):  
Mingrui Liu ◽  
Jing Li ◽  
Bing Chi ◽  
Long Zheng ◽  
Yuexing Zhang ◽  
...  

The Li-O2 battery is recognized as one of the most promising energy storage devices for next-generation automotive batteries due to its extremely high theoretical energy density. The design and preparation...


Author(s):  
Longtao Ren ◽  
Qian Wang ◽  
Yajie Li ◽  
Cejun Hu ◽  
Yajun Zhao ◽  
...  

Rechargeable lithium-sulfur (Li–S) batteries are considered one of the most promising next-generation energy storage devices because of their high theoretical energy density. However, the dissolution of lithium polysulfides (LiPSs) in...


Author(s):  
Juan Yu ◽  
Xuyang Wang ◽  
Jiaxin Peng ◽  
Xuefeng Jia ◽  
Linbo Li ◽  
...  

Abstract Biomass-activated carbon materials are promising electrode materials for lithium-ion hybrid capacitors (LiCs) because of their natural hierarchical pore structure. The efficient utilization of structural pores in activated carbon is very important for their electrochemical performance. Herein, porous biomass-activated carbon (PAC) with large specific surface area was prepared using a one-step activation method with biomass waste as the carbon source and ZnCl2 as the activator. To further improve its pore structure utilization efficiency, the PAC was doped with nitrogen using urea as the nitrogen source. The experimental results confirmed that PAC-1 with a high nitrogen doping level of 4.66% exhibited the most efficient pore utilization among all the samples investigated in this study. PAC-1 exhibited 92% capacity retention after 8000 cycles, showing good cycling stability. Then, to maximize the utilization of high-efficiency energy storage devices, LiNi0.8Co0.15Al0.05O2 (NCA), a promising cathode material for lithium-ion batteries with high specific capacity, was compounded with PAC-1 in different ratios to obtain NCA@PC composites. The NCA@PC-9 composite exhibited excellent capacitance in LiCs and an energy density of 210.9 Wh kg-1 at a high power density of 13.3 kW kg-1. These results provide guidelines for the design of high-performance and low-cost energy storage devices.


The need of energy storage and related devices are increasing day by day, due to the expansion of global population. To deal with such universal crisis, current energy storage devices like supercapacitors need to be improved in their performances and qualities. In this regard, quantum dots (QDs) are extensively being studied, especially due to their excellent properties. The utilization of QDs in supercapacitors is huge as electrode material as well as for fluorescent electrolytes. Various QDs based composites have been made for the same, which includes doping with various metals, non-metals and carbon nanomaterials (CNMs) like graphene, carbon nanotubes (CNTs) etc. In the present chapter the current advancement and futuristic possibilities of supercapacitors have been mentioned extensively.


RSC Advances ◽  
2020 ◽  
Vol 10 (34) ◽  
pp. 20173-20183
Author(s):  
Yasai Wang ◽  
Guilin Feng ◽  
Yang Wang ◽  
Zhenguo Wu ◽  
Yanxiao Chen ◽  
...  

Lithium–sulfur batteries are considered to be promising energy storage devices owing to their high energy density, relatively low price and abundant resources.


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